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Displacive Transformation Mechanisms in Zirconia Ceramics and Other Non-Metals

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Book cover Tailoring Multiphase and Composite Ceramics

Abstract

Phase transformation mechanisms in a variety of non-metals can be studied from the point of view of structural aspects and nucleation, and compared with metallurgical classification schemes.(1–3) In a “reconstructive” transformation first coordination bonds or nearest-neighbor interactions are broken and remade when converting to a new structure. Such processes require a high activation energy and are usually slow and sluggish. They proceed by thermally-activated growth across an interface. “Displacive” transformations on the other hand, involve no rupture of first cordinations, but merely a distortion of the crystal lattice. The activation energy is much lower and the kinetics are fast. Displacive transformations are not necessarily martensitic. This has been a frequent source of confusion, evident in the literature. Martensitic transformations are a subset of displacive transformations.(2) A martensitic mechanism is a “lattice-distortive, virtually diffusionless structure change having a dominant deviatoric component and associated shape change, such that strain energy dominates the kinetics and morphology during the transformation.”(2)

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Authors and Affiliations

  1. Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, IL, 61801, USA

    W. M. Kriven

  2. Department of Ceramic Engineering, University of Illinois at Urbana-Champaign, Urbana, IL, 61801, USA

    W. M. Kriven

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  1. W. M. Kriven
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Editors and Affiliations

  1. The Pennsylvania State University, University Park, Pennsylvania, USA

    Richard E. Tressler , Gary L. Messing , Carlo G. Pantano  & Robert E. Newnham , ,  & 

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© 1986 Plenum Press, New York

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Kriven, W.M. (1986). Displacive Transformation Mechanisms in Zirconia Ceramics and Other Non-Metals. In: Tressler, R.E., Messing, G.L., Pantano, C.G., Newnham, R.E. (eds) Tailoring Multiphase and Composite Ceramics. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2233-7_18

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  • DOI: https://doi.org/10.1007/978-1-4613-2233-7_18

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9309-5

  • Online ISBN: 978-1-4613-2233-7

  • eBook Packages: Springer Book Archive

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