Skip to main content

Statistical Mechanics of Adsorption and Wetting Transitions

  • Chapter
Surfactants in Solution

Abstract

The molecular theory of adsorption, contact angles and wetting transitions has seen considerable advancement during the last several years. Presented here is a status report on our current understanding of adsorption and wetting phenomena. The exposition makes extensive use of van der Waals theory of inhomogeneous fluids which, though simple, captures qualitatively most of the patterns observed experimentally or predicted by more rigorous theories.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. J. G. Kirkwood and F. P. Buff, J. Chem. Phys. 17, 338 (1949).

    Article  CAS  Google Scholar 

  2. F. P. Buff, Z. Elektrochem. 56, 311 (1952).

    CAS  Google Scholar 

  3. F. P. Buff, J. Chem. Phys. 19, 1591 (1951).

    Article  CAS  Google Scholar 

  4. F. P. Buff, J. Chem. Phys. 23, 419 (1955).

    Article  CAS  Google Scholar 

  5. F. P. Buff, J. Chem. Phys. 25, 146 (1956).

    Article  CAS  Google Scholar 

  6. J. H. Irving and J. G. Kirkwood, J. Chem. Phys. 18, 827 (1950).

    Article  Google Scholar 

  7. “The Equilibrium Theory of Classical Fluids,” H. L. Frisch and J. S. Lebowitz, eds., Benjamin, New York. (1966).

    Google Scholar 

  8. See for example, P. Pfeuty and G. Toulouse, “introduction to the Renormalization Group and Critical Phenomena,” Wiley, Chichester (1977).

    Google Scholar 

  9. S.-K. Ma, Modern Theory of Critical Phenomena, New York (1976).

    Google Scholar 

  10. B. Widom, “Statistical Mechanics and Statistical Methods in Theory and Application,” U. Landman, ed., Plenum Press, New York, pp. 33–71 (1976).

    Google Scholar 

  11. R. Evans, Adv. Phys. 28, 143, (1979).

    Article  CAS  Google Scholar 

  12. M. S. Jhon, J. S. Dahler, and R. C. Desai, Adv. Chem. Phys. 46, 279 (1981).

    Article  CAS  Google Scholar 

  13. H. T. Davis and L. E. Scriven, Adv. Chem. Phys. 49, 357 (1982).

    Article  CAS  Google Scholar 

  14. J. S. Rowlinson and B. Widom, Molecular Theory of Capillarity, Clarendon Press, Oxford (1982).

    Google Scholar 

  15. R. E. Benner, Jr., L. E. Scriven, and H. T. Davis, “Structure of the Interfacial Region,” M. Lal, Ed., Royal Society of Chemistry London pp. 169–190 (1982).

    Google Scholar 

  16. A. W. Adamson, “Physical Chemistry of Surfaces,” Interscience Pub., Second Edition, New York (1967).

    Google Scholar 

  17. J. Kerins, Ph.D. Thesis, Cornell University (1981).

    Google Scholar 

  18. D. F. O’Kane and K. L. Mittal, J. Vac. Sci. Technol. 11,567 (1974).

    Article  Google Scholar 

  19. W. A. Zisman, Adv. Chem. Ser. 43, 1 (1964).

    Article  CAS  Google Scholar 

  20. K. L. Mittal, Polymer Eng. Sci. 17, 467 (1977).

    Article  CAS  Google Scholar 

  21. L. A. Girifalco and R. J. Good, J. Phys. Chem. 61, 904 (1959).

    Article  Google Scholar 

  22. R.J. Good and L. A. Girifalco, J. Phys. Chem. 64, 561 (1960).

    Article  CAS  Google Scholar 

  23. J. W. Cahn, J. Chem. Phys. 66, 3667 (1977).

    Article  CAS  Google Scholar 

  24. C. Ebner and W. F. Saam, Phys. Rev. Lett. 38, 1486 (1977).

    Article  CAS  Google Scholar 

  25. For a recent review see R. Pandit, M. Schick, and M. Wortis,Phys. Rev. B 26, 5112 (1982).

    Article  CAS  Google Scholar 

  26. D. E. Sullivan, Phys. Rev. B 20, 3991 (1979).

    Article  CAS  Google Scholar 

  27. D. E. Sullivan, J. Chem. Phys. 74, 2604 (1981).

    Article  CAS  Google Scholar 

  28. C. Ebner, Phys. Rev. A 22, 2776 (1980).

    Article  CAS  Google Scholar 

  29. C. Ebner, Phys. Rev. A 23, 1925 (1981).

    Article  CAS  Google Scholar 

  30. P. Tarazona and R. Evans, Molec. Phys. 47, 1033 (1982).

    Article  CAS  Google Scholar 

  31. D. M. Kroll and R. Lipowsky, Phys. Rev. B 26, 5289 (1982).

    Article  Google Scholar 

  32. G. F. Teletzke, L. E. Scriven and H. T. Davis, J. Colloid Interface Sci. 87, 550 (1982).

    Article  CAS  Google Scholar 

  33. G. F. Teletzke, L. E. Scriven and H. T. Davis, J. Chem Phys. 77, 5794 (1982).

    Article  CAS  Google Scholar 

  34. H. Nakanishi and M. E. Fisher, Phys. Rev. Lett. 49, 1565 (1982).

    Article  CAS  Google Scholar 

  35. R. Lipowsky, Phys. Rev. Lett. 49, 1575 (1982).

    Article  CAS  Google Scholar 

  36. M. P. Nightingale, W. F. Saam, and M. Schick, Phys. Rev. Lett. 51, 1275 (1983).

    Article  CAS  Google Scholar 

  37. P. Tarazona and R. Evans, Molec. Phys. 48, 799 (1983).

    Article  CAS  Google Scholar 

  38. E. H. Hauge and M. Schick, Phys. Rev. B 27, 4288 (1983).

    Article  CAS  Google Scholar 

  39. G. F. Teletzke, L. E. Scriven, and H. T. Davis, J. Chem. Phys., 78, 1431 (1983).

    Article  CAS  Google Scholar 

  40. D. M. Kroll and R. Lipowsky, Phys. Rev. B 28, 5273 (1983).

    Article  CAS  Google Scholar 

  41. R. Evans and P. Tarazona, J. Chem. Phys. 80, 587 (1984).

    Article  CAS  Google Scholar 

  42. R. E. Benner, Jr., G. F. Teletzke, L. E. Scriven, and H. T. Davis, J. Chem. Phys. 80, 589 (1984).

    Article  CAS  Google Scholar 

  43. R. Lipowsky and D. M. Kroll, Phys. Rev. Lett. 52, 2303 (1984).

    Article  CAS  Google Scholar 

  44. Lord Rayleigh, Phil. Mag. 33, 208 (1892).

    Google Scholar 

  45. J. D. van der Waals and P. Kohnstamm, “Lehrbuch der thermodynamic,” Vol. 1, Maas and van Suchtelen, Leipzig (190Ö).

    Google Scholar 

  46. J. W. Cahn and J. E. Hilliard, J. Chem. Phys. 28, 258 (1958).

    Article  CAS  Google Scholar 

  47. V. Bongiorno, L. E. Scriven, and H. T. Davis, J. Colloid Interface Sci. 57, 462 (1976).

    Article  CAS  Google Scholar 

  48. A. J. M. Yang, P. D. Fleming III, and J. H. Gibbs, J. Chem. Phys. 65, 7 (1976).

    Article  Google Scholar 

  49. B. F. McCoy and H. T. Davis, Phys. Rev. A. 20, 1201 (1979).

    Article  CAS  Google Scholar 

  50. D. Y. Peng and D. B. Robinson, Ind. Eng. Chem. Fundam. 15 ,59 (1976).

    Article  CAS  Google Scholar 

  51. A. H. Falls, L. E. Scriven and H. T. Davis, J. Chem. Phys. 78, 7300 (1983).

    Article  CAS  Google Scholar 

  52. W. C. Kung, L. E. Scriven and H. T. Davis, J. Chem. Phys. (to be published).

    Google Scholar 

  53. A. H. Falls, L. E. Scriven and H. T. Davis, J. Chem. Phys. 75, 3986 (1981).

    Article  CAS  Google Scholar 

  54. R. E. Benner, Jr., Ph.D. Thesis, University of Minnesota (1983).

    Google Scholar 

  55. R. E. Benner, Jr., G. F. Teletzke, L. E. Scriven, and H. T. Davis, Molec. Phys. (to be submitted).

    Google Scholar 

  56. D. W. Pohl and W. I. Goldberg, Phys. Rev. Lett. 48, 1111 (1982).

    Article  CAS  Google Scholar 

  57. M. R. Moldover and J. W. Cahn, Science 207, 1073 (1980).

    Article  CAS  Google Scholar 

  58. J. W. Schmidt and M. R. Moldover, J. Chem. Phys. 79, 379 (1983).

    Article  CAS  Google Scholar 

  59. S. Ross and R. E. Kornbrekke, J. Colloid and Interface Science 98, 223 (1984).

    CAS  Google Scholar 

  60. S. Ross and R. E. Kornbrekke, J. Colloid and Interface Science 99, 446 (1984).

    Article  CAS  Google Scholar 

  61. R. L. Reed and R. N. Healy, SPE 8262, Annual Fall Technical Meeting of the Society of Petroleum Engineers, Las Vegas, 1979.

    Google Scholar 

  62. R. L. Reed and R. N. Healy, Society of Petroleum Engineers Journal 24, 342 (1984).

    Article  CAS  Google Scholar 

  63. D. Langevin, private communication.

    Google Scholar 

  64. S. Dietrich and M. Schick, Phys. Rev B, 31, 4718 (1985).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1986 Plenum Press, New York

About this chapter

Cite this chapter

Davis, H.T., Benner, R.E., Scriven, L.E., Teletzke, G.F. (1986). Statistical Mechanics of Adsorption and Wetting Transitions. In: Mittal, K.L., Bothorel, P. (eds) Surfactants in Solution. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1833-0_29

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-1833-0_29

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9024-7

  • Online ISBN: 978-1-4613-1833-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics