Abstract
Chlor-alkali technology is one of the largest electrochemical industries in the world, the main products being, as the name implies, chlorine and sodium hydroxide (caustic) generated simultaneously by the electrolysis of sodium chloride. It is an energy-intensive process and is the second largest consumer of electricity among electrolytic industries next to aluminum. Chlorine and caustic are indispensable intermediates in the chemical industry, chlorine being used in the manufacture of polyvinyl chloride and chlorinated organic compounds which are precursors in the production of polymers such as polyesters and urethanes. Caustic soda, on the other hand, finds extensive use in mineral processing, the pulp and paper industry, and textile and glass manufacturing operations.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
J. W. F. Hardie, Electrolytic Manufacture of Chemicals from SaltThe Chlorine Institute, Atlanta, Georgia, 1975.
J. E. Currey and G. G. Pumplin, Encyclopedia of Chemical Processing and DesignEd. by J. J. McKetta and W. A. Cunningham, Vol. 7, p. 305, Marcel Dekker, New York, 1978.
Diaphragm Cells for Chlorine ProductionSociety of Chemical Industry, London, 1977.
Y. C. Yen, Process economics program report No. 61 (1970), 61A (1974), 61B (1978), 61C (1982)
Stanford Research Institute, Menlo Park, California.
D. L. Caldwell, Comprehensive Treatise of ElectrochemistryVol. 2, Chap. 2, Ed. by J.O’M. Bockris, B. E. Conway, E. A. Yeager, and R. E. White, Plenum Press, New York, 1981.
A. T. Kuhn, Industrial Electrochemical ProcessesElsevier, New York, 1971.
Proceedings of the Oronzio DeNora symposium on chlorine technology, Ed. by O. DeNora, Impiante Elettrochimica S.P.A., Italy, 1979.
Final report on improvements in energy efficiency of industrial electrochemical processes, Ed. by T. R. Beck, ANL/OEPM-77-2, 1977.
Modern Chlor-Alkali Technology(A) Ed. by M. O. Coulter, 1980
Vol. 2, Ed. by C. Jackson, 1983, Society of Chemical Industry, London.
Chlorine production processes: Recent and energy saving developments, Ed. by J. S. Robinson, Noyes Data Corporation, New Jersey, 1981.
D. M. Novak, B. V. Tilak, and B. E. Conway, Modern Aspects of ElectrochemistryNo. 14, Chap. 4, Ed. by J.O’M. Bockris, B. E. Conway, and R. E. White, Plenum Press, New York, 1982.
Electrodes of Conductive Metallic OxidesPart A and Part B, Ed. by S. Trasatti, Elsevier, New York, 1981.
S. Trasatti and W. E. O’Grady, Advances in Electrochemistry and Electrochemical EngineeringVol. 12, p. 177, Ed. by H. Gerischer and C. W. Tobias, Wiley, New York, 1981.
B. V. Tilak, P. W. T. Lu, J. E. Colman, and S. Srinivasan, Comprehensive Treatise of ElectrochemistryVol. 2, Chap. 1, Ed. by J.O’M. Bockris, B. E. Conway, E. Yeager, and R. E. White, Plenum Press, New York, 1981.
A. J. Appleby, H. Kita, M. Chemla, and G. Bronöel, Encyclopedia of Electrochemistry of the ElementsVol. IX, Part A, Chap. IXa-3, Ed. by A. J. Bard, Marcel Dekker, New York, 1982.
M. S. Kircher, H. R. Engle, B. H. Ritter, and A. H. Bartlett, J.Electrochem. Soc.100 (1953) 448.
F. Hine, M. Yasuda, and T. Tanaka, Electrochem. Acta.22 (1977) 429.
F. Hine, M. Yasuda, and K. Fujita, J. Electrochem. Soc.128 (1981) 2314.
C. J. Molnar and M. M. Dorio, paper presented at the Electrochem. Soc. Meeting, Atlanta, Georgia, October 1977.
G. Angel and T. Lunden, J.Electrochem. Soc.99 (1952) 435, 44
G. Angel and T. Lunden, J.Electrochem. Soc. 100 (1953) 3.9
G. Angel and T. Lunden, J.Electrochem. Soc. 102 (1955) 124, 243
G. Angel and T. Lunden, J.Electrochem. Soc. 104 (1957) 167.
W. E. Cowley, B. Lott, and J. H. Enteisle, Trans. Inst. Chem. Eng.41 (1963) 372.
K. Hass, Electrochem. Technol.5 (1967) 246.
F. Hine, S. Matsuura, and S. Yoshizawa, Electrochem. Technol.5 (1967) 251.
F. Hine, M. Yasuda, F. Wang, and K. Yamakawa, Electrochem. Acta 16 (1971) 1519.
R. B. MacMullin, ChlorineACE monograph No. 154, Ed. by J. S. Sconce, p. 151, Reinhold, New York, 1962.
F. Hine, S. Yoshizawa, and S. Okada, Kogyo Kagaku Zashi (J. Chem. Soc. Jpn. Ind. Chem. Sec.) 62 (1959) 769, 773, 778.
F. Hine, T. Sugimori, S. Yoshizawa, and S. Okada, Electrochem. Technol.62 (1959) 955.
F. Hine, S. Yoshizawa, S. Okada, N. Yokota, T. Kadota, and J. Kushiro, Electrochem. Technol 62 (1959) 961.
H. A. Sommers, Chem. Eng. Prog.61(3) (1965) 94.
F. Hine and M. Yasuda, J.Electrochem. Soc.119 (1972) 1057.
F. Hine, M. Yasuda, and M. Higuchi, Chlorine bicentennial symposium, p. 278, Electrochem. Soc., 1974.
Y. Sekine and C. Motohashi, Soda to Enso (Soda and Chlorine) 33 (1982) 66.
J. J. Wolff and R. E. Anderson, paper presented at the AIChE Meeting, Orlando, Florida, May, 1982.
F. Hine and Y. Yagishita, Soda to Enso (Soda and Chlorine) 24 (1973) 131.
N. Yokota, Soda to Enso (Soda and Chlorine) 9 (1958) 495.
N. Yokota, Kagaku Kogaku (J. Soc. Chem. Eng. Jpn.) 23 (1959) 438
N. Yokota, Kagaku Kogaku (J. Soc. Chem. Eng. Jpn.) 25 (1961) 170.
P. J. Kienholz, paper presented at the Chemical Marketing Research Association, New York, May 1983.
F. Hine, M. Yasuda, I. Sugiura, and T. Noda, J.Electrochem. Soc.121 (1974) 220.
F. Hine and M. Yasuda, J.Electrochem. Soc.121 (1974) 1289.
British patent 6490/67, 1967.
H. B. Beer, Diaphragm Cells for Chlorine Productionp. 11, Society of Chemical Industry, London, 1977.
O. DeNora, Chem. Ing. Tech.42 (1970) 222
O. DeNora, Chem. Ing. Tech. 43 (1971) 182.
K. J. O’Leary, U.S. Patent No. 3,776,834, 1973.
F. Hine, M. Yasuda, T. Noda, T. Yoshida, and J. Okuda, J.Electrochem. Soc.126 (1979) 1439.
R. G. Erenburg, L. I. Khristalik, and V. I. Bystrov, Electrokhimiya 8 (1972) 1740.
R. G. Erenburg, L. I. Khristalik, and I. P. Yaroshevskaya, Electrokhimiya 11 (1975) 1068, 1072, 1236.
V. E. Kazarinov, L. I. Khristalik, and Yu. V. Pleskov, Trans. SAEST (India) 12 (1977) 287.
British patent 877,901 (1961) ;U.S. Patents Nos. 3,977,958, 4,142,005, and 4,061,549.
M. J. Hazelrigg and D. L. Caldwell, Abstract Nq. 457, Electrochem. Soc. Meeting, Seattle, Washington, May 1978 ;Chap. 10 in Ref. 9A.
S. Matsuura, Y. Ozaki, K. Motani, Y. Ohashi, and Y. Onoue, Abstract No. 417, Electrochem. Soc. Meeting, St. Louis, Missouri, May 1980.
Japanese patent Sho 25-2305.
K. Kanzaki and K. Fukatsu, Denki Kagaku (J. Electrochem. Soc. Jpn.) 19 (1951) 255
K. Kanzaki and K. Fukatsu, Denki Kagaku (J. Electrochem. Soc. Jpn.) 23 (1955) 169.
F. Hine, M. Yasuda and M. Watanabe, Denki Kagaku (J. Electrochem. Soc. Jpn.) 47 (1979) 401.
I. Malkin and J. R. Brannan, Abstract No. 262, Electrochem. Soc. Meeting,. Boston, May 1979.
A. M. Greenberg, New Materials and New ProcessesEd. by M. Nagayama et alp. 238, J.E.S. Press, Cleveland, Ohio, 1981.
D. W. Carnell and C. R. S. Needes, Abstract No. 260, Electrochem. Soc. Meeting, Boston, May 1979.
D. E. Brown, F. O. Fogarty, M. N. Mahmood, and A. K. Turner, Chap. 14 in Ref. 9B.
W. W. Carlin and W. B. Darlington, Abstract No. 261, Electrochem. Soc. Meeting, Boston, May 1979 W. B. Darlington, p. 30 in Ref. 7.
U.S. Patent No.4,358,353 (1982) K. Viswanathan and B. V. Tilak, J.Electrochem. Soc.131 (1984) 1551.
M. C. M. Man and A. L. C. Tseung, Abstract No. 263, Electrochem. Soc. Meeting, Boston, May 1979
British patent 1,556,452.
E. Yeager, Electrochemistry in Industry-New DirectionsEd. by U. Landau, E. Yeager, and D. Kortan, p. 29, Plenum Press, New York, 1982.
E. Yeager, Proc. Renewable Fuels and Advanced Power Sources for Transportation on Workshop, June 1982, Ed. by H. L. Chum and S. Srinivasan, p. 27, Report No. SERI/CP-234-1707 DE 83011988.
V. H. Thomas, Paper presented at the 5th Symposium on Soda Industry, Kyoto, November 1981.
L. J. Gestaut, J. A. Moomaw, and V. H. Thomas, paper presented at the Chlorine Institute’s 25th Plant Operations Seminar, Atlanta, Georgia, February 1982.
L. J. Gestaut, T. M. Clere, C. E. Graham and W. R. Bennett, Abstract No. 393
L. J. Gestaut, T. M. Clere, A. J. Niksa and C. E. Graham, Abstract No. 124, Electrochem. Soc. Meeting, Washington, D.C., October 1983.
R. B. MacMullin, Chem. Eng. Prog.46 (1950) 440.
Constitution of Binary Alloys, Ed. by M. Hansen, McGraw-Hill, New York, 1958.
Constitution of Binary Alloys, 1st Suppl., Ed. by R. P. Elliott, McGraw-Hill, New York, 1965.
Constitution of Binary Alloys, 2nd Suppl., Ed. by F. A. Shunk, McGraw-Hill, New York, 1969.
Supplement to Mellor’s Comprehensive Treatise on Inorganic and Theoretical Chemistry, Vol. 2, Suppl. 2, p. 581, Longmans, London, 164.
J. Balej, Electrochim. Acta.21 (1976) 953.
F. Hine, Muki Kogyo Kagaku (Inorganic Industrial Chemistry)p. 21, Asakura, Tokyo, 1967.
F. Hine, M. Okada, and S. Yoshizawa, Denki Kagaku 27 (1959) 419.
F. Hine, Electrochem. Technol 2 (1964) 79.
T. H. Chilton and A. P. Colburn, Ind. Eng. Chem.27 (1935) 255.
W. L. McCabe and J. C. Smith, Unit Operations of Chemical EngineeringSecond Edition, McGraw-Hill, New York, 1967.
R. B. MacMullin and G. A. Muccini, AIChe J.2 (1956) 393.
F. Hine, M. Yasuda, and T. Tanaka, Electrochim. Acta 22 (1977) 429.
B. Nagy and T. F. Bates, Am. Mineralogist 37 (1952) 1055.
G. J. Young and F. H. Healy, J. Phys. Chem.58 (1954) 881.
F. L. Pundsack, J. Phys. Chem.59 (1955) 892.
S. C. Clark and P. F. Holt, Nature 4708 (1960) 237.
I. Choi and R. W. Smith, J. Colloid Interface Sci.40 (1972) 253.
M. S. Kircher, ChlorineA.C.S. Monograph 154, Ed. by J. S. Sconce, p. 105, Reinhold, New York, 1962.
R. B. MacMullin, private communication.
F. Hine and M. Yasuda, J. Electrochem. Soc.118 (1971) 166.
T. Mukaibo, Denki Kagaku 20 (1952) 482.
R. E. White, J. S. Beckerdite, and J. Van Zee, Abstract No. 560, Electrochem. Soc. Meeting, San Francisco, May 1983
J. Van Zee and R. E. White, J. Elec-trochem. Soc.132 (1985) 818.
V. V. Stender, O. S. Ksenzhek, and V. N. Lazarev, Zh. Prikl. Khim.40 (1967) 1293.
O. S. Ksenzhek and V. M. Serbrit-Skii, Sov. Electrochem.4 (1968) 1294.
V. M. Serebrit-Skii and O. S. Ksenzhek, J. Appl. Chem. U.S.S.R.43 (1970) 69
V. M. Serebrit-Skii and O. S. Ksenzhek, Sov. Electrochem.7 (1971) 1592.
V. L. Kubasov, Sov. Electrochem.12 (1976) 72.
A. W. Bryson, P. G. Cook, and M. G. Lawrence, Chem. Eng. Commun.3 (1979) 53.
W. H. Koh, AIChe Symp. Ser.77(204) (1981) 213.
D. L. Caldwell, P. A. Poush, J. W. Van Zee, and R. E. White, Proc. Symp.Electrochem. Process and Plant Designp. 216, Ed. by R. C. Alkire, T. R. Beck, and R. D. Varjian, Proceedings Vol. 83-6, The Electrochem. Soc., New Jersey, 1983.
K. Viswanathan, Abstract No. 415, Electrochem. Soc. Meeting, Minneapolis, Minnesota, May 1981.
M. Seko, S. Ogawa, and K. Kimoto, paper presented at the Am. Chem. Soc. Centennial Meeting, New York, April 1976.
D. J. Vaughan, DuPont Innovation 4(3) (1973) 10.
D. Bergner, J.Appl. Electrochem.12 (1982) 631.
Chemical WeekNov. 17 (1982) 35.
M. Seko, paper presented at the ACS Polymer Division Workshop on Perfluori-nated Ionomer Membranes, Lake Buena Vista, Florida, February 1982.
T. Sata, K. Motani, and Y. Ohashi, Ion Exchange MembranesEd. by D. S. Flett, Chap. 9, p. 137, Society of Chemical Industry, London, 1983.
M. Seko, U.S. Patent No. 4,178,218, 1979.
C. J. Molnar, E. H. Price, and P. R. Resnick, U.S. Patent No. 4,176,215, 1979.
T. Asawa, Y. Oda, and T. Gunjima, Japanese Patent. Appl. No. 52-36589, 1977.
M. Seko, Y. Yamakoshi, H. Miyauchi, M. Fukomoto, K. Kimoto, I. Watanabe, T. Hane, and S. Tsushima, U.S. Patent No. 4,151,053, 1979.
W. G. Grot, G. J. Molnar, and P. R. Resnick, Belgian Patent No. 866122, 1978.
T. Sata, A. Nakahara, and J. Ito, Japanese Pat. Appl. No. 53-137888, 1978.
Wm. D. Morrison, paper presented at the Chlorine Institute’s 26th Chlorine Plant Operations Seminar, New Orleans, Louisiana, February 1983.
M. Seko, A. Yomiyama, and S. Ogawa, Ion Exchange MembranesEd. by D. S. Flett, Chap. 8, p. 121, Society of Chemical Industry, London, 1983.
H. Ukihashi, T. Asawa, and H. Miyake, Ion Exchange MembranesEd. by D. S. Flett, Chap. 11, p. 165, Society of Chemical Industry, London, 1983.
K. A. Mauritz and A. J. Hopfinger, Modern Aspects of ElectrochemistryNo. 14, Chap. 6, Ed. by J.O’M. Bockris, B. E. Conway, and R. E. White, Plenum Press, New York, 1982.
D. N. Bennion, Proc. Symp. on Membranes and Ionic and Electronic Conducting Polymersp. 78, Ed. by E. B. Yeager, B. Schuum, K. Mauritz, K. Abbey, D. Blankenship, and J. Akridge, proceedings Vol. 83-3, The Electrochem. Soc., 1983.
J. Jorne, J.Electrochem. Soc.129 (1982) 722.
M. Seko, S. Ogawa, M. Yoshida, and H. Shiroki, paper presented at the Inter-national Society of Electrochemistry, 34th Meeting, Erlangen, Germany, Septem-ber 1983.
F. Hine, M. Yasuda, Y. Ogata, and K. Hara, J.Electrochem. Soc.131 (1984) 83.
G. H. Sedahmed and L. W. Shemilt, J.Appl. Electrochem.14 (1984) 123.
S. M. Ibrahim, E. H. Price, and R. A. Smith, p. 53, Ref. 9B.
S. Ogawa, paper presented at Indian Inst. Chem. Eng., New Delhi, March 1980.
Brochure entitled MGC-Monopolar Membrane Electrolyzer-Data sheet, ECL-MGC-1 by Eltech Systems Corporation, 1983.
M. Esayian and J. H. Austin, paper presented at the 27th Chlorine Plant Operations Seminar, Washington, D.C., February 1984.
T. Tozuka, H. Aikawa, T. Onishi, K. Yamaguchi, I. Kumagai, and T. Ichisaka, paper presented at the 27th Chlorine Plant Operations Seminar, Washington, D.C., February 1984.
B. Noli, paper presented at the 27th Chlorine Plant Operations Seminar, Washing-ton, D.C., February 1984.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1986 Plenum Press, New York
About this chapter
Cite this chapter
Hine, F., Tilak, B.V., Viswanathan, K. (1986). Chemistry and Chemical Engineering in the Chlor-Alkali Industry. In: White, R.E., Bockris, J.O., Conway, B.E. (eds) Modern Aspects of Electrochemistry. Modern Aspects of Electrochemistry, vol 18. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1791-3_5
Download citation
DOI: https://doi.org/10.1007/978-1-4613-1791-3_5
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4612-9003-2
Online ISBN: 978-1-4613-1791-3
eBook Packages: Springer Book Archive