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Geospeedometry: An Extension of Geothermometry

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Kinetics and Equilibrium in Mineral Reactions

Part of the book series: Advances in Physical Geochemistry ((PHYSICAL GEOCHE,volume 3))

Abstract

One of the basic aims of petrology is to relate observed mineral assemblages to their previous temperature-pressure history. To assess the previous thermal history, we have relied on an understanding of thermodynamics and phase equilibria. The assumption is made that the various minerals and their chemical compositions measured today will reveal a temperature and pressure which are geologically significant. This procedure is quite valid if equilibrium is achieved and preserved over significant portions of the mineral assemblage. However, in this latter case, by the very nature of equilibrium, effects of any previous or posterior processes are completely lost. An important point is that, by the use of thermodynamics, the dynamics or history of a rock is immediately subjugated to a secondary role.

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References

  • Adams, G. E., and Bishop, F. C. (1982) Experimental investigation of Ca-Mg exchange between olivine, orthopyroxene, and clinopyroxene: potential for geobarometry, Earth Planet. Sci. Lett. 57, 241–250.

    Article  Google Scholar 

  • Anderson, D. E. (1981) Diffusion in electrolyte mixtures, in Kinetics of Geochemical Processes, vol. 8, Reviews in Mineralogy, edited by A. C. Lasaga and R. J. Kirkpatrick, Ch. 6., pp. 211–260, Min. Soc. Amer., Washington, D.C.

    Google Scholar 

  • Bishop, F. C. (1980) The distribution of Fe2+ and Mg between coexisting ilmenite and pyroxene with applications to geothermometry, Amer. J. Sci. 280, 46–77.

    Article  Google Scholar 

  • Bottinga, I., and Allegre, C. (1976) Geophysical, petrological and geochemical models of the oceanic lithosphere. Tectonophysics, 32, 9–59.

    Article  Google Scholar 

  • Brady, J. B., and McCallister, R. H. (1983) Diffusion data for clinopyroxenes from homogenization and self-diffusion experiments, Amer. Mineral., 68, 95–105.

    Google Scholar 

  • Buening, D. K., and Buseck, P. R. (1973) Fe-Mg lattice diffusion in olivine, J. Geophys. Res. 78, 6852–6861.

    Article  Google Scholar 

  • Carswell, D. A., and Gibb, F. G. F. (1980) The equilibration conditions and petrogenesis of European crustal garnet lherzolites, Lithos 13, 19–29.

    Article  Google Scholar 

  • Dahl, P. S. (1979) Comparative geothermometry based on major-element and oxygen isotope distributions in Precambrian metamorphic rocks from southwestern Montana, Amer. Mineral. 64, 1280–1293.

    Google Scholar 

  • Dahl, P. S. (1980) The thermal-compositional dependence of Fe2+-Mg distributions between coexisting garnet and pyroxene: Applications to geothermometry, Amer. Mineral. 65, 854–866.

    Google Scholar 

  • Dodson, M. H. (1973) Closure temperature in cooling geochronological and petrological systems, Contrib. Mineral. Petrol. 40, 259–274.

    Article  Google Scholar 

  • Elphick, S. C., Ganguly, J., and Loomis, T. P. (1981) Experimental study of Fe-Mg interdiffusion in aluminumsilicate garnet, EOS (abstract), Trans. Amer. Geophys. Union 62(17), 411.

    Google Scholar 

  • Ferry, J. M. (1980) A comparative study of geothermometers and geobarometers in pelitic schists from south-central Maine, Amer. Mineral. 65, 720–732.

    Google Scholar 

  • Ferry, J. M., and Spear, F. S. (1978) Experimental calibration of the partitioning of Fe and Mg between biotite and garnet, Contrib. Mineral. Perol. 66, 113–117.

    Article  Google Scholar 

  • Freer, R. (1981) Diffusion in silicate minerals and glasses: a data digest and guide to the literature, Contrib. Mineral. Petrol. 76, 440–454.

    Article  Google Scholar 

  • Harte, B., and Freer, R. (1982) Diffusion data and their bearing on the interpretation of mantle nodules and the evolution of the mantle lithosphere, Terra Cognita 2(3), 273–275.

    Google Scholar 

  • Harte, B., Jackson, P. M., and Macintyre, R. M. (1981) Age of mineral equilibria in granulite facies nodules from kimberlites, Nature 291, 147–148.

    Article  Google Scholar 

  • Lasaga, A. C. (1979) Multicomponent exchange and diffusion in silicates, Geochim. Cosmochim. Acta 43, 455–469.

    Article  Google Scholar 

  • Lasaga, A. C. (1981) The atomistic basis of kinetics: defects in minerals, in Kinetics of Geochemical Processes, vol. 8, Reviews in Mineralogy, edited by A. C. Lasaga and R. J. Kirkpatrick, Ch. 7., pp. 261–320, Min. Soc. Amer., Washington, D.C.

    Google Scholar 

  • Lasaga, A. C., Richardson, S. M., and Holland, H. D. (1977) The mathematics of cation diffusion and exchange between silicate minerals during retrograde metamorphism, in Energetics of Geological Processes, edited by S. K. Saxena and S. Bhattachanji, pp. 353–388, Springer-Verlag, New York.

    Google Scholar 

  • Lindner, R., and Akerstrom, A. (1958) Z. Phys. Chem. 18, 303.

    Article  Google Scholar 

  • McCallister, R. H., Brady, J. B., and Mysen, B. O. (1978) Self-diffusion of Ca in diopside, Carnegie Institute Reports 78, 574–577.

    Google Scholar 

  • Mori, T., and Green, D. H. (1978) Laboratory duplication of phase equilibria observed in natural garnet lherzolites, J. Geol. 86, 83–97.

    Article  Google Scholar 

  • Navrotsky, A. (1976) Silicates and related minerals: Solid state chemistry and thermodynamics applied to geothermometry and geobarometry, Prog. in Solid State Chem. 11, 203–264.

    Article  Google Scholar 

  • Newton, R. C. (1977) Thermochemistry of garnets and aluminous pyroxenes in the CMAS system, in Thermodynamics in Geology, edited by D. G. Fraser, pp. 29–55, Reidel Pub. Co., Boston.

    Google Scholar 

  • Roheim, A., and Green, D. H. (1974) Experimental determination of the temperature and pressure dependence of the Fe-Mg partition coefficient for coexisting garnet and clinopyroxenes, Contrib. Mineral. Petrol. 48, 179–203.

    Article  Google Scholar 

  • Sanford, R. F. and Huebner, J. S. (1979) Reexamination of diffusion processes in 77115 and 77215 (abstract), in Lunar and Planetary Science, Vol. X, pp. 1052–1054, Lunar and Planetary Science Institute, Houston, Texas.

    Google Scholar 

  • Saxena, S. K. (1972) Retrieval of thermodynamic data from a study of inter-crystalline and intra-crystalline ion-exchange equilibrium, Amer. Mineral. 57, 1782–1800.

    Google Scholar 

  • Saxena, S. K. (1973) Thermodynamics of Rock-Forming Crystalline Solutions, Springer-Verlag, New York.

    Google Scholar 

  • Smith, D., and Roden, M. F. (1981) Geothermometry and kinetics in a two-spinel peri-dotite nodule, Colorado Plateau, Amer. Mineral. 66, 334–345.

    Google Scholar 

  • Thompson, A. B. (1976) Mineral reactions in pelitic rocks: II. Calculation of some P-T-X(Fe-Mg) phase relations, Amer. J. Sci. 276, 425–454.

    Article  Google Scholar 

  • Tracy, R. J., Robinson, P., and Thompson, A. B. (1976) Garnet composition and zoning in the determination of temperature and pressure of metamorphism, central Massachusetts, Amer. Mineral. 61, 762–775.

    Google Scholar 

  • Wood, B. J. (1977) Experimental determination of the mixing properties of solid solutions with particular reference to garnet and clinopyroxene solutions, in Thermodynamics in Geology, edited by D. G. Fraser, Ch. 2, pp. 11–28, Reidel Pub. Co., Boston.

    Google Scholar 

  • Wood, B. J., and Fraser, D. G. (1978) Elementary Thermodynamics for Geologists, Oxford Univ. Press, New York/London.

    Google Scholar 

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© 1983 Springer-Verlag New York Inc.

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Lasaga, A.C. (1983). Geospeedometry: An Extension of Geothermometry. In: Saxena, S.K. (eds) Kinetics and Equilibrium in Mineral Reactions. Advances in Physical Geochemistry, vol 3. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-5587-1_3

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  • DOI: https://doi.org/10.1007/978-1-4612-5587-1_3

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4612-5589-5

  • Online ISBN: 978-1-4612-5587-1

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