Abstract
The addition of ethanol to the cyano group of salicyl-aldehyde cyanoacetylhydrazone (SCH) is catalyzed by Cu(II) chloride, bromide, and sulphate, while it remains unchangeable in complexes derived from Cu(II) acetate. The isolated Cu(II) complexes have been characterized by conventional physical and chemical methods. Infrared spectra indicate that the ligand coordinates in a tridentate and/or bidentate manner. The stereochemistry of these Cu(II) complexes is discussed and elucidated with the help of magnetic and spectral measurements. The novel organic compound, l-salicylhydrazo-3-imino-3-ethoxypropionic acid hydrazide (SIEPH), was synthesized and its structure confirmed by elemental analysis and spectrophotometry techniques.
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Mostafa, M.M., El-Shazely, R.M., Shallaby, A.EH.M. (1987). The Role of Cu(II) in the Addition of Ethanol to the Cyano Group and the Preparation of Novel Organic Compounds. In: Sorenson, J.R.J. (eds) Biology of Copper Complexes. Experimental Biology and Medicine, vol 16. Humana Press. https://doi.org/10.1007/978-1-4612-4584-1_40
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DOI: https://doi.org/10.1007/978-1-4612-4584-1_40
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