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Electronic Structure, Lattice Dynamics, and Magnetic Interactions

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High Temperature Superconductivity

Part of the book series: Graduate Texts in Contemporary Physics ((MSBL))

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Abstract

Superconductivity in the copper oxide systems occurs near a structural instability (orthorhombic↔tetragonal) as well as a metal-insulator transition which can be controlled by doping or oxygen stoichiometry. At low temperatures, the metallic phase becomes superconducting, while the insulating phase shows long range antiferromagnetic order. The structure of most of the high-T c superconductors are layered perovskite with large anisotropy (see Chapter 4), and the most unique feature is the presence of CU-O2 layers which seem to be crucial for the high temperature superconductivity. The only exception is the cubic perovskite Ba 1−x K x BiO 3−y , which has an onset temperature of 30 K but has the CU-O2 layers missing [1]. Instead of antiferromagnetism (spin density wave), the superconducting phase is near a planar breathing-type displacement of the oxygen atoms away from one of the Bi neighbors (charge density wave). It will be interesting to see if this new cubic material has the same mechanism to achieve higher T c as the cuprate superconductors.

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Wang, Cp.S. (1990). Electronic Structure, Lattice Dynamics, and Magnetic Interactions. In: Lynn, J.W. (eds) High Temperature Superconductivity. Graduate Texts in Contemporary Physics. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-3222-3_5

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