Abstract
The results of molecular dynamics simulations of Lennard-Jones systems in the meta-stable supercooled state are presented. The variation of various time-correlation functions and transport coefficients with temperature is discussed and compared with recently developed mode-coupling theories. The temperature dependence of the viscosity and coefficient of self-diffusion is well described by a power law with an exponent μ = 1.8, in close agreement with the prediction of mode coupling models.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
J. Jäckle, Rep. Prog. Phys. 49, 171 (1986)
M. Klinger, Phys. Rep. 165, 275 (1988)
E. Leutheusser, Phys. Rev. A29, 2765 (1984)
U. Bengtzelius, W. Götze and A. Sjölander, J. Phys. C17, 5915 (1984)
W. Götze, Z. Phys. B60, 195 (1985)
W. Götze and L. Sjögren, Z. Phys. 865, 415 (1987)
W. Knaak, F. Mezei and B. Farago, Europhys. Lett. 7, 529 (1988)
S.P. Das, G.F. Mazenko, S. Ramaswamy and J. Toner, Phys. Rev. Lett. 54, 118 (1985)
S.P. Das and G.F. Mazenko, Phys. Rev. A34, 2265 (1986)
U. Bengtzelius, Phys. Rev. A34, 5059 (1986) A33, 3433 (1986)
J.R. Fox and H.C. Andersen, J. Phys. Chem. 88, 4019 (1984)
J.J. Ullo and H.C. Andersen, J. Phys. Chem. 88, 4019 (1984)
C.A. Angell, J.H.R. Clarke and L.V. Woodcock, Adv. Chem. Phys. 48, 397 (1981)
A. Rahman, M.J. Mandell and J.P. McTague, J. Chem. Phys. 64, 1564 (1976)
R. D. Mountain, and D. Thirumalai, Phys. Rev. A36, 3300 (1987)
M.J. D. Brakkee and S.W. de Leeuw, Proc. of the International Workshop on “Static and Dynamic Properties of Liquids”, June 27 — July 4 1988, Dubrovnik. M. Davidovic, Ed; Springer Verlag (in press)
M.J.D. Brakkee and S.W. de Leeuw, submitted for publication.
S. Nosé, J. Chem. Phys. 81, 511 (1984)
H.C. Andersen, J. Chem. Phys. 72, 2384 (1980)
G.P. Johari, A. Hallbrucker and E. Mayer, J. Phys. Chem. 93, 2648 (1988)
R. Zallen, “Physics of Amorphous Solids”, J. Whiley, New York, 1983, Chapter 2.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1990 Plenum Press, New York
About this chapter
Cite this chapter
de Leeuw, S.W., Brakkee, M.J.D. (1990). Structure and Dynamics of Supercooled Fluids. In: Aguilera-Navarro, V.C. (eds) Condensed Matter Theories. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0605-4_10
Download citation
DOI: https://doi.org/10.1007/978-1-4613-0605-4_10
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4612-7888-7
Online ISBN: 978-1-4613-0605-4
eBook Packages: Springer Book Archive