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Reaction Progress: A Monitor of Fluid—Rock Interaction during Metamorphic and Hydrothermal Events

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Fluid—Rock Interactions during Metamorphism

Part of the book series: Advances in Physical Geochemistry ((PHYSICAL GEOCHE,volume 5))

Abstract

When fluid infiltrates a rock and they are not in chemical equilibrium, chemical reactions proceed between fluid and minerals in the rock. Once the stoichiometry of the mineral—fluid reaction and the composition of the fluid is taken into account, the progress of the reaction serves as a quantitative measure of how much fluid the rock chemically interacts with. Reaction progress therefore serves as a natural fossil flux meter for fluid—rock interactions during, for example, metamorphism and hydrothermal events. Numerous applications can be made. On an outcrop scale, reaction progress can determine whether fluid flow was pervasive or was channelized along bedding, fractures, or foliation. On a regional scale, reaction progress can identify metamorphic and hydrothermal infiltration fronts and the relationship between fluid—rock interaction and the degree of metamorphism or alteration. On the scale of an entire metamorphic belt, reaction progress may reveal whether fluid released during metamorphism flows to the surface in a single pass or is recirculated in crustal-scale metamorphic hydrothermal cells.

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References

  • Bird, D.K., and Norton, D.L. (1981) Theoretical prediction of phase relations among aqueous solutions and minerals: Salton Sea geothermal system. Geochim. Cosmo- chim. Acta 45, 1479–1493.

    Article  Google Scholar 

  • Bird, D.K., Schiffman, P., and Elders, W.A., Williams, A.E., and McDowell, S.D. (1984) Calc-silicate mineralization in active geothermal systems. Econ. Geol. 79, 671–695.

    Article  Google Scholar 

  • Brimhall, G.H., Jr. (1979) Lithologie determination of mass transfer mechanisms of multiple-stage porphyry copper mineralization at Butte, Montana: Vein formation by hypogene leaching and enrichment of potassium-silicate protore. Econ. Geol. 74, 556–589.

    Article  Google Scholar 

  • Clayton, R.N., Muffler, L.J.P., and White, D.E. (1968) Oxygen isotope study of calcite and silicates of the River Ranch No. 1 well, Salton Sea geothermal field, California. Am. J. S ci. 266, 968–979.

    Google Scholar 

  • DeDonder, Th. (1920) Leçons de Thermodynamique et de Chimie-Physique. Gauthier-Villars, Paris.

    Google Scholar 

  • England, P.C., and Richardson, S.W. (1977) The influence of erosion upon the mineral faciès of rocks from different metamorphic environments. J. Geol. Soc. London 134, 201–213.

    Article  Google Scholar 

  • England, P.C., and Thompson, A.B. (1984) Pressure-temperature-time paths of regional metamorphism. Part I. Heat transfer during evolution of regions of thickened continental crust. Petrol. 25, 894–928.

    Google Scholar 

  • Ferry, J.M. (1980) A case study of the amount and distribution of heat and fluid during metamorphism. Contrib. Mineral. Petrol. 71, 373–385.

    Article  Google Scholar 

  • Ferry, J.M. (1981) Petrology of graphitic sulfide-rich schists from south-central Maine: An example of desulfidation during prograde regional metamorphism. Amer. Mineral. 66, 908–930.

    Google Scholar 

  • Ferry, J.M. (1983a) Applications of the reaction progress variable in metamorphic petrology. J. Petrol. 24, 343–376.

    Google Scholar 

  • Ferry, J.M. (1983b) Regional metamorphism of the Vassalboro Formation, south- central Maine, USA: A case study of the role of fluid in metamorphic petrogenesis. J. Geol. Soc. London 140, 551–576.

    Article  Google Scholar 

  • Ferry, J.M. (1983c) On the control of temperature, fluid composition, and reaction progress during metamorphism. Amer. J. Sci. 283A, 201–232.

    Google Scholar 

  • Ferry, J.M. (1984a) Phase composition as a measure of reaction progress and an experimental model for the high-temperature metamorphism of mafic igneous rocks. Amer. Mineral. 69, 677–691.

    Google Scholar 

  • Ferry, J.M. (1984b) A biotite isograd in south-central Maine, U.S.A.: Mineral reactions, fluid transfer, and heat transfer. J. Petrol. 25, 871–893.

    Google Scholar 

  • Ferry, J.M. (1985) Hydrothermal alteration of Tertiary igneous rocks from the Isle of Syke, northwest Scotland. I. Gabbros. Contrib. Mineral. Petrol. 91, 264–282.

    Article  Google Scholar 

  • Ferry, J.M., and Burt, D.M. (1982) Characterization of metamorphic fluid composition through mineral equilibria, in Characterization of Metamorphism through Mineral Equilibria, edited by J.M. Ferry, pp. 207–262. Mineral. Soc. Amer., Washington, DC.

    Google Scholar 

  • Fitts, D.D. (1962) Nonequilibrium Thermodynamics. McGraw-Hill, New York.

    Google Scholar 

  • Forester, R.W., and Taylor, H.P. (1977) 180/160, D/H, and 13C/12C studies of the Tertiary igneous complex of Skye, Scotland. Amer. J. Sci. 277, 136–177.

    Google Scholar 

  • Helgeson, H.C. (1968) Evaluation of irreversible reactions in geochemical processes involving minerals and aqueous solutions. I. Thermodynamic relations. Geochim. Cosmochim. Acta 32, 853–877.

    Article  Google Scholar 

  • Helgeson, H.C. (1970) A chemical and thermodynamic model of ore deposition in hydrothermal systems. Mineral. Soc. Amer. Spec. Pap. 3, 155–186.

    Google Scholar 

  • Helgeson, H.C., Garrels, R.M., and Mackenzie, F.T. (1969) Evaluation of irreversible reactions in geochemical processes involving minerals and aqueous solutions. II. Applications. Geochim. Cosmochim. Acta 33, 455–481.

    Article  Google Scholar 

  • Helgeson, H.C., Brown, T.H., Nigrini, A., and Jones, T.A. (1970) Calculation of mass transfer in geochemical processes involving aqueous solutions. Geochim. Cosmochim. Acta 34, 569–592.

    Article  Google Scholar 

  • Hover-Granath, V.C., Papike, J.J., and Labotka, T.C. (1983) The Notch Peak contact metamorphic aureole, Utah: Petrology of the Big Horse limestone member of the Orr Formation. Geol. Soc. Amer. Bull. 94, 889–906.

    Article  Google Scholar 

  • Labotka, T.C., White, C.E., and Papike, J.J. (1984) The evolution of water in the contact-metamorphic aureole of the Duluth Complex, northeastern Minnesota. Geol. Soc. Amer. Bull. 95, 788–804.

    Article  Google Scholar 

  • McDowell, S.D., and Elders, W.A. (1983) Allogenic layer silicate minerals in borehole Elmore #1, Salton Sea geothermal field, California. Amer. Mineral. 68, 1146— 1159.

    Google Scholar 

  • Muffler, L.J.P., and White, D.E. (1969) Active metamorphism of Upper Cretaceous sediments in the Salton Sea geothermal field and the Salton Trough, southeastern California. Geol. Soc. Amer. Bull. 80, 157–182.

    Article  Google Scholar 

  • Nabelek, P.I., Labotka, T.C., O’Neil, J.R., and Papike, J.J. (1984) Contrasting fluid/ rock interaction between the Notch Peak granitic intrusion and argillites and limestones in western Utah: Evidence from stable isotopes and phase assemblages. Contrib. Mineral Petrol. 86, 25–34.

    Article  Google Scholar 

  • Norton, D.L., and Knight, J. (1977) Transport phenomena in hydrothermal systems: Cooling plutons. Amer. J. Sci. 277, 937–981.

    Article  Google Scholar 

  • Norton, D.L., and Taylor, H.P., Jr. (1979) Quantitative simulation of the hydrothermal systems of crystallizing magmas on the basis of transport theory and oxygen isotope data: An analysis of the Skaergaard intrusion. J. Petrol. 20, 421–486.

    Google Scholar 

  • Prigogine, I., and Defay, R. (1954) Chemical Thermodynamics. Longman, London.

    Google Scholar 

  • Rice, J.M., and Ferry, J.M. (1982) Buffering, infiltration, and the control of intensive variables during metamorphism, in Characterization of Metamorphism through Mineral Equilibria, edited by J.M. Ferry, pp. 263–326. Mineral. Soc. Amer., Washington, DC.

    Google Scholar 

  • Rumble, D. (1982) Stable isotope fractionation during metamorphic devolatilization reactions, in Characterization of Metamorphism through Mineral Equilibria, edited by J.M. Ferry, pp. 327–354. Mineral. Soc. Amer., Washington, DC.

    Google Scholar 

  • Rumble, D., Ferry, J.M., Hoering, T.C., and Boucot, A.J. (1982) Fluid flow during metamorphism at the Beaver Brook fossil locality, New Hampshire. Amer. J. Sci. 282, 886–919.

    Google Scholar 

  • Schiffman, P., Elders, W.A., Williams, A.E., McDowell, S.D., and Bird, D.K. (1984) Active metasomatism in the Cerro Prieto geothermal system, Baja California, Mexico: A telescoped low-pressure, low-temperature metamorphic facies series. Geology 12, 12–15.

    Article  Google Scholar 

  • Spear, F.S. (1984) Contrasting P-T paths of Barrovian and Buchan metamorphism, central New England. Trans. Amer. Geophys. Union 65, 1148.

    Google Scholar 

  • Spear, F.S., and Selverstone, J. (1983) Quantitative P-T paths from zoned minerals: Theory and tectonic applications. Contrib. Mineral. Petrol. 83, 348–357.

    Article  Google Scholar 

  • Taylor, H.P., Jr. (1977) Water/rock interactions and the origin of H20 in granitic batholiths. J. Geol. Soc. London 133, 509–558.

    Article  Google Scholar 

  • Thompson, A.B., and England, P.C. (1984) Pressure-temperature-time paths of regional metamorphism. Part II. Their inference and interpretation using mineral assemblages in metamorphic rocks. J. Petrol. 25, 929–955.

    Google Scholar 

  • Thompson, J.B., Jr. (1982a) Composition space: An algebraic and geometric approach, in Characterization of Metamorphism through Mineral Equilibria, edited by J.M. Ferry, pp. 1–32. Mineral. Soc. Amer., Washington, DC.

    Google Scholar 

  • Thompson, J.B., Jr. (1982b) Reaction space: An algebraic and geometric approach, in Characterization of Metamorphism through Mineral Equilibria, edited by J.M. Ferry, pp. 33–52. Mineral. Soc. Amer., Washington, DC.

    Google Scholar 

  • Thompson, J.B., Jr., Laird, J., and Thompson, A.B. (1982) Reactions in amphibo- lite, greenschist and blueschist. J. Petrol. 23, 1–27.

    Google Scholar 

  • Tracy, R.J., Rye, D.M., Hewitt, D.A., and Schiffries, C.M. (1983) Petrologic and stable-isotopic studies of fluid—rock interactions, south-central Connecticut. I. The role of infiltration in producing reaction assemblages in impure marbles. Amer. J. Sci. 283A, 589 - 616.

    Google Scholar 

  • Turner, F.J. (1981) Metamorphic Petrology. Mineralogical, Field, and Tectonic Aspects. McGraw-Hill, New York.

    Google Scholar 

  • Walther, J.V., and Orville, P.M. (1982) Volatile production and transport in regional metamorphism. Contrib. Mineral. Petrol. 79, 252–257.

    Article  Google Scholar 

  • Walther, J.V., and Wood, B.J. (1984) Rate and mechanism in prograde metamorphism. Contrib. Mineral. Petrol. 88, 246–259.

    Article  Google Scholar 

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© 1986 Springer-Verlag New York Inc.

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Ferry, J.M. (1986). Reaction Progress: A Monitor of Fluid—Rock Interaction during Metamorphic and Hydrothermal Events. In: Walther, J.V., Wood, B.J. (eds) Fluid—Rock Interactions during Metamorphism. Advances in Physical Geochemistry, vol 5. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-4896-5_3

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  • DOI: https://doi.org/10.1007/978-1-4612-4896-5_3

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-0-387-96244-3

  • Online ISBN: 978-1-4612-4896-5

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