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The Oxidation of Organic Compounds by Metal Complexes in Zeolites

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Oxygen Complexes and Oxygen Activation by Transition Metals

Abstract

The selective oxidation of organic compounds to desired products has long been a challenge to chemists. The industrial oxidation of hydrocarbons to useful oxygenated compounds is commercially important and is carried out on a very large scale — on the order of several billons of pounds per year. The reactions are usually carried out at high temperatures(>150°C) and pressures,1 and often leave much to be desired in terms of selectivity. The difficultylies in the fact that the desired products are often themselves easily oxidizable, so that a certain percentage of the carbon is inevitably lost to CO and CO2, and other byproducts.

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© 1988 Plenum Press, New York

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Tolman, C.A., Herron, N. (1988). The Oxidation of Organic Compounds by Metal Complexes in Zeolites. In: Martell, A.E., Sawyer, D.T. (eds) Oxygen Complexes and Oxygen Activation by Transition Metals. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0955-0_21

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  • DOI: https://doi.org/10.1007/978-1-4613-0955-0_21

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-8263-1

  • Online ISBN: 978-1-4613-0955-0

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