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Brillouin Zone Concept and Crystal Symmetry of Intermetallic High Pressure Phases

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Stability of Materials

Part of the book series: NATO ASI Series ((NSSB,volume 355))

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Abstract

Crystal structure of some intermetallic phases is known to be controlled by a number of valence electrons in an alloy. Phase stability was explained by Fermi sphere - Brillouin zone interaction [1-3]. The sequence of electron phases in the Cu-Zn alloy along the valence concentration 1.35 → 1.5 → 1.62 → 1.75 is as follows:

$$ \alpha (fcc) \to \beta (bcc) \to \gamma (complex cubic) \to \varepsilon (hcp). $$

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© 1996 Plenum Press, New York

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Degtyareva, V.F. (1996). Brillouin Zone Concept and Crystal Symmetry of Intermetallic High Pressure Phases. In: Gonis, A., Turchi, P.E.A., Kudrnovský, J. (eds) Stability of Materials. NATO ASI Series, vol 355. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0385-5_41

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  • DOI: https://doi.org/10.1007/978-1-4613-0385-5_41

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-8028-3

  • Online ISBN: 978-1-4613-0385-5

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