Abstract
Lignins are seldom accorded a prominent place in compendia about biodegradable polymeric materials. Yet lignin derivatives are available in huge quantities from plant sources, and they are (albeit slowly) biodegradable. Indeed high (85%) industrial by-product lignin contents in thermoplastics were first reported in 19971, and since then a U.S. patent2 has been issued in response to the discovery of plasticizers for simple derivatives of the same kind of raw materials. Previously it had usually been impossible to incorporate any lignin derivative at levels beyond 25–40% into a polymeric material without sacrificing its mechanical integrity. The present article traces the development of the conceptual basis for the paradigm shift that has occurred in formulating useful lignin-based thermoplastics.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Li, Y., Mlynár, J., and Sarkanen, S., 1997, The first 85% kraft-lignin-based thermoplastics. J. Polym. Sci., Part B: Polym. Phys. 35: 1899–1910.
Sarkanen, S., and Li, Y., January 9, 2001, Compositions Based on Lignin Derivatives. US Pat. 6172204.
Lewis, N. G., Davin, L. B., and Sarkanen, S., 1999, The Nature and Function of Lignins. In Comprehensive Natural Products Chemistry (D. H. R. Barton, K. Nakanishi and O. Meth-Cohn, eds.), Elsevier Science, Oxford, Vol. 3 (B. M. Pinto, Vol. ed.), pp. 617–745.
Sakakibara, A., 1980, A structural model of softwood lignin. Wood Sci. Technol. 14: 89–100.
Brunow, G., Kilpeläinen, I., Sipilä, J., Syrjänen, K., Karhunen, P., Setälä, H., and Rummakko, P., 1998, Oxidative Coupling of Phenols and the Biosynthesis of Lignin. In Lignin and Lignan Biosynthesis (N. G. Lewis and S. Sarkanen, eds.), ACS Symposium Series No. 697, American Chemical Society, Washington, D.C., pp. 131–147.
Argyropoulos, D. S., Jurasek, L., Kristofová, L., Xia, Z., Sun, Y., and Palus, S., 2002, Abundance and reactivity of dibenzodioxocins in softwood lignin. J. Agric. Food Chem. 50: 658–666.
Gierer, J., 1980, Chemical aspects of kraft pulping. Wood Sci. Technol. 14: 241–266.
Kirkman, A. G., Gratzl, J. S., and Edwards, L. L., 1986, Kraft lignin recovery by ultrafiltration—economic feasibility and impact on the kraft recovery system. Tappi J. 69(5): 110–114.
Hergert, H. L., 1998, Developments in Organosolv Pulping—An Overview. In Environmentally Friendly Technologies for the Pulp and Paper Industry (R. A. Young and M. Akhtar, eds.), Wiley, New York, pp. 5–67.
Vinzant, T. B., Ehrman, C. I., Adney, W. S., Thomas, S. R., and Himmel, M. E., 1997, Simultaneous saccharification and fermentation of pretreated hardwoods—effect of lignin content. Appl. Biochem. Biotechnol. 62: 99–104.
Dorsch, R., and Nghiem, N., 1998, Specialty chemicals with emphasis on environmentally benign products and processes. Appl. Biochem. Biotechnol 70-72: 843–844.
Holzman, D., 1999, Monsanto moves into the contract production arena. Gen. Eng. News 19(4): 1,8,35.
Anterola, A. M., and Lewis, N. G., 2002, Trends in lignin modification—a comprehensive analysis of the effects of genetic manipulations/mutations on lignification and vascular integrity. Phytochemistry 61: 221–294.
Lignin—Properties and Materials (W. G. Glasser and S. Sarkanen, eds.), 1989, ACS Symposium Series No. 397, American Chemical Society, Washington, D.C.
Meister, J. J., 1986, Review of the Synthesis, Characterization, and Testing of Graft Copolymers of Lignin. In Renewable-Resource Materials—New Polymer Sources (C. E. Carraher, Jr. and L. H. Sperling, eds.), Plenum Publishing Corp., New York, pp. 305–322.
Lindberg, J. J., Kuusela, T. A., and Levon, K., 1989, Specialty Polymers from Lignin. In Lignin—Properties and Materials (W. G. Glasser and S. Sarkanen, eds.), ACS Symposium Series No. 397, American Chemical Society, Washington, D.C., pp. 190–204.
Yoshida, H., Mörck, R., Kringstad, K. P., and Hatakeyama, H., 1990, Kraft lignin in polyurethanes; II: Effects of the molecular weight of kraft lignin on the properties of polyurethanes from a kraft lignin-polyether triol-polymeric MDI system. J. Appl. Polym. Sci. 40: 1819–1832.
Kelley, S. S., Glasser, W. G., and Ward, T. C., 1989, Effect of Soft-Segment Content on the Properties of Lignin-Based Polyurethanes. In Lignin—Properties and Materials (W. G. Glasser and S. Sarkanen, eds.), ACS Symposium Series No. 397, American Chemical Society, Washington, D.C., pp. 402–413.
Sarkanen, S., Teller, D. C., Stevens, C. R., and McCarthy, J. L., 1984, Associative interactions between kraft lignin components. Macromolecules 17: 2588–2597.
Dutta, S., Garver, T. M., Jr., and Sarkanen, S., 1989, Modes of Association between Kraft Lignin Components. In Lignin—Properties and Materials (W. G. Glasser and S. Sarkanen, eds.), ACS Symposium Series No. 397, American Chemical Society, Washington, D.C., pp. 155–176.
Dutta, S., and Sarkanen, S., 1990, A New Emphasis in Strategies for Developing Lignin-Based Plastics. In Materials Interactions Relevant to the Pulp, Paper, and Wood Industries (D. F. Caulfield, J. D. Passaretti and S. F. Sobczynski, eds.), MRS Symposium Proceedings Vol. 197, Materials Research Society, Pittsburgh, pp. 31–39.
Mlynár, J., and Sarkanen, S., 1996, Renaissance in Ultracentrifugal Sedimentation Equilibrium Calibrations of Size Exclusion Chromatographic Elution Profiles. In Strategies in Size Exclusion Chromatography (M. Potschka and P. L. Dubin, eds.), ACS Symposium Series No. 635, American Chemical Society, Washington, D.C., pp. 379–400.
Garver, T. M., Jr., Iwen, M. L., and Sarkanen, S., 1989, The Kinetics of Macromolecular Kraft Lignin Complex Dissociation. In Fifth International Symposium on Wood and Pulping Chemistry, TAPPI Proceedings, TAPPI, Atlanta, Vol. I, pp. 113–119.
Li, Y., 1995, Noncovalent Interactions between Kraft Lignin Components. MS Thesis University of Minnesota.
Li, Y., and Sarkanen, S., 2000, Thermoplastics with Very High Lignin Contents. In Lignin—Historical, Biological, and Materials Perspectives (W. G. Glasser, R. A. Northey and T. P. Schultz, eds.), ACS Symposium Series No. 742, American Chemical Society, Washington, D.C., pp. 351–366.
Sarkanen, S., and Li, Y., 1999, Plasticizers that Transform Alkylated Kraft Lignins into Thermoplastics. In Biomass—A Growth Opportunity in Green Energy and Value-Added Products (R. P. Overend and E. Chornet, eds.), Proceedings of the 4th Biomass Conference of the Americas, Elsevier Science Ltd., Oxford, Vol. 1, pp. 533–539.
Li, Y., and Sarkanen, S., 2001, Kraft lignin-based thermoplastic polymer blends. In 11th International Symposium on Wood and Pulping Chemistry, ATIP, Paris, Vol. I, pp. 75–78.
Lu, X., and Weiss, R. A., 1992, Relationship between the glass transition temperature and the interaction parameter of miscible binary polymer blends. Macromolecules 25: 3242–3246.
Gordon, M, and Taylor, J. S., 1952, Ideal copolymers and the second-order transitions of synthetic rubbers. I: Non-crystalline copolymers. J. Appl. Chem. 2: 493–500.
Kwei, T. K., 1984, The effect of hydrogen-bonding on the glass transition temperatures of polymer mixtures. J. Polym. Sci., Polym. Lett. 22: 307–313.
Prud’homme, R. E., 1982, Miscibility phenomena in polyester/chlorinated polymer blends. Polym. Eng. Sci. 22: 90–95.
Lin, A. A., Kwei, T. K., and Reiser, A., 1989, On the physical meaning of the Kwei equation for the glass transition temperature of polymer blends. Macromolecules 22: 4112–4119.
Li, Y., and Sarkanen, S., 2002, Alkylated kraft lignin based thermoplastic blends with aliphatic polyesters. Macromolecules 35: 9707–9715.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2003 Springer Science+Business Media New York
About this paper
Cite this paper
Li, Y., Sarkanen, S. (2003). Biodegradable Kraft Lignin-based Thermoplastics. In: Chiellini, E., Solaro, R. (eds) Biodegradable Polymers and Plastics. Springer, Boston, MA. https://doi.org/10.1007/978-1-4419-9240-6_9
Download citation
DOI: https://doi.org/10.1007/978-1-4419-9240-6_9
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-4854-2
Online ISBN: 978-1-4419-9240-6
eBook Packages: Springer Book Archive