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Electron Transfer Reactions on Oxide-Covered Metal Electrodes

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Modern Aspects of Electrochemistry

Part of the book series: Modern Aspects of Electrochemistry ((MAOE,volume 17))

Abstract

At bare metal electrodes the rates of outer-sphere electron transfer reactions show only a small dependence on the nature of the substrate1a the exchange current densities of a particular reaction on various metals differ by no more than about one order of magnitude, and the transfer coefficients are generally close to 0.5. These experimental findings are in line with theoretical considerations.1b,2

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Authors and Affiliations

  1. Institut für Physikalische Chemie der Universität Düsseldorf, D-4000, Düsseldorf, Federal Republic of Germany

    W. Schmickler & J. W. Schultze

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  1. W. Schmickler
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Editors and Affiliations

  1. Department of Chemistry, Texas A&M University, College Station, Texas, USA

    J. O’M. Bockris

  2. Department of Chemistry, University of Ottawa, Ottawa, Ontario, Canada

    B. E. Conway

  3. Department of Chemical Engineering, Texas A&M University, College Station, Texas, USA

    Ralph E. White

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Schmickler, W., Schultze, J.W. (1986). Electron Transfer Reactions on Oxide-Covered Metal Electrodes. In: Bockris, J.O., Conway, B.E., White, R.E. (eds) Modern Aspects of Electrochemistry. Modern Aspects of Electrochemistry, vol 17. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2133-0_5

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  • DOI: https://doi.org/10.1007/978-1-4613-2133-0_5

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