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Abstract

Contrary to the concept of valence compensation, the title compounds exhibit a metallic behavior. The M(Cu,Ni) atoms effect a charge transfer and induce n-type behavior whereas ZrSiS and NbSiAs are p-type metals.

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© 1987 Plenum Press, New York

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Janaki, J., Subba Rao, G.V. (1987). Studies on ZrSiS and ZrMSiAs(M=Cu,Ni) Phases with the PbFCl Structure. In: Gupta, L.C., Malik, S.K. (eds) Theoretical and Experimental Aspects of Valence Fluctuations and Heavy Fermions. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0947-5_124

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  • DOI: https://doi.org/10.1007/978-1-4613-0947-5_124

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-8259-4

  • Online ISBN: 978-1-4613-0947-5

  • eBook Packages: Springer Book Archive

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