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Heterogeneous Catalysis Through Microcontact Printing

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The Power of Click Chemistry for Molecular Machines and Surface Patterning

Part of the book series: Springer Theses ((Springer Theses))

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Abstract

Minting a Stamp. The preparation of copper metal-coated elastomeric stamps and their use in catalyzing the CuAAC reaction heterogeneously through microcontact printing is described. This so-called StampCat process is compared to other conventional surface-functionalization techniques, including traditional microcontact printing and solution-surface based reactions in order to develop a fundamental understanding of the reaction efficiencies and surface features endowed by these different methods for promoting reactions at surfaces.

This Chapter is reproduced in part with permission from: Spruell JM, Sheriff BA, Rozkiewicz DI, Dichtel WR, Rohde RD, Reinhoudt DN, Stoddart JF., Heath JR Angew. Chem. Int. Ed.2008, 47, 9927–9932.

Author Contributions: J.M. Spruell, D.I. Rozkiewicz, W.R. Dichtel, and J.R. Heath conceived the project. J.M. Spruell, J.R. Heath and J.F. Stoddart prepared the original manuscript. J.M. Spruell, D.I. Rozkiewicz, and B.A. Sheriff performed microcontact printing. J.M. Spruell synthesized all compounds used in these investigations. J.M. Spruell and B.A. Sheriff performed IR, electrochemical, and water contact angle characterization. D.I. Rozkiewicz performed AFM and confocal fluorescence microscopies. R.D. Rohde performed XPS analysis. D.N. Reinhoudt, J.F. Stoddart, and J.R. Heath supervised the original research.

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Authors and Affiliations

  1. Institute and Materials Research Laboratory, University of California, Santa Barbara, CA, USA

    Jason M. Spruell

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  1. Jason M. Spruell
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Correspondence to Jason M. Spruell .

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Spruell, J.M. (2011). Heterogeneous Catalysis Through Microcontact Printing. In: The Power of Click Chemistry for Molecular Machines and Surface Patterning. Springer Theses. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-9647-3_4

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