Abstract
The use of electrochemistry to activate and precisely tune heterogeneous catalytic processes is a new development1-7 which originally emerged due to the existence of solid electrolytes. Depending on their composition, these specific anionic or cationic conductor materials exhibit substantial electrical conductivity at temperatures between 25 and 1000°C. Within this broad temperature range, which covers practically all heterogeneous catalytic reactions, solid electrolytes can be used as reversible in situ promoter donors or poison acceptors to affect the catalytic activity and product selectivity of metals deposited on solid electrolytes in a very pronounced, reversible, and, to some extent, predictable manner.
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References
C. G. Vayenasfn, S. Bebelis, and S. Neophytides, J. Phys. Chem. 92 (1988) 5083.
S. Bebelis and C. G. Vayenas, J. Catal 118 (1989) 125.
C. G. Vayenas, S. Bebelis, and S. Ladas, Nature (London) 343 (1990) 625.
C. G. Vayenas, S. Bebelis, I. V Yentekakis, and H.-G. Lintz, Catal. Today 11 (1992) 303.
J. Pritchard, Nature (London) 343 (1990) 592.
J. O’M. Bockris and Z. S. Minevski, Elektrochim. Acta 39 (1994) 1471.
I. V. Yentekakis, G. Moggridge, C. G. Vayenas, and R. M. Lambert, J. Catal 146 (1994) 293.
S. Neophytides, D. Tsiplakides, P. Stonehart, M. M. Jaksic, and C. G. Vayenas, Nature (London) 370 (1994) 45.
C. Wagner, Adv. Catal 21 (1970) 323.
C. G. Vayenas and H. M. Saltsburg, J. Catal. 57 (1979) 296.
S. Pancharatnam, R. A. Huggins, and D. M. Mason, J. Electrochem. Soc. 122 (1975) 869.
C. G. Vayenas and R. D. Fair, Science 208 (1980) 593.
M. Stoukides and C. G. Vayenas, J. Catal 70(1981) 137; J. Electrochem. Soc. 131 (1984) 839.
I. V. Yentekakis and C. G. Vayenas, J. Catal 111 (1988) 170.
T. I. Politova, V. A. Sobyanin, and V. D. Belyaev, React. Kinet. Catal. Lett. 41 (1990) 321.
A. Marina and V. A. Sobyanin, Catal Lett. 13 (1992) 61.
C. A. Cavalca, G. Larsen, C. G. Vayenas, and G. L. Haller, J. Phys. Chem. 97 (1993) 6115.
L. Basini, C. A. Cavalca and G. L. Haller, J. Phys. Chem. 98 (1994) 10853; C. A. Cavalca, Ph.D. Thesis, Yale Univ. (1995).
I. Harkness and R. M. Lambert, J. Catal 152 (1995) 211.
P. C. Chiang, D. Eng, and M. Stoukides, J. Catal. 139 (1993) 683.
E. Varkaraki, J. Nicole, E. Plattner, Ch. Comninellis, and C. G. Vayenas, J. of Applied Electrochem. 25(1995) 978.
C. G. Vayenas, S. Bebelis, S. Neophytides, and I. V. Yentekakis, Appl. Phys. (A) 49 (1989) 95.
C. G. Vayenas, S. Bebelis, I. V. Yentekakis, P. Tsiakaras, and H. Karasali, Platinum Met. Rev. 34(3) (1990) 122.
C. G. Vayenas, S. Bebelis, and C. Kyriazis, Chemtech 21 (1991) 500.
C. G. Vayenas, in Elementary Reaction Steps in Heterogeneous Catalysis, Ed. by R. W. Joyner and R. A. van Santen, Kluwer Academic Publishers, Dordrecht, The Netherlands, 1993, pp. 73–92.
C. G. Vayenas, S. Bebelis, I. V. Yentekakis, Ch. Karavasilis, and Y. Jiang, Solid State Ionics 72(1994) 321.
C. G. Vayenas, S. Ladas, S. Bebelis, I. V. Yentekakis, S. Neophytides, Y. Jiang, Ch. Karavasilis, and C. Pliangos, Electrochim. Acta 39 (1994) 1849.
C. G. Vayenas, Solid State Ionics 28–30 (1988) 1521.
M. Stoukides, Ind. Eng. Chem. Res. 27 (1988) 1745.
P. J. Gellings, H. S. A. Koopmans, and A. J. Burgraaf, Appl. Catal 39 (1988) 1.
H.-G. Lintz and C. G. Vayenas, Angew. Chem. 101 (1989) 725; Angew. Chem., Int. Ed. Engl. 28 (1989) 708.
C. Wagner and W. Schottky, Z Phys. Chem. Bll (1930) 163.
H. Rickert, Electrochemistry of Solids, Springer-Verlag, Berlin, 1982.
G. C. Farrington, B. Dunn, and J. C. Thomas, in High Conductivity Solid Ionic Conductors, Ed. by T. Takahashi, World Scientific, Singapore, 1989.
E. C. Subbarao and H. S. Maiti, Solid State Ionics 11 (1984) 317.
D. F. Schriver and G. C. Farrington, Chem. Eng. News 1985 (May 20)
W. Göpel, Sensors and Actuators B 18–19 (1994) 1.1
F. Grosz, in Proceedings of the 2nd International Symposium on Solid Oxide Fuel Cells, Athens, Greece, CEC Publ., Luxembourg, 1991, pp. 7–24.
H. Iwahara, T. Esaka, H. Uchida, and N. Maeda, Solid State Ionics 3–4 (1981) 359.
S. Neophytides and C. G. Vayenas, J. Catal 118 (1989) 147.
C. G. Vayenas and S. Neophytides, J. Catal 127 (1991) 645.
C. G. Vayenas, S. Bebelis, and M. Despotopoulou, J. Catal 128 (1991) 415.
S. Bebelis and C. G. Vayenas, J. Catal 138 (1992) 588; 138 (1992) 570.
P. Tsiakaras and C. G. Vayenas, J. Catal 140 (1993) 53.
P. Tsiakaras and C. G. Vayenas, J. Catal 144 (1993) 333.
C. G. Vayenas, A. Ioannides, and S. Bebelis, J. Catal 129 (1991) 67.
I. V. Yentekakis and S. Bebelis, J. Catal 137 (1992) 278.
C. Pliangos, I. V. Yentekakis, X. E. Verykios, and C. G. Vayenas, J. Catal 154 (1995) 124.
A. Kaloyannis and C. G. Vayenas, J. Catal, submitted.
Ch. Karavassilis, S. Bebelis, and C. G. Vayenas, J. Catal, submitted.
H. Karasali, S. Bebelis, and C. G. Vayenas, J. Catal manuscript in preparation.
S. Neophytides, S. Bebelis, and C. G. Vayenas, Proceedings of the 1st European Solid Oxide Fuel Cell Forum, Ed. U. Bossel, J. Kinzel Publ., Lucerne, Switzerland (1994), Vol 1, pp. 197–206.
A. Marina, V. A. Sobyanin, and V. D. Belyaev, Materials Sei and Engineering B13 (1992) 153.
A. Mar’ina, V. A. Sobyanin, V. D. Belyaev, and V. N. Parmon, Catal Today 13 (1992) 567.
S. Neophytides, D. Tsiplakides, O. Enea, M. M. Jaksic, and C. G. Vayenas, Electrochim. Acta, manuscript in preparation.
I. V. Yentekakis and C. G.Vayenas, J. Catal 149 (1994) 238.
N. A. Anastasijevic, H. Baltruschat, and J. Heitbaum, Electrochim. Acta 38 (1993) 1067.
C. G. Vayenas, C. Georgakis, J. N. Michaels, and J. Tormo, J. Catal. 67 (1981) 348.
S. Ladas, S. Bebelis, and C. G. Vayenas, Surf. Sei. 251/252 (1991) 1062–1069.
Y. Jiang, I. V. Yentekakis, and C. G. Vayenas, J. Catal. 148 (1994) 240.
B. C. H. Steele, in Electrode Processes in Solid State Ionics, Ed. by M. Kleitz and J. Dupuy, Reidel, Dordrecht, The Netherlands, 1976.
J. N. Michaels, C. G. Vayenas, and L. L. Hegedus, J. Electrochem. Soc. 133 (1985) 552.
S. C. Singhal and H. Iwahara, eds., Proceedings of the 3rd International Symposium on Solid Oxide Fuel Cells, Vol. 93–94, The Electrochemical Society, Pennington, New Jersey, 1993.
R. D. Fair and C. G. Vayenas, J. Electrochem. Soc. 127, (1980) 1478.
C. Sigal and C. G. Vayenas, Solid States Ionics 5 (1981) 567.
C. G. Vayenas, S. Bebelis, and C. C. Kyriazis, Chemtech 21 (1991) 422; 21 (1991) 500.
I. V. Yentekakis and C. G. Vayenas, J. Electrochem. Soc. 136 (1989) 996.
S. Neophytides and C. G. Vayenas, J. Electrochem. Soc. 137 (1990) 834.
Y. Jiang, I. V. Yentekakis, and C. G. Vayenas, Science 264 (1994) 1563.
N. Kiratzis and M. Stoukides, J. Electrochem. Soc. 134 (1987) 1925.
J. N. Michaels and C. G. Vayenas, J. Catal. 85 (1987) 477.
J. N. Michaels and C. G. Vayenas, J. Electrochem. Soc. 131 (1984) 2544.
R. DiCosimo, J. D. Burrington, and R. K. Grasselli, J. Catal. 102 (1986) 234.
E. J. L. Schouler, M. Kleitz, E. Forest, E. Fernandez, and P. Fabry, Solid State Ionics 3–4 (1981) 431.
T. M. Giir and R. A. Huggins, J. Electrochem. Soc. 126 (1979) 1067.
T. M. Giir and R. A. Huggins, Science 219 (1983) 967.
T. M. Giir and R. A. Huggins, J. Catal. 102 (1986) 443.
T. Hayakawa, T. Tsunoda, H. Orita, T. Kameyama, H. Takahashi, K. Takehira, and K. Fukuda, J. Chem. Soc. Jpn. Chem. Commun. 1986,961.
K. Otsuka, S. Yokoyama, and A. Morikawa, Chem. Lett. Chem. Soc. Jpn. 1985, 319.
S. Seimanides and M. Stoukides, J. Electrochem. Soc. 133 (1986) 1535.
K. Otsuka, K. Suga, and I. Yamanaka, Catal. Lett. 1 (1988) 423.
K. Otsuka, K. Suga, and I. Yamanaka, Chem. Lett. Jpn. 1988, 317.
V. D. Belyaev, O. V. Bazhan, V. A. Sobyanin, and V. N. Parmon, in New Developments in Selective Oxidation, Ed. by G. Centi and F. Trifiro, Elsevier, Amsterdam, 1990, p. 469.
D. Eng and M. Stoukides, Catal.-Rev.-Sci.-Eng. 33 (1991) 375.
D. Eng and M. Stoukides, J. Catal. 30 (1991) 306.
P. H. Chiang, D. Eng, and M. Stoukides, J. Electrochem. Soc. 138 (1991) Lll.
W. Dönitz and E. Erdle, Int. J. Hydrogen Energy 10 (1985) 291.
D. Eng and M. Stoukides, Catal. Lett. 9 (1991) 47.
P. Tsiakaras, Ph.D. Thesis, University of Patras, 1993.
D. Y. Wang and A. S. Nowick, J. Electrochem. Soc. 126 (1979) 1155.
D. Y. Wang and A. S. Nowick, J. Electrocliem. Soc. 126 (1979) 1166.
D. Y. Wang and A. S. Nowick, J. Electrochem. Soc. 128 (1981) 55.
E. J. L. Schouler and M. Kleitz, J. Electrochem. Soc. 134 (1987) 1045.
H. H. Hildenbrand and H.-G. Lintz, Catal. Today 9 (1991) 153.
H. Okamoto, G. Kawamura, and T. Kudo, J. Catal. 82 (1983) 322.
C. G. Vayenas, J. Catal. 90 (1984) 371.
J. Tafel, Z Phys. Chem. (Leipzig) 50 (1905) 641.
J. A. V. Butler, Trans. Faraday Soc. 19 (1924) 729.
T. Erdey-Gruz and M. Volmer, Z. Phys. Chem. (Leipzig)150 (1930) 203.
J. O’M. Bockris and A. K. N. Reddy, Modern Electrochemistry, Vol. 2, Plenum Press, New York, 1970.
J. O’M. Bockris and S. U. M. Khan, Surface Electrochemistry: A Molecular Level Approach, Plenum Press, New York, 1993.
J. S. Newman, Electrochemical Systems, Prentice-Hall, Englewood Cliffs, New Jersey, 1973.
M. Manton, Ph.D. Thesis, MIT, 1986.
C. G. Vayenas and J. N. Michaels, Surf Sei. 120 (1982) L405.
M. Peukert and H. P. Bonzel, Surf. Sei. 145 (1984) 239.
M. Peukert and H. Ibach, Surf. Sei. 136 (1983) 319.
Y. Jiang, A. Kaloyannis, and C. G. Vayenas, Electrochim. Acta38 (1993) 2533.
H. J. Reiss, J. Phys. Chem. 89 (1985) 3783.
H. J. Reiss, J. Electrochem. Soc. 135 (1988) 2476.
P. M. Gundry and F. C. Tompkins, in Experimental Methods in Catalyst Research, Ed. By R. B. Anderson, Academic Press, New York, 1968, pp. 100–168.
J. Hölzl and F. K. Schulte, in Solid Surface Physics, Ed. by G. Höhler, and E. Niekisch, Springer-Verlag, Berlin, 1979, pp. 1–150.
S. Trasatti, in Advances in Electrochemistry and Electrochemical Engineering, Vol. 10, Ed. by H. Gerischer and C. W. Tobias, John Wiley & Sons, New York, 1977.
H. Amariglio, J. Chim. Phys. 64 (1967) 1391.
N. W. Ashcroft and N. D. Mermin, in Solid State Physics, Hott-Saunders Intl. Eds., Philadelphia, USA, 1976, pp. 354–371.
C. Lamy, in Propriétés Electriques des Interfaces Chargées, Ed. by D. Schuhmann, Masson, Paris, 1978, pp. 210–241.
W. Schröder and J. Hölzl, Solid State Commun. 24 (1977) 777.
C. A. Papageorgopoulos and J. M. Chen, Surf. Sei. 52 (1975) 40.
H. P. Bonzel, Surf. Sei. Rep. 8 (1987) 43.
D. Heskett, Surf. Sei. 199 (1988) 67.
T. Aruga and Y. Murata, Prog. Surf. Sei. 31 (1989) 61.
K. J. Uram, L. Ng, and J. R. Yates, Jr., Surf. Sei. 177 (1986) 253.
T. Arakawa, A. Saito, and J. Shiokawa, Appl Surf. Sei. 16 (1983) 365.
T. Arakawa, A. Saito, and J. Shiokawa, Chem. Phys. Lett. 94 (1983) 250.
U. Vóhrer, Ph.D. Thesis, University of Tübingen, 1992.
S. Ladas, S. Kennou, S. Bebelis, and C. G. Vayenas, J. Phys. Chem. 97 (1993) 8845.
I. V. Yentekakis and C. G. Vayenas, manuscript in preparation.
M. Boudart and G. Djéga-Mariadassou, Kinetics of Heterogeneous Catalytic Reactions, Princeton University Press, Princeton, New Jersey, 1984.
Z. Xu, J. T. Yates, Jr., L. C. Wang, and H. J. Kreuzer, J. Chem. Phys. 96 (1991) 1628.
S. Neophytides and C. G. Vayenas, Ionics 1 (1995) 80; J. Phys. Chem. 1995, in press.
J. L. Falconer and R. J. Madix, Surf. Sei. 48 (1975) 393.
C. G. Vayenas, B. Lee, and J. N. Michaels, J. Catal66 (1980) 36.
V. A. Sobyanin, V. I. Sobolev, V. D. Belyaev, O. A. Mar’ina, A. K. Demin, and A. S. Lipilin, Catal Lett. 18 (1993)153.
V. A. Sobyanin and V. D. Belyaev, React. Kinet. Catal. Lett. 51(2) (1993) 373.
M. Boudart, J. Am. Chem. Soc. 74 (1952) 3556.
S. Cerny and V. Ponec, Catal Rev. 2 (1968) 249.
E. Shustorovich, J. Mol. Catal54 (1989) 307.
G. Pacchioni, F. Ilias, S. Neophytides, and CG. Vayenas, manuscript in preparation.
S. Neophytides, D. Tsiplakides, P. Stonehart, M. M. Jaksic, and C. G. Vayenas, Electrochim. Acta, submitted, 1995.
E. Cremer, Adv. Catal. 7 (1955) 75.
G.-M. Schwab, J. Catal. 84 (1983) 1.
S. Seimanides, P. Tsiakaras, X. E. Verykios, and C. G. Vayenas, Appl. Catal. 68 (1991) 41.
V D. Belyaev, V. A. Sobyanin, A. K. Demin, A. S. Lipilin, and V. A. Zapesotski, Mendeleev Commun. 1991, 53.
H. Karasali and C. G. Vayenas, Mater. Sei. Forum76 (1991) 171.
D. Lackey and P. A. King, J. Chem. Soc, Faraday Trans. 1 1987, 83.
I. V. Yentekakis, S. Neophytides, and C. G. Vayenas, J. Catal67 (1981) 348.
S. Ladas, R. Imbihl, and G. Eni, Surf. Sei. 219 (1989) 88.
Ch. Karavasilis, S. Bebelis, and C. G. Vayenas, Mater. Sei. Forum76 (1991) 175.
148Ch. Karavasilis, S. Bebelis, and C. G. Vayenas, J. Catal, submitted, 1995, in press.
R. A. Van Santen and H. P. C. E. Kuipers, Adv. Catal. 35 (1987) 265.
R. B. Grant and R. M. Lambert, J. Catal92 (1985) 364.
H. Karasali, Ph.D. Thesis, University of Patras, 1994.
H. Alqahtany, P.-H. Chiang, D. Eng, M. Stoukides, and A. R. Robbat, Catal. Lett. 13 (1992) 289.
E. Lamy-Pitara, L. Bencharif, and J. Barbier, Appl Catal18 (1985) 117.
C. Pliangos, I. V. Yentekakis, X. E. Verykios, and C. G. Vayenas, J. Catal. 154 (1995) 124.
G. L. Haller and D. E. Resasco, Adv. Catal. 36 (1989) 173.
S. J. Tauster, S. C. Fung, and R. L. Garten, J. Am. Chem. Soc. 100 (1978) 170.
H. Baltruschat, N. A. Anastasijevic, M. Beltowska-Brzezinska, G. Hambitzer, and J. Heitbaum, Ber. Bunsenges. Phys. Chem. 94 (1990) 996.
S. Neophytides, D. Tsiplakides, P. Stonehart, M. Jaksic, and C. G. Vayenas, Electrochim. Acta, submitted, 1995.
B. E. Conway, in Electrodes of Conductive Metallic Oxides, Ed. by S. Trassatti, Elsevier, Amsterdam, 1981, Chapter 9.
B. E. Conway and B. K. Tilak, Adv. Catal. 38 (1992) 1.
E. Plattner and Ch. Comninellis, in Process Technologies for Water Treatment, Ed. by S. Stucki, Plenum Press, New York, 1988, pp. 205–217.
D. L. Rath and D. M. Kolb, Surface Science109 (1981) 641.
E. R. Kotz, H. Neff, and K. Müller, J. Electroanal Chem. 215 (1986) 33.
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Vayenas, C.G., Jaksic, M.M., Bebelis, S.I., Neophytides, S.G. (1996). The Electrochemical Activation of Catalytic Reactions. In: Bockris, J.O., Conway, B.E., White, R.E. (eds) Modern Aspects of Electrochemistry. Modern Aspects of Electrochemistry, vol 29. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0327-5_2
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