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Surfactants in Solution pp 1421–1430Cite as

Structure of a Fluorinated Nonionic O/W Microemulsion

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Abstract

Small angle neutron scattering has been used to study some O/W fluorinated microemulsions. We report some results concerning the ternary mixture: water + C6F13CH2(EO)5 + perfluorodecalin, for temperatures between 15°C and 40°C. We find a rapid change of the shape of the aggregates at low concentration, transforming from rod-like particles to oblate globules. Details on the structure of the interfacial film are also given, as regards the hydration rate, the conformation of the surfactant and the penetration of the oil.

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Author information

Authors and Affiliations

  1. Laboratoire d’Etudes des Solutions Organiques et Colloidales, UA CNRS 406, Université de Nancy I, B.P. N°239, 54506, Vandoeuvre les Nancy, France

    Jean-Claude Ravey & Marie-José Stébé

  2. Institut Laue Langevin, I.L.L., 156 X, 38042, Grenoble Cedex, France

    Rudolph Oberthür

Authors
  1. Jean-Claude Ravey
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  2. Marie-José Stébé
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  3. Rudolph Oberthür
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Editor information

Editors and Affiliations

  1. IBM Corporate Technical Institutes, 500 Columbus Ave., Thornwood, NY, 10594, USA

    Kashmiri Lal Mittal M.Sc.(First Class First), Ph.D. (Fellow of the American Institute of Chemists and Indian Chemial Society) (Fellow of the American Institute of Chemists and Indian Chemial Society)

  2. Centre de Recherches Paul Pascal, Domaine Universitaire, F-33405, Talence Cedex, France

    P. Bothorel (Professor of Chemistry at the University of Bordeaux, Assistant Director, Scientific Director of the GRECO “Microemulsions” (French cooperative action on microemulsions), consultant to the French Oil Company) (Professor of Chemistry at the University of Bordeaux, Assistant Director, Scientific Director of the GRECO “Microemulsions” (French cooperative action on microemulsions), consultant to the French Oil Company)

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© 1986 Plenum Press, New York

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Ravey, JC., Stébé, MJ., Oberthür, R. (1986). Structure of a Fluorinated Nonionic O/W Microemulsion. In: Mittal, K.L., Bothorel, P. (eds) Surfactants in Solution. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1833-0_24

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  • DOI: https://doi.org/10.1007/978-1-4613-1833-0_24

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9024-7

  • Online ISBN: 978-1-4613-1833-0

  • eBook Packages: Springer Book Archive

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