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The Chemistry and Activation of Dioxygen Species (O2, O2-., and HOOH) in Biology

  • Donald T. Sawyer

Abstract

Biological systems activate dioxygen(02) for controlled energy transduction and chemical syntheses. This is accomplished via electron-transfer reduction of 02 to 02 -and HOOH, and its atomization with metalloproteins to accomplish atom-transfer chemistry. These reactive intermediates have been characterized by the use of (a) transition-metal complexes as models for metalloproteins and (b) model substrates.

Keywords

Reactive Intermediate Porphyrin Ring Allylic Hydrogen Br0nsted Acid Dioxygen Species 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1988

Authors and Affiliations

  • Donald T. Sawyer
    • 1
  1. 1.Department of ChemistryTexas A&M UniversityCollege StationUSA

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