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Trace-Anion Catalysis of Outer-Sphere Heterogeneous Charge-Transfer Reactions

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Modern Aspects of Electrochemistry

Part of the book series: Modern Aspects of Electrochemistry ((MAOE,volume 37))

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Abstract

That anions can affect the rate of metal redox reactions has been known for a long time. More often than not, this was caused by formation of complex ions in the solution, thereby completely changing the nature of the reaction, although other causes (electrostatic effects and surface ligand bridging) have also been considered. This general field has been summarized in a review by Weaver.1 Much of the early work was carried out on mercury electrodes, usually with polarographic techniques, reviewed by de Levie.2 The anion concentration and the ratio of anion to reactant concentration were so high in practically all these reports that bulk solution complex formation could not be ignored.

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References

  1. M. J. Weaver in Comprehensive Chemical Kinetics, Ed. by R.G. Compton, Vol. 27, Elsevier, NY, 1987, 1.

    Google Scholar 

  2. R. de Levie, J. Electrochem. Soc. 118 (1971) 185C.

    Article  Google Scholar 

  3. H. Gerischer, Z. Elektrochem. 54 (1950) 362.

    Google Scholar 

  4. R. J. Davenport, D. C. Johnson, Anal. Chem. 45 (1973) 1755.

    Article  CAS  Google Scholar 

  5. L. R. Taylor, B. A. Parkinson, D. C. Johnson, Electrocim. Acta 20 (1975) 1005.

    Article  CAS  Google Scholar 

  6. D. C. Johnson, E. W. Resnick, Anal. Chem. 49 (1977) 1913.

    Google Scholar 

  7. J. Weber, Z. Samec, V. Marecek, J. Electroanal. Chem. 89 (1978) 271.

    Article  CAS  Google Scholar 

  8. J. T. Wadden, MS Thesis, Memorial University of Newfoundland, Canada (1978).

    Google Scholar 

  9. F. R. Smith, J. T. Wadden, Prepr. Can. Symp. Catal. 6 (1979) 263.

    CAS  Google Scholar 

  10. S. W. Barr, K. L. Guyer, M. J. Weaver, J. Electroanal Chem. 111 (1980) 41.

    Article  Google Scholar 

  11. H. Verplaetse, P. Kiekens, E. Temmerman, F. Verbeek, Talanta 28 (1981) 431.

    Article  Google Scholar 

  12. N. C. Hung, Z. Nagy, J. Electrochem. Soc. 134 (1987) 2215.

    Article  CAS  Google Scholar 

  13. P. K. Wrona, Polish J. Chem. 65 (1991) 687.

    CAS  Google Scholar 

  14. Z. Nagy, L. A. Curtiss, N. C. Hung, D.J. Zurawski, R. M. Yonco, J. Electroanal. Chem. 325 (1992) 313.

    Article  Google Scholar 

  15. Z. Nagy, J. P. Blaudeau, N. C. Hung, L.A. Curtiss, D.J. Zurawski, J. Electrochem. Soc. 142 (1995) L87.

    Article  CAS  Google Scholar 

  16. N. C. Hung, Z. Nagy, unpublished results.

    Google Scholar 

  17. C. A. McDermott, K. R. Kneten, R. L. McCreary, J. Electrochem. Soc. 140 (1993) 2593.

    Article  Google Scholar 

  18. P. Chen, M. A. Fryling, R. L. McCreary, Anal. Chem, 67 (1995) 3115.

    Article  CAS  Google Scholar 

  19. N. Tanaka, R. Tamamushi, Electrochim. Acta 9 (1964) 963.

    Article  CAS  Google Scholar 

  20. R. Tamamushi, Kinetic Parameters of Electrode Reactions of Metallic Compounds, Butterworths, London, 1975.

    Google Scholar 

  21. K. E. Heusler, in Encyclopedia of Electrochemistry of the Elements, Ed. by A.J. Bard, Vol. IXA, Marcel Dekker, New York, 1982, 229.

    Google Scholar 

  22. M. R. Rosenthal, J. Chem. Ed. 50 (1973) 331.

    Article  CAS  Google Scholar 

  23. L. Johansson, Coord. Chem. Rev. 12 (1974) 241.

    Article  CAS  Google Scholar 

  24. S. Ya. Vasina, O. A. Petrii, Soviet Electrochem. 6 (1970) 231.

    Google Scholar 

  25. J. Clavilier, C. N. Van Huong, J. Electroanal. Chem. 80 (1977) 101.

    Article  CAS  Google Scholar 

  26. W. Boeld, M. Breiter, Electrochim. Acta 5 (1961) 145.

    Article  CAS  Google Scholar 

  27. M. W. Breiter, Electrochim. Acta 8 (1963) 447.

    Article  CAS  Google Scholar 

  28. M.W. Breiter, Electrochim. Acta, 8 (1963) 925.

    Article  Google Scholar 

  29. S. Gilman, in Electroanalytical Chemistry, Ed. by A.J. Bard, Vol. 2, Marcel Dekker, New York, 1967, 111.

    Google Scholar 

  30. D. A. J. Rand, R. Woods, J. Electroanal. Chem. 35 (1972) 209.

    Article  CAS  Google Scholar 

  31. T. Takamura, Y. Sato, K. Takamura, J. Electroanal. Chem. 41 (1973) 31.

    Article  CAS  Google Scholar 

  32. C. M. Ferro, A. J. Calandra, A. J. Arvia, J. Electroanal. Chem. 55 (1974) 291.

    Article  CAS  Google Scholar 

  33. G. Horanyi, G. Vertes, J. Electroanal. Chem. 64 (1975) 252.

    Article  CAS  Google Scholar 

  34. F. Colom, M. J. Gonzalez-Tejera, J. Electroanal Chem. 190 (1985) 243.

    Article  CAS  Google Scholar 

  35. M. Sanchez Cruz, M. J. Gonzalez-Tejera, M. C. Villamanan, Electrochim. Acta 30 (1985) 1563.

    Article  CAS  Google Scholar 

  36. G. M. Brown, J. Electroanal Chem., 198 (1986) 319.

    Article  CAS  Google Scholar 

  37. K.L. Guyer, S.W. Barr, R.J. Cave, M.J. Weaver, in Electrode Processes 1979, Ed. by S. Bruckenstein, J.D.E. McIntyre, B. Miller, E. Yeager, The Electrochemical Society Softbound Proceedings Series, Vol. 80-3, Pennington, NJ, 1980, p. 390.

    Google Scholar 

  38. H. Taube, Electron Transfer Reactions of Complex Ions in Solution, Academic Press, New York, 1970, p. 4.

    Google Scholar 

  39. G. Horanyi, E. M. Rizmayer, P. Joo, J. Electroanal. Chem. 152 (1983) 211.

    Article  CAS  Google Scholar 

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Author information

Authors and Affiliations

  1. Materials Science Division, Argonne National Laboratory, Argonne, Illinois, 60439, USA

    Zoltán Nagy

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  1. Zoltán Nagy
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Editor information

Editors and Affiliations

  1. University of South Carolina, Columbia, South Carolina, USA

    Ralph E. White

  2. University of Ottawa, Ottawa, Ontario, Canada

    B. E. Conway

  3. University of Patras, Patras, Greece

    C. G. Vayenas

  4. Superior, Colorado, USA

    Maria E. Gamboa-Adelco (Managing Editor) (Managing Editor)

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Nagy, Z. (2004). Trace-Anion Catalysis of Outer-Sphere Heterogeneous Charge-Transfer Reactions. In: White, R.E., Conway, B.E., Vayenas, C.G., Gamboa-Adelco, M.E. (eds) Modern Aspects of Electrochemistry. Modern Aspects of Electrochemistry, vol 37. Springer, Boston, MA. https://doi.org/10.1007/978-1-4419-9027-3_5

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  • DOI: https://doi.org/10.1007/978-1-4419-9027-3_5

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-4763-7

  • Online ISBN: 978-1-4419-9027-3

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