Abstract
Femtosecond visible and infrared analogues of multiple-pulse NMR techniques provide novel snapshot probes into the structure and electronic and vibrational dynamics of complex molecular assemblies such as photosynthetic antennae, proteins, and hydrogen-bonded liquids. The response of complex molecules to a series of femtosecond optical laser pulses provides a multidimensional view into molecular structure as well as a vibrational motions, interactions, and relaxations. In complete analogy with NMR techniques, spreading the spectroscopic information in more than one dimension helps resolve congested spectra, eliminates certain static broadening mechanisms and provides structural and dynamical information unavailable from one-dimensional measurements. The basic concepts underlying these generalized techniques will be surveyed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2003 Springer Science+Business Media New York
About this paper
Cite this paper
Mukamel, S. (2003). Multitime coherent spectroscopies of complex molecules: from infrared to X-ray. In: Bigelow, N.P., Eberly, J.H., Stroud, C.R., Walmsley, I.A. (eds) Coherence and Quantum Optics VIII. Springer, Boston, MA. https://doi.org/10.1007/978-1-4419-8907-9_27
Download citation
DOI: https://doi.org/10.1007/978-1-4419-8907-9_27
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-4715-6
Online ISBN: 978-1-4419-8907-9
eBook Packages: Springer Book Archive