Modification of Photochemical Reactivity By Incorporation of Reactants into Hydrophobic Pockets and Cavities: Conformational and Cage Effects

  • S. Devanathan
  • G. Dasaratha Reddy
  • V. Ramamurthy

Abstract

The control and modification of reactivity through incorporation of molecules into organized assemblies remains an area of considerable interest. A specific subarea that has attracted recent interest concerns reactivity of molecules incorporated into host-guest systems. In this context, we have investigated the photochemical behavior of a large number of organic molecules in micellar and cyclodextrin media. The photochemical Norrish type I and type II reactions of cyclodextrin and micellar bound benzoin alkyl ethers have been explored. The irradiation in micellar and cyclodextrin media leads to a large change in product distribution from that found in benzene and methanol. Conformational and cage effects have been proposed to be responsible for the dramatic alteration in the photobehavior.

Keywords

Benzene Cage Recrystallization Ketone CTAB 

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Copyright information

© Plenum Press, New York 1989

Authors and Affiliations

  • S. Devanathan
    • 1
  • G. Dasaratha Reddy
    • 1
  • V. Ramamurthy
    • 1
  1. 1.Department of Organic ChemistryIndian Institute of ScienceBangaloreIndia

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