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Stereospecificity of Heterogeneous Ziegler-Natta Catalysts

  • Chapter
Isospecific Polymerization of Olefins

Part of the book series: Polymers ((POLYMERS,volume 9))

Abstract

The most prominent feature of heterogeneous Ziegler-Natta catalysts is their ability to produce isotactic olefin polymers exhibiting a combination of outstanding mechanical characteristics. This ability adds a new dimension to the description of the catalysts and the polymerization processes: the study of catalyst and polymerization parameters influencing polyolefin stereoregularity. Such studies usually pursue two goals: improvement of catalyst isospecificity and understanding of the mechanism of isotactic polymer formation. It is the second topic that constitutes the main subject of this chapter.

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Kissin, Y.V. (1985). Stereospecificity of Heterogeneous Ziegler-Natta Catalysts. In: Isospecific Polymerization of Olefins. Polymers, vol 9. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-5084-5_3

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