Skip to main content
SpringerLink
Log in

Metal—Alkyl and Metal—Hydride Bond Formation and Fission

Oxidative Addition and Reductive Elimination

  • Chapter
Mechanisms of Inorganic and Organometallic Reactions

  • 191 Accesses

Abstract

The “activation” of thermodynamically stable carbon-hydrogen and hydrogen-hydrogen bonds may be accomplished by oxidatively adding them across certain coordinatively unsaturated metal fragments. This fledgling area of transition metalorganic chemistry is currently attracting much interest among inorganic and organometallic chemists. Within the last decade, many breakthroughs have occurred, including the activation of alkanes and the discovery of agostic and metal dihydrogen complexes. Key reviews which have appeared during 1987 and the first half of 1988 have included thorough monographs on ligation by σ-bonded groups (i.e., C-H and H-H)(1) and on dihydrogen complexes.(2) Activation of C—H bonds has been reviewed in the Soviet literature.(3) Other pertinent reviews have focused upon reactions of dinuclear dppm complexes,(4) cyclometalation,(5,6) industrial homogenous catalysis, (7) anionic metal hydrides, (8) organoplatinum(IV) chemistry,(9) and the homogenous catalytic chemistry of ruthenium(1O) and iridium. (11)

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Reference

  1. R. H. Crabtree and D. G. Hamilton, Adv. Organomet. Chem., 28, 299 (1988).

    CAS  Google Scholar 

  2. G. J. Kubas, Acc. Chem. Res., 21, 120 (1988).

    Google Scholar 

  3. A. E. Shilov and G. B. Shul’pin, Russ. Chem. Rev., 56, 442 (1987).

    Google Scholar 

  4. B. Chaudret, B. Delavaux, and R. Poilblanc, Coord. Chem. Rev., 86, 191 (1988).

    CAS  Google Scholar 

  5. I. Omae, Coord. Chem. Rev., 83, 137 (1988).

    CAS  Google Scholar 

  6. I. P. Rothwell, Acc. Chem. Res., 21, 153 (1988).

    CAS  Google Scholar 

  7. G. W. Parshall and W. A. Nugent, ChemTech., 184, 314, 376 (1988).

    Google Scholar 

  8. M. Y. Darensbourg and C. E. Ash, Adv. Orgnnomet. Chem., 27, 1 (1987).

    CAS  Google Scholar 

  9. V. K. Jain, G. S. Rao, and L. Jain, Adv. Organomet. Chem., 27, 113 (1987).

    CAS  Google Scholar 

  10. J. Halpern, Pure Appl. Chem., 59, 173 (1987).

    CAS  Google Scholar 

  11. J. D. Atwood, Coord. Chem. Rev., 83, 93 (1988).

    CAS  Google Scholar 

  12. C. Bianchini, C. Mealli, M. Peruzzini, and F. Zanobini, J. Am. Chem. Soc., 109, 5548 (1987).

    CAS  Google Scholar 

  13. R. H. Morris, K. A. Earl, R. L. Luck, N. J. Lazarowych, and A. Sella, Inorg. Chem., 26, 2674 (1987).

    CAS  Google Scholar 

  14. P. J. Hay, J. Am. Chem. Soc., 109, 705 (1987).

    CAS  Google Scholar 

  15. F. Volatron, Y. Jean, and A. Lledos, New J. Chem., 11, 651 (1987).

    CAS  Google Scholar 

  16. J. K. Burdett, J. R. Phillips, M. R. Pourian, M. Poliakoff, J. J. Turner, and R. Upmacis, Inorg. Chem., 26, 3054 (1987).

    CAS  Google Scholar 

  17. D. M. Heinekey, N. G. Payne, and G. K. Schulte, J. Am. Chem. Soc., 110, 2303 (1988).

    CAS  Google Scholar 

  18. M. Antberg, K.-M. Frosin, and L. Dahlenburg, J. Organomet. Chem., 338, 319 (1988).

    CAS  Google Scholar 

  19. M. Antberg, L. Dahlenburg, K.-M. Frosin, and N. Hock, Chem. Ber., 121, 859 (1988).

    CAS  Google Scholar 

  20. M. S. Chinn and D. M. Heinekey, J. Am. Chem. Soc., 109, 5865 (1987).

    CAS  Google Scholar 

  21. F. M. Conroy-Lewis and S. J. Simpson, J. Chem. Soc., Chem. Commun., 1675 (1987).

    Google Scholar 

  22. G. J. Kubas, R. R. Ryan, and C. J. Unkefer, J. Am. Chem. Soc., 109, 8113 (1987).

    CAS  Google Scholar 

  23. M. Bautista, K. A. Earl, R. H. Morris, and A. Sella, J. Am. Chem. Soc., 109, 3781 (1987).

    Google Scholar 

  24. M. T. Bautista, K. A. Earl, and R. H. Morris, Inorg. Chem., 27, 1124 (1988).

    CAS  Google Scholar 

  25. M. T. Bautista, K. A. Earl, P. A. Maltby, and R. H. Morris, J. Am. Chem. Soc., 110, 4056 (1988).

    CAS  Google Scholar 

  26. R. A. Henderson, J. Chem. Soc., Chem. Commun., 1670 (1987).

    Google Scholar 

  27. A. A. Gonzalez, S. L. Mukerjee, S.-J. Chou, Z. Kai, and C. D. Hoff, J. Am. Chem. Soc., 110, 4419 (1988).

    CAS  Google Scholar 

  28. S. A. Jackson, R. K. Upmacis, M. Poliakoff, J. J. Turner, J. K. Burdett, and F.-W. Grevels, J. Chem. Soc., Chem. Commun., 678 (1987).

    Google Scholar 

  29. R. L. Sweany and F. N. Russell, Organometallics, 7, 719 (1988).

    CAS  Google Scholar 

  30. T. Arliguie, B. Chaudret, R. H. Morris, and A. Sella, Inorg. Chem., 27, 598 (1988).

    CAS  Google Scholar 

  31. C. Hampton, T. W. Dekleva, B. R. James, and W. R. Cullen, Inorg. Chim. Acta, 145, 165 (1988).

    CAS  Google Scholar 

  32. X. L. R. Fontaine, E. H. Fowles, and B. L. Shaw, J. Chem. Soc., Chem. Commun., 482 (1988).

    Google Scholar 

  33. J. B. Schilling, W. A. Goddard, and J. L. Beauchamp, J. Am. Chem. Soc., 109, 5565 (1987).

    CAS  Google Scholar 

  34. J. B. Schilling, W. A. Goddard, and J. L. Beauchamp, J. Am. Chem. Soc., 109, 5573 (1987).

    CAS  Google Scholar 

  35. T. Ziegler, V. Tschinke, and A. Becke, J. Am. Chem. Soc., 109, 1351 (1987).

    CAS  Google Scholar 

  36. J. A. Labinger and J. E. Bercaw, Organometallics, 7, 926 (1988).

    CAS  Google Scholar 

  37. M. J. Calhorda and J. A. M. Simoes, Organometallics, 6, 1188 (1987).

    CAS  Google Scholar 

  38. M. J. Calhorda, A. R. Dias, M. E. M. da Piedade, M. S. Salema, and J. A. M. Simoes, Organometallics, 6, 734 (1987).

    CAS  Google Scholar 

  39. A. R. Dias, M. S. Salema, J. A. M. Simoes, J. W. Pattiasina, and J. H. Teuben, J. Organomet. Chem., 346, C4 (1988).

    CAS  Google Scholar 

  40. R. T. Edidin, J. M. Sullivan, and J. R. Norton, J. Am. Chem. Soc., 109, 3945 (1987).

    CAS  Google Scholar 

  41. D. L. Packett and W. C. Trogler, Inorg. Chem., 27, 1768 (1988).

    CAS  Google Scholar 

  42. D. L. Packett, A. Syed, and W. C. Trogler, Organometallics, 7, 159 (1988).

    CAS  Google Scholar 

  43. A. Scrivanti, R. Campostrini, and G. Carturan, Inorg. Chim. Acta, 142, 187 (1988).

    CAS  Google Scholar 

  44. C. S. Christ, J. R. Eyler, and D. E. Richardson, J. Am. Chem. Soc., 110, 4038 (1988).

    CAS  Google Scholar 

  45. J. Powell, M. R. Gregg, and J. F. Sawyer, J. Chem. Soc., Chem. Commun., 1029 (1987).

    Google Scholar 

  46. U.Koelle, P. P. Infelta, and M. Gratzel, Inorg. Chem., 27, 879 (1988).

    CAS  Google Scholar 

  47. A. J. Kunin, C. E. Johnson, J. A. Maguire, W. D. Jones, and R. Eisenberg, J. Am. Chem. SOC., 109, 2963 (1987).

    CAS  Google Scholar 

  48. M. D. Fryzuk, P. A. MacNeil, and S. J. Rettig, J. Am. Chem. Soc., 109, 2803 (1987).

    CAS  Google Scholar 

  49. M. D. Fryzuk, and K. Bhangu, J. Am. Chem. Soc., 110, 961 (1988).

    CAS  Google Scholar 

  50. M. M. T. Khan, E. R. Rao, M. R. H. Siddiqui, B. T. Khan, S. Begum, S. M. Ali, and J. Reddy, J. Mol. Catal., 45, 35 (1988).

    CAS  Google Scholar 

  51. C. Bianchini, A. Meli, M. Peruzzini, and F. Zanobini, J. Chem. Soc., Chem. Commun., 971 (1987).

    Google Scholar 

  52. W. A. Schenk and J. Leissner, Z. Naturforsch., 42b, 967 (1987).

    Google Scholar 

  53. M. Iglesias, C. del Pino, J. L. Nieto, S. G. Blanco, and S. M. Carrera, Inorg. Chim. Acta, 145, 91 (1988).

    CAS  Google Scholar 

  54. M. C. Jennings, N. C. Payne, and R. J. Puddephatt, Inorg. Chem., 26, 3776 (1987).

    CAS  Google Scholar 

  55. F. Bottomley, T.-T. Chin, G. O.Egharevba, L. M. Kane, D. A. Pataki, and P. S. White, Organometallics, 7, 1214 (1988).

    CAS  Google Scholar 

  56. A. L. Casalnuovo, J. C. Calabrese, and D. Milstein, Inorg. Chem., 26, 971 (1987).

    CAS  Google Scholar 

  57. A. B. Anderson and S. Baldwin, Organometallics, 6, 1621 (1987).

    CAS  Google Scholar 

  58. S.-C. Chang, R. H. Hauge, W. E. Billups, J. L. Margrave, and Z. H. Kafafi, Inorg. Chem., 27, 205 (1988).

    CAS  Google Scholar 

  59. J. B. Schilling and J. L. Beauchamp, Organometallics, 7, 194 (1988).

    CAS  Google Scholar 

  60. J. B. Schilling and J. L. Beauchamp, J. Am. Chem. Soc., 110, 15 (1988).

    CAS  Google Scholar 

  61. M. A. Hanratty, J. L. Beauchamp, A. J. Illies, P. van Koppen, and M. T. Bowers, J. Am. Chem. Soc., 110, 1 (1988).

    CAS  Google Scholar 

  62. J. Chang and R. G. Bergman, J. Am. Chem. Soc., 109, 4298 (1987).

    CAS  Google Scholar 

  63. P. K. Byers, A. J. Canty, B. W. Skelton, and A. H. White, J. Chem. Soc., Chem. Commun., 1093 (1987).

    Google Scholar 

  64. P. K. Byers and A. J. Canty, J. Chem. Soc., Chem. Commun., 639 (1988).

    Google Scholar 

  65. D. P. Klein, J. C. Hayes, and R. G. Bergman, J. Am. Chem. Soc., 110, 3704 (1988).

    CAS  Google Scholar 

  66. S. P. Nolan, C. D. Hoff, P. O.Stoutland, L. J. Newman, J. M. Buchanan, R. G. Bergman, G. K. Yang, and K. S. Peters, J. Am. Chem. Soc., 109, 3143 (1987).

    CAS  Google Scholar 

  67. D. E. Marx and A. J. Lees, Inorg. Chem., 27, 1121 (1988).

    CAS  Google Scholar 

  68. A. J. Rest, I. Whitwell, W. A. G. Graham, J. K. Hoyano, and A. D. McMaster, J. Chem. Soc., Dalton Trans., 1181 (1987).

    Google Scholar 

  69. J. Mascetti and A. J. Rest, J. Chem. Soc., Chem. Commun., 221 (1987).

    Google Scholar 

  70. S. T. Belt, D. M. Haddleton, R. N. Perutz, B. P. H. Smith, and A. J. Dixon, J. Chem. Soc., Chem. Commun., 1347 (1987).

    Google Scholar 

  71. D. M. Haddleton, A. McCamley, and R. N. Perutz, J. Am. Chem. Soc., 110, 1810 (1988).

    CAS  Google Scholar 

  72. R. H. Hill and M. S. Wrighton, Organometallics, 6, 632 (1987).

    CAS  Google Scholar 

  73. H.Rabaa, J.-Y. Saillard, and U. Schubert, J. Organomet. Chem., 330, 397 (1987).

    CAS  Google Scholar 

  74. W. D. McGhee and R. G. Bergman, J. Am. Chem. Soc., 110, 4246 (1988).

    CAS  Google Scholar 

  75. C. K. Ghosh and W. A. G. Graham, J. Am. Chem. Soc., 109, 4726 (1987).

    CAS  Google Scholar 

  76. M. Hackett, J. A. Ibers, and G. M. Whitesides, J. Am. Chem. Soc., 110, 1436 (1988).

    CAS  Google Scholar 

  77. M. Hackett and G. M. Whitesides, J. Am. Chem. Soc., 110, 1449 (1988).

    CAS  Google Scholar 

  78. M. V. Baker and L. D. Field, J. Am. Chem. Soc., 109, 2825 (1987).

    CAS  Google Scholar 

  79. M. E. Vol’pin, I. S. Akhrem, S. V. Reznichenko, and V. V. Grushin, J. Organomet. Chem., 334, 109 (1987).

    Google Scholar 

  80. T. Sakakura and M. Tanaka, J. Chem. Soc., Chem. Commun., 758 (1987).

    Google Scholar 

  81. T. Sakakura and M. Tanaka, Chem. Lett., 249 (1987).

    Google Scholar 

  82. T. Sakakura, T. Hayashi, and M. Tanaka, Chem. Lett., 859 (1987).

    Google Scholar 

  83. T. Sakakura and M. Tanaka, Chem. Lett., 1113 (1987).

    Google Scholar 

  84. K. Nomura and Y. Saito, J. Chem. Soc., Chem. Commun., 161 (1988).

    Google Scholar 

  85. T. Sakakura, K. Sasaki, Y. Tokunaga, K. Wada, and M. Tanaka, Chem. Lett., 155 (1988).

    Google Scholar 

  86. T. Sakakura, T. Sodeyama, Y. Tokunaga, and M. Tanaka, Chem. Lett., 263 (1988).

    Google Scholar 

  87. R. N. McDonald and M. T. Jones, Organometallics, 6, 1991 (1987).

    CAS  Google Scholar 

  88. F. D. Miller and R. D. Sanner, Organometallics, 7, 818 (1988).

    CAS  Google Scholar 

  89. P. Legzdins, J. T. Martin, F. W. B. Einstein, and R. H. Jones, Organometallics, 6, 1826 (1987).

    CAS  Google Scholar 

  90. C. Bianchini, A. Meli, M. Peruzzini, A. Vacca, and F. Zanobini, Organometallics, 6, 2453 (1987).

    CAS  Google Scholar 

  91. C. Bianchini, C. Mealli, M. Peruzzini, F. Vizza, and F. Zanobini, J. Organomet. Chem., 346, C53 (1988).

    CAS  Google Scholar 

  92. C. Bianchini, M. Peruzzini, F. Vizza, and F. Zanobini, J. Organomet. Chem., 348, C9 (1988).

    CAS  Google Scholar 

  93. C. Bianchini, M. Peruzzini, and F. Zanobini, J. Organomet. Chem., 326, C79 (1987).

    CAS  Google Scholar 

  94. T. B. Marder, D. Zargarian, J. C. Calabrese, T. H. Herskovitz, and D. Milstein, J. Chem. Soc., Chem. Commun., 1484 (1987).

    Google Scholar 

  95. P. A. Chetcuti, C. B. Knobler, and M. F. Hawthorne, Organometallics, 7, 650 (1988).

    CAS  Google Scholar 

  96. T. Sakakura, T. Sodeyama, Y. Tokunaga, and M. Tanaka, Chem. Lett., 2211 (1987).

    Google Scholar 

  97. M. Tanaka, T. Sakakura, Y. Tokunaga, and T. Sodeyama, Chem. Lett., 2373 (1987).

    Google Scholar 

  98. T.Sakakura, Y. Tokunaga, T. Sodeyama, and M. Tanaka, Chem. Lett., 2375 (1987).

    Google Scholar 

  99. P. D. Grebenik, M. L. H. Green, A. Izquierdo, V. S. B. Mtetwa, and K. Prout, J. Chem. Soc., Dalton Trans., 9 (1987).

    Google Scholar 

  100. H. Suzuki, D. H. Lee, N. Oshima, and Y. Moro-oka, Organometallics, 6, 1569 (1987).

    CAS  Google Scholar 

  101. W. D. Jones and J. A. Maguire, Organometallics, 6, 1728 (1987).

    CAS  Google Scholar 

  102. R. L. Williamson and M. B. Hall, J. Am. Chem. Soc., 110, 4428 (1988).

    CAS  Google Scholar 

  103. G. Erker, R. Zwettler, C. Kruger, R. Schlund, I. Hyla-Kryspin, and R. Gleiter, J. Organomet. Chem., 346, C15 (1988).

    CAS  Google Scholar 

  104. A. D. Horton, M. J. Mays, and M. McPartlin, J. Chem. Soc., Chem. Commun., 424 (1987).

    Google Scholar 

  105. A. Albinati, C. G. Anklin, F. Ganazzoli, H. Ruegg, and P. S. Pregosin, Inorg. Chem., 26, 503 (1987).

    CAS  Google Scholar 

  106. A. Albinati, C. Arz, and P. S. Pregosin, Inorg. Chem., 26, 508 (1987).

    CAS  Google Scholar 

  107. F.Bouachir, B. Chaudret, F. Dahan, and I. Tkatchenko, New J. Chem., 11, 527 (1987).

    CAS  Google Scholar 

  108. B. Buchmann, U.Piantini, W. von Philipsborn, and A. Salzer, Helv. Chim. Acm, 70, 1487 (1987).

    CAS  Google Scholar 

  109. J. R. Bleeke, J. J. Kotyk, D. A. More, and D. J. Rauscher, J. Am. Chem. Soc., 109,417 (1987).

    CAS  Google Scholar 

  110. C. Schulze, H. Schwarz, D. A. Peake, and M. L. Gross, J. Am. Chem. Soc., 109,2368 (1987).

    CAS  Google Scholar 

  111. C. Schulze, and H. Schwarz, J. Am. Chem. Soc., 110, 67 (1988).

    CAS  Google Scholar 

  112. C. Schulze, T. Weiske, and H. Schwarz, Organometallics, 7, 898 (1988).

    CAS  Google Scholar 

  113. K. Eller, C. B. Lebrilla, T. Drewello, and H. Schwarz, J. Am. Chem. Soc., 110, 3068 (1988).

    CAS  Google Scholar 

  114. C. B. Lebrilla, T. Drewello, and H. Schwan, Organometallics, 6, 2450 (1987).

    CAS  Google Scholar 

  115. C. B. Lebrilla, T. Drewello, and H. Schwarz, Organometallics, 6, 2268 (1987).

    CAS  Google Scholar 

  116. S. L. Buchwald and R. B. Nielsen, J. Am. Chem. Soc., 110, 3171 (1988).

    CAS  Google Scholar 

  117. L. R. Chamberlain, J. L. Kerschner, A. P. Rothwell, I. P. Rothwell, and J. C. Huffman, J. Am. Chem. Soc., 109, 6471 (1987).

    CAS  Google Scholar 

  118. A. D. Ryabov, Inorg. Chem., 26, 1252 (1987).

    CAS  Google Scholar 

  119. T. P.Kee, V. C. Gibson, and W. Clegg, J. Organomet. Chem., 325, C14 (1987).

    CAS  Google Scholar 

  120. M. C. Navarro-Ranninger, A. Alvarez-Valdes, M. J. Camazon, J. Roman, and R. Lozano, J. Organomet. Chem., 331, 107 (1987).

    CAS  Google Scholar 

  121. A. Suarez, J. M. Vila, M. T. Pereira, E. Gayoso, and M. Gayoso, J. Organomet. Chem., 335, 359 (1987).

    CAS  Google Scholar 

  122. R. C. Davis, T. J. Grinter, D. Leaver, R. M. O’Neil, and G. A. Thomsom, J. Chem. Res. (S), 280 (1987).

    Google Scholar 

  123. J. L. Kerschner, P. E. Fanwick, and I. P. Rothwell, J. Am. Chem. Soc., 109, 5840 (1987).

    CAS  Google Scholar 

  124. Y. Fuchita, M. Nakashima, K. Hiraki, M. Kawatani, and K. Ohnuma, J. Chem. Soc., Dalton Trans., 785 (1988).

    Google Scholar 

  125. E. C. Alyea and J. Malito, J. Organomet. Chem., 340, 119 (1988).

    CAS  Google Scholar 

  126. A. A. H. van der Zeijden, G. van Koten, R. Luijk, K. Vrieze, C. Slob, H. Krabbendam, and A. L. Spek, Inorg. Chem., 27, 1014 (1988).

    Google Scholar 

  127. M. Nonoyama, Inorg. Chim. Acta, 145, 53 (1988).

    CAS  Google Scholar 

  128. F. A. Cotton and K. R. Dunbar, J. Am. Chem. Soc., 109, 2199 (1987).

    CAS  Google Scholar 

  129. F. A. Cotton and K. R. Dunbar, J. Am. Chem. Soc., 109, 3142 (1987).

    CAS  Google Scholar 

  130. F. Barcelo, F. A. Cotton, P. Lahuerta, M. Sanau, W. Schwotzer, and M. A. Ubeda, Organometallics, 6, 1105 (1987).

    CAS  Google Scholar 

  131. F. A. Cotton and R. Poli, Organometallics, 6, 1743 (1987).

    CAS  Google Scholar 

  132. S.-L. Soong, J. H. Hain, M. Millar, and S. A. Koch, Organometallics, 7, 556 (1988).

    CAS  Google Scholar 

  133. F. Barcelo, P. Lahuerta, M. A. Ubeda, C. Foces-Foces, F. H. Cano, and M. Martinez-Ripoll, Organometallics, 7, 584 (1988).

    CAS  Google Scholar 

  134. F. A. Cotton, F. Barcelo, P. Lahuerta, R. Llusar, J. Paya, and M. A. Ubeda, Inorg. Chem., 27, 1010 (1988).

    CAS  Google Scholar 

  135. L. Manojlovic-Muir, D. A. Brandes, and R. J. Puddephatt, J. Organomet. Chem., 332, 201 (1987).

    CAS  Google Scholar 

  136. A. J. Deeming, K. I. Hardcastle, and S. E. Kabir, J. Chem. Soc., Dalton Trans., 827 (1988).

    Google Scholar 

  137. R. Cordone and H. Taube, J. Am. Chem. Soc., 109, 8101 (1987).

    CAS  Google Scholar 

  138. A. R. Bulls, W. P. Schaefer, M. Serfas, and J. E. Bercaw, Organometallics, 6, 1219 (1987).

    CAS  Google Scholar 

  139. L. E. Schock, C. P. Brock, and T. J. Marks, Organometallics, 6, 232 (1987).

    CAS  Google Scholar 

  140. N. Lugan, G. Lavigne, and J.-J. Bonnet, Inorg. Chem., 26, 585 (1987).

    CAS  Google Scholar 

  141. R. D. Adams, J. E. Babin, and H.S. Kim, J. Am. Chem. Soc., 109, 1414 (1987).

    CAS  Google Scholar 

  142. R. D. Adams, J. E. Babin, and H.-S. Kim, Organometallics, 6, 749 (1987).

    CAS  Google Scholar 

  143. M. R. Churchill, T. S. Janik, T. P. Duggan, and J. B. Keister, Organometallics, 6, 799 (1987).

    CAS  Google Scholar 

  144. T. K. Dutta, J. C. Vites, G. B. Jacobsen, and T. P. Fehlner, Organometallics, 6, 842 (1987).

    CAS  Google Scholar 

  145. T. K. Dutta, X. Meng, J. C. Vites, and T. P. Fehlner, Organometallics, 6, 2191 (1987).

    CAS  Google Scholar 

  146. R. D. Adams and J. E. Babin, Organometallics, 6, 2236 (1987).

    CAS  Google Scholar 

  147. R. D. Adams and J. E. Babin, J. Am. Chem. Soc., 109, 6872 (1987).

    CAS  Google Scholar 

  148. M. T. Jones and R. N. McDonald, Organometallics, 7, 1221 (1988).

    CAS  Google Scholar 

  149. J. D. Scott, M. Crespo, C. M. Anderson, and R. J. Puddephatt, Organometallics, 6, 1772 (1987).

    CAS  Google Scholar 

  150. G. J. Arsenault, M. Crespo, and R. J. Puddephatt, Organometallics, 6, 2255 (1987).

    CAS  Google Scholar 

  151. M. Crespo and R. J. Puddephatt, Organometallics, 6, 2548 (1987).

    CAS  Google Scholar 

  152. P. K. Monaghan and R. J. Puddephatt, J. Chem. Soc., Dalton Trans., 595 (1988).

    Google Scholar 

  153. S. S. Basson, J. G. Leipoldt, A. Roodt, and J. A. Venter, Inorg. Chim. Acta, 128, 31 (1987).

    CAS  Google Scholar 

  154. G. J. van Zyl, G. J. Lamprecht, J. G. Leipoldt, and T. W. Swaddle, Inorg. Chim. Acta, 143, 223 (1988).

    Google Scholar 

  155. J. G. Leipoldt, E. C. Steynberg, and R. van Eldik, Inorg. Chem., 26, 3068 (1987).

    CAS  Google Scholar 

  156. K.-T. Aye, D. Colpitts, G. Ferguson, and R. J. Puddephatt, Organometallics, 7, 1454 (1988).

    CAS  Google Scholar 

  157. P. K. Byers, A. J. Canty, M. Crespo, R. J. Puddephatt, and J. D. Scott, Organometallics, 7, 1363 (1988).

    CAS  Google Scholar 

  158. M. R. Churchill, J. C. Fettinger, T. S. Janik, W. M. Rees, J. S. Thompson, S. Tomaszewski, and J. D. Atwood, J. Organomet. Chem., 323, 233 (1987).

    CAS  Google Scholar 

  159. R. Sustmann and G. Kopp, J. Organomet. Chem., 347, 325 (1988).

    Google Scholar 

  160. F. Ozawa, T. Hidaka, T. Yamamoto, and A. Yamamoto, J. Organomet. Chem., 330, 253 (1987).

    CAS  Google Scholar 

  161. M. J. Burk, B. Segmuller, and R. H. Crabtree, Organometallics, 6, 2241 (1987).

    CAS  Google Scholar 

  162. K. Ishikawa, S. Fukuzumi, and T. Tanaka, Bull. Chem. Soc. Jpn., 60, 563 (1987).

    CAS  Google Scholar 

  163. C. R. Randall, M. E. Silver, and J. A. Ibers, Inorg. Chim. Acta, 128, 39 (1987).

    CAS  Google Scholar 

  164. D. M. Roundhill, M. K. Dickson, and S. J. Atherton, J. Organornet. Chem., 335, 413 (1987).

    CAS  Google Scholar 

  165. M. D. Fryzuk, P. A. MacNeil, and N. T. McManus, Organometallics, 6, 882 (1987).

    CAS  Google Scholar 

  166. R. G. Finke, S. R. Keenan, D. A. Schiraldi, and P. L. Watson, Organometallics, 6, 1356 (1987).

    CAS  Google Scholar 

  167. T. G. Richmond, M. A. King, E. P. Kelson, and A. M. Arif, Organometallics, 6, 1995 (1987).

    CAS  Google Scholar 

  168. T. G. Richmond, C. E. Osterberg, and A. M. Arif, J. Am. Chem. Soc., 109, 8091 (1987).

    CAS  Google Scholar 

  169. J. C. Green, M. L. H. Green, D. O’Hare, R. R. Watson, and J. A. Bandy, J. Chem. Soc., Dalton Trans., 391 (1987).

    Google Scholar 

  170. G. M. Smith, M. Sabat, and T. J. Marks, J. Am. Chem. Soc., 109, 1854 (1987).

    CAS  Google Scholar 

  171. C. J. Burns and R. A.Andersen, J. Am. Chem. Soc., 109, 5853 (1987).

    CAS  Google Scholar 

  172. E. N. Jacobsen, K. I. Goldberg, and R. G. Bergman, J. Am. Chem. Soc., 110, 3706 (1988).

    CAS  Google Scholar 

  173. R. S. Sternal, M. Sabat, and T. J. Marks, J. Am. Chem. Soc., 109, 7920 (1987).

    CAS  Google Scholar 

  174. S. M. Baxter, G. S. Ferguson, and P. T. Wolczanski, J. Am. Chem. Soc., 110, 4231 (1988).

    CAS  Google Scholar 

  175. M. A. Ciriano, F. Viguri, L. A. Oro, A. Tiripicchio, and M. Tiripicchio-Camellini, Angew. Chem., Int. Ed. Engl., 26, 444 (1987).

    Google Scholar 

  176. M. A. Bennett, S. K. Bhargava, K. D. Griffiths, and G. B. Robertson, Angew. Chem., Int. Ed. Engl., 26, 260 (1987).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Imperial Chemical Industries P.L.C., Billingham, Cleveland, UK

    M. V. Twigg

Authors
  1. M. V. Twigg
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Imperial Chemical Industries P.L.C., Billingham, Cleveland, UK

    M. V. Twigg

Rights and permissions

Reprints and permissions

Copyright information

© 1989 Plenum Press, New York

About this chapter

Cite this chapter

Twigg, M.V. (1989). Metal—Alkyl and Metal—Hydride Bond Formation and Fission. In: Twigg, M.V. (eds) Mechanisms of Inorganic and Organometallic Reactions. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0827-0_11

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-0827-0_11

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-8102-3

  • Online ISBN: 978-1-4613-0827-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation