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Redox Reactions between Two Metal Complexes

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Mechanisms of Inorganic and Organometallic Reactions

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Abstract

The investigations of the kinetics and mechanisms of electron transfer between metal complexes are continuing to diversify, from the reactions of octahedral species in aqueous solution to systems involving less common metals and coordination geometries in nonaqueous media. The activity in the study of electron transfer reactions involving metalloproteins is increasing rapidly, with an emphasis on the rate dependencies on distance and free energy. The format of the Chapter remains much the same as in previous volumes, with sections covering metal aqua and oxo ions, metal ion complexes, and metalloproteins. The rate and activation parameters are presented in four tables, with the data for electron transfer reactions between metal complexes in Table 2.1, directly measured electron self-exchange rate data in Table 2.2, and the data for intramolecular and bimolecular reactions involving metalloproteins in Tables 2.3 and 2.4, respectively. The discussion in each section of the text and the data in the tables are arranged, for the most part, in the order of increasing atomic number of the central metal ion in the reductant.

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    M. V. Twigg

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    M. V. Twigg

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Twigg, M.V. (1989). Redox Reactions between Two Metal Complexes. In: Twigg, M.V. (eds) Mechanisms of Inorganic and Organometallic Reactions. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0827-0_2

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  • DOI: https://doi.org/10.1007/978-1-4613-0827-0_2

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