Abstract
Thermochromic reactions are of particular interest not only from the practical (1) and pedagogic (2) points of view, but also from a more fundamental standpoint (3). A number of studies drawn from a wide variety of domains have been devoted to their behavior (4–6).
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References
L.G. Spears Jr. and L.G. Spears, Chemical storage of solar energy using an old color change demonstration. J. Chem. Educ. 61:3 (1984).
J.P. Byrne, Thermodynamic data from the thermochromic effect. J. Chem. Educ. 55:267 (1978).
J. Sunamoto and T. Hamada, Solvatochromism and Thermochromism of Co(II) complexes solubilized in reversible micelles. Bull. Chem. Soc. Jap. 51:3120 (1978).
T. Sakai and N. Ohno, Selective determination of spartein by thermochromism of associates with tetrabromophenylphthalein ethyl ester. The Analyst (London) 107:634 (1982).
H.D. Hardt and A. Pierre, Fluorescence thermochromism of pyridine copper iodides. Z. Anorg. Allg. Chem. 402:107 (1973).
V.S. Marevtsev, N.L. Zaichenko, V.D. Ermakova, S.I. Beshenko, V.A. Linskii, T. Gradyushuko and M.I. Cherkashin, Effect of electron donor and electron acceptor substituents on photo and thermochromic properties of indoline spiropyranes. Isv. Akad. Nauk. SSR, Ser. Khim. 10:2272 (1980).
J.H. Day, Thermochromism of inorganic compounds. Chem. Rev. 68:649 (1968).
D. Lavabre, J.C. Micheau and G. Levy, Comparison of thermochromic equilibrium of Co(II) and Ni(II) complexes. J. Chem. Educ. to appear (Oct. 1987).
Y. Fukada, A. Shimamura, M. Mukaida, E. Fujita and K. Sone, Mixed copper (II) chelates with N,N,N’,N’,-tetramethylethylenediamine and beta-diketones. J. Inorg. Nucl. Chem. 36:1265 (1974).
Y. Fukada and K. Sone, Mixed Nickel (II) chelates with N,N,N’,N’,-tetramethylethylenediamine and beta-diketones. J. Inorg. Nucl. Chem. 34:2315 (1972).
J.E. Huheey, Inorganic Chemistry. Harper and Row, p.334, Edit. 1972.
J.R. Long and R.S. Drago, The rigorous evaluation of spectrophotometry data to obtain an equilibrium constant. J. Chem. Educ. 59:1037 (1982).
Y. Ihara, A. Wada, Y. Fukada and K. Sone, Preparation and thermal square planar-octahedral transformation of nickel complexes containing 1,2-butanediamine or 3,3-dimethyl-l,2- butanediamine in solid phase. Bull. Chem. Soc. Jap. 59:1037 (1986).
R. Hammer and H.F. Klein, The tetrakis(triphosphine)cobalt anion. Z. Naturforsch. B 32B(2):148 (1977).
I. Grenthe, P. Paoletti, M. Sandstroem and S. Glikberg, Thermochromism in copper (II) complexes. Structure of the red and blue-violet forms of bis(N,N-diethylethylenediamine copper(II) perchlorate and the non-thermochromic violet bis(N,ethylenediamine copper(II) perchlorate. Inorg. Chem. 18:2687 (1979).
I. Rosenthal, P. Peretz and K.A. Muskat, Thermochromic and hyperchromic effects in rhodamine B solutions. J. Phys. Chem. 83:350 (1979).
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© 1988 Plenum Press, New York
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Tan-Sien-Hee, L., Lavabre, D., Micheau, J.C., Levy, G. (1988). Determination of Thermodynamic and Spectral Parameters of a Thermochromic Equilibrium by UV/VIS Spectroscopy in Different Solvents. In: Moreau, M., Turq, P. (eds) Chemical Reactivity in Liquids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1023-5_10
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DOI: https://doi.org/10.1007/978-1-4613-1023-5_10
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