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Synthetic Dioxygen Carriers for Dioxygen Transport

  • Chapter
Oxygen Complexes and Oxygen Activation by Transition Metals

Abstract

Synthetic Dioxygen Carriers, a Key Area for the 1990s The promising application areas for synthetic dioxygen carriers range from internal medicine and small devices to the commodity gas market and basic fuel production and there seems little doubt this area will impact the lives of most people in the developed nations during the coming decades. Government and societal leaders, both Nationally and internationally,1,2,3continue to look to synthetics as possible eventual sources of dioxygen transport materials for temporary whole blood substitutes, envisioning such scenarios as those associated with major disasters and military engagements. Existing research has been focused on portable devices4 to provide dioxygen enriched atmospheres for those suffering such maladies as emphysema and for the very different area of underwater dioxygen supply.5,6 Dioxygen electrode systems for batteries are attractive targets on the full range of scales from tiny hearing aid cells through electric automobiles to fuel cells for the storage of off-peak energy by electric utility companies. For many large scale uses, for example foundry operation, a moderate enrichment of the dioxygen level is adequate and this is an especially attractive target area for separation techniques based on the use of transition metal dioxygen carriers.7,8 The cleansing of contaminated atmospheres is a less than obvious but related area for application. Using the same basic science and technology, control of very low levels of O2is possible with such materials since the variability of O2affinities of carriers spans many orders of magnitude (at least 6 andpossibly 10 or 12). Commodity level applications are most dramaticallyshown by the potential demands of the synfuel industry as revealed by industrial response to the synfuel goals set by the Cartera administration.9,10,11 It was concluded by American dioxygen-supplyingindustry that the existing cryogenic technology couldnotbe expanded fast enough to meet the needs of the then projected synfuel industry and that at least one new major technology would have to be exploited. The first attempts to exploit transition metal dioxygen carriers were military.12,13

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Authors and Affiliations

  1. The Ohio State University, 120 West 18th Avenue, Columbus, Ohio, 43210, USA

    Daryle H. Busch (Professor of Chemistry)

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Editors and Affiliations

  1. Texas A&M University, College Station, Texas, USA

    Arthur E. Martell  & Donald T. Sawyer  & 

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© 1988 Plenum Press, New York

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Busch, D.H. (1988). Synthetic Dioxygen Carriers for Dioxygen Transport. In: Martell, A.E., Sawyer, D.T. (eds) Oxygen Complexes and Oxygen Activation by Transition Metals. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0955-0_6

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  • DOI: https://doi.org/10.1007/978-1-4613-0955-0_6

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-8263-1

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