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Notions from Linear Algebra and Bra-Ket Notation

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Abstract

The Schrödinger equation (1.14) is linear in the wave function ψ(x, t). This implies that for any set of solutions ψ1(x, t), \({\psi }_{2}(x,t),\ldots \), any linear combination \(\psi (x,t) = {C}_{1}{\psi }_{1}(x,t) + {C}_{2}{\psi }_{2}(x,t) + \ldots \) with complex coefficients C n is also a solution. The set of solutions of equation (1.14) for fixed potential V will therefore have the structure of a complex vector space, and we can think of the wave function ψ(x, t) as a particular vector in this vector space. Furthermore, we can map this vector bijectively into different, but equivalent representations where the wave function depends on different variables. An example of this is Fourier transformation (2.5) into a wave function which depends on a wave vector k,

$$\psi (k,t) = \frac{1} {{\sqrt{2\pi }}^{3}} \int \nolimits \nolimits \!{d}^{3}x\,\exp \!\left (-\mathrm{i}k \cdot x\right )\psi (x,t).$$

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Notes

  1. 1.

    For scattering off two-dimensional crystals the Laue conditions can be recast in simpler forms in special cases. E.g. for orthogonal incidence a plane grating equation can be derived from the Laue conditions, or if the momentum transfer Δk is in the plane of the crystal a two-dimensional Bragg equation can be derived.

  2. 2.

    Normalizability is important for the correctness of equation (4.33), because for states in an energy continuum the left hand side of equation (4.32) may not vanish in the degenerate limit E ψ → E ϕ, see Problem 8.

  3. 3.

    P. Güttinger, Diplomarbeit, ETH Zürich, Z. Phys. 73, 169 (1932). Exceptionally, there is no summation convention used in equation (4.36).

  4. 4.

    R.P. Feynman, Phys. Rev. 56, 340 (1939).

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Correspondence to Rainer Dick .

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© 2012 Springer Science+Business Media, LLC

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Dick, R. (2012). Notions from Linear Algebra and Bra-Ket Notation. In: Advanced Quantum Mechanics. Graduate Texts in Physics. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-8077-9_4

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  • DOI: https://doi.org/10.1007/978-1-4419-8077-9_4

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  • Online ISBN: 978-1-4419-8077-9

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