Advertisement

Amazing Light pp 173-190 | Cite as

The Electronic Emission Spectra of Triatomic Hydrogen: The 6025Å Bands of H2D and HD2

  • Izabel Dabrowski
  • Gerhard Herzberg

Abstract

In the original work on triatomic hydrogen [1–5], transitions were reported which characterized the n = 2 and the n = 3 Rydberg states, the lowest bound states of the molecule. Only the isotopomers H3 and D3 were considered in detail. The spectra of the triatomic molecule were observed in the cathode glow of a hollow cathode discharge, superimposed on the spectra of the diatomic molecule. In fact the lines of the triatomic were distinguishable from those of the diatomic only because they did not occur in the anode glow.

Keywords

Rydberg State Sharp Line Hollow Cathode Discharge Vibronic Interaction Fourier Transform Spectrometer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. [1]
    G. Herzberg, J. Chem. Phys. 70, 4806 (1979).ADSCrossRefGoogle Scholar
  2. [2]
    I. Dabrowski and G. Herzberg, Can. J. Phys. 58, 1238 (1980).ADSCrossRefGoogle Scholar
  3. [3]
    G. Herzberg and J. K. G. Watson, Can. J. Phys. 58, 1250 (1980).ADSCrossRefGoogle Scholar
  4. [4]
    G. Herzberg, H. Lew, J. J. Sloan, and J. K. G. Watson, Can. J. Phys. 59, 428 (1981).ADSCrossRefGoogle Scholar
  5. [5]
    G. Herzberg, J. T. Hougen, and J. K. G. Watson, Can. J. Phys. 60, 1261 (1982).ADSCrossRefGoogle Scholar
  6. [6]
    I. Dabrowski, G. Herzberg, B. P. Hurley, R.H. Lipson, M. Vervloet, and D. -C. Wang, Mol. Phys. 63, 269 (1988).ADSCrossRefGoogle Scholar
  7. [7]
    I. Dabrowski, G. Herzberg, and R. H. Lipson, Mol. Phys. 63, 289 (1988).ADSCrossRefGoogle Scholar
  8. [8]
    I. Dabrowski, G. DiLonardo, G. Herzberg, J. W. C. Johns, D. A. Sadovskii, and M. Vervloet, J. Chem. Phys. 97, 7093 (1992).ADSCrossRefGoogle Scholar
  9. [9]
    D. Cossart, C. Cossart-Magos, G. Gandra, and J. M. Robbe, J. Mol. Spectrosc. 109, 166 (1985).Google Scholar
  10. [10]
    H. Figger, M.N. Dixit, R. Maier, W. Schrepp, H. Walther, I.R. Peterkin, and J. K. G. Watson, Phys. Rev. Lett. 52, 906, (1984).ADSCrossRefGoogle Scholar
  11. [11]
    H. Figger, Y. Fukida, W. Ketterle, and H. Walther, Can. J. Phys. 62, 1274 (1984).ADSCrossRefGoogle Scholar
  12. [12]
    H. Figger, W. Ketterle, and H. Walther, Zeit. fur Physik D 13, 129 (1989).CrossRefGoogle Scholar
  13. [13]
    W. Ketterle, H. Figger, and H. Walther, Zeit. fur Physik D 13, 139 (1989).CrossRefGoogle Scholar
  14. [14]
    V. Kaufman and B. Edlen, Jour. Phys. Chem. Ref. Data 3, 825 (1974).ADSCrossRefGoogle Scholar
  15. [15]
    S. C. Foster, A. R. W. McKellar, I. R. Peterkin, J. K. G. Watson, F. S. Pan, M. W. Crofton, R. S. Altman, and T. Oka, J. Chem. Phys. 84, 91 (1986).ADSCrossRefGoogle Scholar
  16. [16]
    S. C. Foster, A. R. W. McKellar, and J. K. G. Watson, J. Chem. Phys. 85, 664 (1986).ADSCrossRefGoogle Scholar
  17. [17]
    G. Herzberg, Molecular Spectra and Molecular Structure: II. Infrared and Raman Spectra of Polyatomic Molecules, Krieger Publishing Co. Malabar, Florida (1991).Google Scholar

Copyright information

© Springer-Verlag New York, Inc. 1996

Authors and Affiliations

  • Izabel Dabrowski
  • Gerhard Herzberg

There are no affiliations available

Personalised recommendations