Abstract
This chapter describes the hydrogen production by solar-powered steam reforming. This process allows some upgrading of the reformed fuel (in terms of heat value and environmental impact) and significant reduction (40–50 %) in CO2 emission to the atmosphere, with respect to the conventional steam reforming process. Additionally, solar steam reforming is presented as an emission-free process: the only carbon-containing by-product stream is well suited for the application of CCS technologies, and the overall process can also be considered as a “fuel pre-combustion decarbonization route”. Application of pressurized membrane reactors for low-temperature steam reforming improves the overall process efficiency and enhances the recovery of CO2 thanks to its relatively high partial pressure in the by-product stream. The application of SERP technology for in situ CO2 separation is discussed too.
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Abbreviations
- CCS:
-
Carbon Capture and Storage
- CSP:
-
Concentrating Solar Power
- FC:
-
Fuel Cell
- HCNG:
-
Hydrogen Containing Natural Gas
- HTF:
-
Heat Transfer Fluid
- ICE:
-
Internal Combustion Engine
- IMR:
-
Integrated Membrane Reformer
- MS:
-
Molten Salt
- MSMR:
-
Multi-Stage Membrane Reformer
- NG:
-
Natural Gas
- PSA:
-
Pressure Swing Adsorption
- PV:
-
Photovoltaic
- RES:
-
Renewable Energy Sources
- SERP:
-
CO2 Sorption Enhanced Reforming Process
- SMR:
-
Steam Methane Reforming
- SR:
-
Steam Reforming
- WGS:
-
Water–Gas-Shift reaction
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Giaconia, A. (2013). Hydrogen Production by Solar Steam Reforming as a Fuel Decarbonization Route. In: Falco, M., Iaquaniello, G., Centi, G. (eds) CO2: A Valuable Source of Carbon. Green Energy and Technology. Springer, London. https://doi.org/10.1007/978-1-4471-5119-7_7
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DOI: https://doi.org/10.1007/978-1-4471-5119-7_7
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