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Laser-Excited Atomic Fluorescence Spectrometry

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Lasers in Chemical Analysis

Abstract

It is quite appropriate that lasers should be utilized for atomic fluorescence spectrometry (AFS). Both share similar times of origin and development. During the 1960s, the laser was developed as a light source and AFS as a spectrometric technique. In 1971, with the advent of commercially available tunable dye lasers, laser-excited atomic fluorescence spectrometry (LEAFS) had its beginning as an analytical method (1, 2). Researchers had been looking for a high-intensity excitation source, and tunable dye lasers were found to provide high spectral irradiance at atomic transitions. LEAFS has been develped to be the method of choice for single-element trace analysis where low detection limits and large linear dynamic ranges are desired, and where spectral interferences arising from concomitant sample species need to be eliminated for accurate results. LEAFS features also make it a strong candidate as a sequential multielement analysis technique. LEAFS can make important contributions in the areas of forensic, clinical—biological, and environmental analysis, as well as in areas such as combustion diagnostics. A considerable amount of applications research is expected within the next few years.

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References

  1. M. B. Denton and H. V. Malmstadt, Appl. Phys. Lett. 18, 485 (1971).

    Article  CAS  Google Scholar 

  2. L. M. Fraser and J. D. Winefordner, Anal. Chem. 43, 1693 (1971).

    Article  CAS  Google Scholar 

  3. N. Omenetto and J. D. Winefordner, Prog. Analyt. Atom. Spectrosc. 2, 1 (1979).

    CAS  Google Scholar 

  4. S. J. Weeks, H. Haraguchi, and J. D. Winefordner, Anal. Chem. 50, 360 (1978).

    Article  CAS  Google Scholar 

  5. N. Omenetto, G. D. Boutilier, S. J. Weeks, B. W. Smith, and J. D. Winefordner, Anal. Chem. 49, 1076 (1977).

    Article  CAS  Google Scholar 

  6. N. Omenetto and J. D. Winefordner, Appl. Spectrosc. 26, 555 (1972).

    Article  CAS  Google Scholar 

  7. N. Omenetto, N. N. Hatch, L. M. Fraser, and J. D. Winefordner, Spectrochim, Acta 28B, 65 (1973).

    Article  CAS  Google Scholar 

  8. D. R. de Olivares, PhD Thesis, Indiana University, Bloomington, IN, 1976.

    Google Scholar 

  9. K. Fujiwara, N. Omenetto, J. B. Bradshaw, J. N. Bower, S. Nikdel, and J. D. Winefordner, Spectochim. Acta 34B, 317 (1979).

    Article  Google Scholar 

  10. S. J. Weeks, H. Haraguchi, and J. D. Winefordner, J. Quant. Spectrosc. Radiat. Transfer 19, 633 (1978).

    Article  CAS  Google Scholar 

  11. N. Omenetto, J. Bower, J. Bradshaw, C. A. Van Dijk, and J. D. Winefordner, J. Quant. Spectrosc. Radiat. Transfer, 24, 147 (1980).

    Article  CAS  Google Scholar 

  12. G. D. Boutilier, M. B. Blackburn, J. M. Mermet, S. J. Weeks, H. Haraguchi, J. D. Winefordner, and N. Omenetto, Appl. Opt. 17, 229 (1978).

    Google Scholar 

  13. D. R. de Olivares and G. M. Hieftje, Spectrochim. Acta 33B, 79 (1978).

    Article  Google Scholar 

  14. N. Omenetto and J. D. Winefordner, in Analytical Laser Spectroscopy, N. Omenetto, ed., Wiley, New York, 1979, Chapter 4.

    Google Scholar 

  15. R. A. Van Calcar, M. J. M. Van de Ven, B. K. Van Uitert, K. J. Biewenga, Tj. Hollander, and C. Th. J. Alemade, J. Quant. Spectrosc. Radiat. Transfer 21, 11 (1979).

    Article  Google Scholar 

  16. S. J. Weeks, PhD Thesis, University of Florida, Gainesville, Fl. 1977.

    Google Scholar 

  17. J. W. Daily, Appl. Opt. 17, 225 (1978).

    Article  CAS  Google Scholar 

  18. M. S. Epstein, J. Bradshaw, S. Bayer, J. Bower, E. Voigtman, and J. D. Winefordner, Appl. Spectrosc. 34, 372 (1980).

    Article  CAS  Google Scholar 

  19. M. S. Epstein, S. Bayer, J. Bradshaw, E. Voightman, and J. D. Winefordner, Spectrochim. Acta 35B, 233 (1980).

    Article  Google Scholar 

  20. R. E. Setchell, paper number WSS/CI 74-6, presented at the Combustion Institute Spring Meeting, Pullman, Washington, May 6–7, 1974.

    Google Scholar 

  21. J. Bradshaw, Univ. of Florida, Gainesville, Fla., personal communication.

    Google Scholar 

  22. J. M. Harris, F. E., Lytle, and T. C. McCain, Anal. Chem. 43, 2095 (1976).

    Article  Google Scholar 

  23. J. N. Bower, J. Bradshaw, J. J. Horvath, and J. D. Winefordner, Univ. of Florida, Gainesville, Fla., unpublished work.

    Google Scholar 

  24. S. J. Weeks, J. C. Travis, and J. R. De Voe, paper presented at the Sixth Annual Meeting of the Federation of Analytical Chemistry and Spectroscopy, Sept. 16–21, 1979, Philadelphia, Penn.

    Google Scholar 

  25. D. J. Johnson, F. W. Plankey, and J. D. Winefordner, Anal Chem. 47, 1739 (1975).

    Article  CAS  Google Scholar 

  26. M. S. Epstein, S. Nikdel, J. D. Bradshaw, M. A. Kosinski, J. N. Bower, and J. D. Winefordner, Anal Chimica Acta, 113, 221 (1980).

    Article  CAS  Google Scholar 

  27. J. D. Winefordner, in New Applications of Lasers to Chemistry, G. M. Hieftje, ed., American Chemical Society, Washington, DC, 1978, Chapter 4.

    Google Scholar 

  28. M. B. Blackburn, J. M. Mermet, G. D. Boutilier, and J. D. Winefordner, Appl. Opt. 18, 1804 (1979).

    Article  CAS  Google Scholar 

  29. J. Bradshaw, J. Bower, S. Weeks, K. Fujiwara, N. Omenetto, H. Haraguchi, and J. D. Winefordner, Proceedings of the 10th Materials Research Symposium on Characterization of High Temperature Vapors and Gases, NBS, Washington, DC, 1978.

    Google Scholar 

  30. N. Omenetto, S. Nikdel, R. D. Reeves, J. Bradshaw, J. Bower, and J. D. Winefordner, Spectrochim. Acta 35B, 507 (1980).

    Article  Google Scholar 

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Weeks, S.J., Winefordner, J.D. (1981). Laser-Excited Atomic Fluorescence Spectrometry. In: Hieftje, G.M., Travis, J.C., Lytle, F.E. (eds) Lasers in Chemical Analysis. Contemporary Instrumentation and Analysis. Humana Press. https://doi.org/10.1007/978-1-4612-6009-7_8

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  • DOI: https://doi.org/10.1007/978-1-4612-6009-7_8

  • Publisher Name: Humana Press

  • Print ISBN: 978-1-4612-6011-0

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