Abstract
The dual character of comb-shaped polymers, which consists of the independent behavior of the main and side chains of the macromolecules in the condensed state, is manifested to the greatest degree in dilute solutions where the intermolecular interaction of the chains is reduced to a minimum. The unusual structure of comb-shaped polymers which contain long and relatively independently behaving segments of methylene groups of varying length in association with the polar groups of the macromolecules is the basis for considering them as amphiphilic systems with a given number and length of the branches.
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Platé, N.A., Shibaev, V.P. (1987). Comb-Shaped Macromolecules in Solutions and Intramolecular Interactions. In: Comb-Shaped Polymers and Liquid Crystals. Specialty Polymers. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1951-1_4
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