Abstract
The actinyl ion UO 22+in single crystals of CS 2UO 2CI 4is linear and centrosymmetric. Electronic transitions in the region 350-500 nm are parity forbidden by an electric dipole mechanism in single photon absorption spectroscopy. Low temperature, polarized, fluorescence excitation spectra were presented in which the excitation was a pulsed,tunable infrared dye laser operating from 700-1000 nm. Two-photon spectroscopy clearly reveals the presence of 12 “allowed” electronic origins.
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© 1987 Springer-Verlag Berlin Heidelberg
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Thorne, J.R.G., Denning, R.G. (1987). Two-Photon Excitation Spectroscopy of Actinyl Ions. In: Di Bartolo, B. (eds) Spectroscopy of Solid-State Laser-Type Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0899-7_29
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DOI: https://doi.org/10.1007/978-1-4613-0899-7_29
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4612-8235-8
Online ISBN: 978-1-4613-0899-7
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