Remedial Technology Selection for Chlorinated Solvent Plumes

  • Hans F. Stroo
Part of the SERDP/ESTCP Environmental Remediation Technology book series (SERDP/ESTCP)


The number of technology options for chlorinated aliphatic hydrocarbons (CAHs) has increased significantly over the last 20 years. Initially, pump-and-treat was the de facto presumptive remedy, and extraction systems were installed at the overwhelming majority of sites. Pump-and-treat can be an effective mass removal technology and has been used successfully in several cases. However, under most conditions, these systems primarily provide hydraulic control and plume containment (USEPA, 1999; NRC, 1994). Further, pump-and-treat systems require continued operation and maintenance for long time periods, often at a considerable annual cost.


Life Cycle Cost Reductive Dechlorination Permeable Reactive Barrier Soil Vapor Extraction Nanoscale Iron 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


  1. AFCEE (Air Force Center for Environmental Excellence). 2004. Principles and Practices of Enhanced Anaerobic Bioremediation of Chlorinated Solvents. Prepared by Parsons Infrastructure and Technology Group, Inc. for AFCEE, Brooks City-Base, TX, USA; Naval Facilities Engineering Service Center (NFESC), Port Hueneme, CA, USA; and the Environmental Security Technology Certification Program (ESTCP), Arlington, VA, USA. Accessed June 2, 2010.
  2. Agrawal A, Ferguson WJ, Gardner BO, Christ J, Bandstra JZ, Tratnyek PG. 2002. Effects of carbonate on contaminant reduction by zero-valent iron. Environ Sci Technol 36:4326–4333.CrossRefGoogle Scholar
  3. Alvarez-Cohen L, McCarty PL. 1991. Effects of toxicity, aeration, and reductant supply on trichloroethene transformation by a mixed methanotrophic culture. Appl Environ Microbiol 57:228–235.Google Scholar
  4. ARCADIS. 2002. Technical Protocol for Using Soluble Carbohydrates to Enhance Reductive Dechlorination of Chlorinated Aliphatic Hydrocarbons. Prepared for the Air Force Center for Environmental Excellence (AFCEE), Brooks-City Base, TX, USA, and the DoD Environmental Security Technology Certification Program (ESTCP), Arlington, VA, USA. Accessed June 13, 2009.
  5. Aziz CE, Hampton MM, Schipper M, Haas P. 2001. Organic mulch biowall treatment of chlorinated solvent-impacted groundwater. Proceedings, Sixth International Symposium on In-Situ and On-Site Bioremediation, San Diego, CA, USA, June 4–7, pp 73–78.Google Scholar
  6. Battelle. 2003. Evaluating the Longevity and Hydraulic Performance of Permeable Reactive Barriers at Department of Defense Sites. Cost and Performance Report. ESTCP, Arlington, VA, USA. Accessed June 13, 2009.
  7. Borden RC, Lee MD. 2002. Method for Remediation of Contaminated Aquifers. U.S. Patent No. 6,398,960 B1.Google Scholar
  8. Bradley PM, Chapelle FH. 1996. Anaerobic mineralization of vinyl chloride in Fe(III)-reducing, aquifer sediments. Environ Sci Technol 30:2084–2086.CrossRefGoogle Scholar
  9. Butler E, Hayes K. 1999. Kinetics of the transformation of trichloroethylene and tetrachloroethylene by iron sulfide. Environ Sci Technol 33:2021–2027.CrossRefGoogle Scholar
  10. Cantrell KJ, Kaplan DI, Gilmore TJ. 1997. Injection of colloidal Fe0 particles in sand with shear-thinning fluids. J Environ Eng 123:786–791.CrossRefGoogle Scholar
  11. Chappell J. 1998. Phytoremediation of TCE in Groundwater Using Populus. Status Report prepared for the USEPA, Technology Innovation Office, Washington, DC, USA. Accessed June 13, 2009.
  12. Crimi ML, Siegrist RL. 2004. Impact of reaction conditions on MnO2 genesis during permanganate oxidation. J Environ Eng 130:562–572.CrossRefGoogle Scholar
  13. Critto A, Cantarella L, Carlon C, Giove S, Petruzzelli G, Marcomini A. 2006. Decision support–oriented selection of remediation technologies to rehabilitate contaminated sites. Integr Environ Assess Manag 2:273–285.Google Scholar
  14. DoD (U.S. Department of Defense). 1998. Evaluation of DoD Waste Site Groundwater Pump-and-Treat Operations. Report Number 98–090. Department of Defense, Office of the Inspector General, Arlington, VA, USA. Accessed June 13, 2009.
  15. DoD. 2005. Defense Environmental Programs: Annual Report to Congress, Fiscal Year 2004. Accessed June 13, 2008.
  16. Dunmade I. 2004. Sustainability studies of remediation technologies of Alberta. Proceedings, Remediation Technology Symposium, Banff, Alberta, Canada, October. Accessed June 13, 2009.Google Scholar
  17. Eberts SM, Schalk CW, Vose J, Harvey GJ. 1999. Hydrologic effects of cottonwood trees on a shallow aquifer containing trichloroethene. Hydrol Sci Technol 15:115–121.Google Scholar
  18. Eberts SM, Harvey GJ, Jones SA, Beckman SW. 2003. Multiple-process assessment for a chlorinated-solvent plume. In McCutcheon SC, Schnoor JL, eds, Phytoremediation–Transformation and Control of Contaminants. Wiley Press, Hoboken, NJ, USA, pp 589–633.Google Scholar
  19. Elliot D, Zhang W. 2001. Field assessment of nanoparticles for groundwater treatment. Environ Sci Technol 35:4922–4926.CrossRefGoogle Scholar
  20. ESTCP. 1999. Technology Status Review: In Situ Oxidation. ESTCP, Arlington, VA, USA. Accessed June 13, 2009.
  21. ESTCP. 2005. Bioaugmentation for Remediation of Chlorinated Solvents: Technology Development, Status, and Research Needs. ESTCP, Arlington, VA, USA. Accessed June 13, 2009.
  22. Farrell J, Kason M, Melitas N, Li T. 2000. Investigation of long-term performance of zero-valent iron for reductive dechlorination of trichloroethylene. Environ Sci Technol 34:514–521.CrossRefGoogle Scholar
  23. Fennell DE, Carroll AB, Gossett JM, Zinder SH. 2001. Assessment of indigenous reductive dechlorinating potential at a TCE-contaminated site using microcosms, polymerase chain reaction analysis, and site data. Environ Sci Technol 35:1830–1839.CrossRefGoogle Scholar
  24. Ferrey ML, Wilkin RT, Forand RG, Wilson JT. 2004. Nonbiological removal of cis-dichloroethylene and 1,1–dichloroethylene in aquifer sediment containing magnetite. Environ Sci Technol 38:1746–1752.CrossRefGoogle Scholar
  25. GAO (U.S. Government Accountability Office). 2005. Groundwater Contamination: DOD Uses and Develops a Range of Remediation Technologies to Clean up Military Sites. Report to Congressional Committees. Report No. 05–666. GAO, Washington, DC, USA. Accessed June 13, 2009.
  26. Gates DD, Siegrist RL. 1995. In situ chemical oxidation of trichloroethylene using hydrogen peroxide. J Environ Eng 121:639–644.CrossRefGoogle Scholar
  27. Gavaskar A, Yoon WS, Sminchak J, Sass B, Gupta N, Hicks J, Lal V. 2005. Long-Term Performance Assessment of a Permeable Reactive Barrier at Former Naval Air Station Moffett Field. Naval Facilities Engineering Service Center, Port Hueneme, CA, USA. Accessed June 13, 2009.
  28. Gillham RW, O’Hannesin SF. 1994. Enhanced degradation of halogenated aliphatics by zero-valent iron. Ground Water 32:958–967.CrossRefGoogle Scholar
  29. Godsy EM, Warren E, Paganelli VV. 2003. The role of microbial reductive dechlorination of TCE at a phytoremediation site. Int J Phytoremediation 5:73–87.CrossRefGoogle Scholar
  30. Hazen TC, Lombard KH, Looney BB, Enzien MV, Hougherty JM, Fliermans CB, Wear J, Eddy-Dilek CA. 1994. Summary of in situ bioremediation (methane biostimulation) via horizontal wells at the Savannah River Site integrated demonstration project. In Situ Remediation: Scientific Basis for Current and Future Technologies. Battelle Press. Richland, WA, USA, pp 137–150.Google Scholar
  31. Hendrickson ER, Payne JA, Young RM, Starr MG, Perry MP, Buonamici LW. 2002. Molecular analysis of Dehalococcoides 16S ribosomal DNA from chloroethene-contaminated sites throughout North America and Europe. Appl Environ Microbiol 68:485–495.CrossRefGoogle Scholar
  32. Hopkins GD, Munakata J, Semprini L, McCarty PL. 1993. Trichloroethene concentration effects on pilot field-scale in-situ groundwater bioremediation by phenol-oxidizing microorganisms. Environ Sci Technol 27:2542–2547.CrossRefGoogle Scholar
  33. Hughes JB, Newell CJ, Fisher RT. 1997. Process for In-Situ Biodegradation of Chlorinated Aliphatic Hydrocarbons by Subsurface Hydrogen Injection. U.S. Patent No. 5,602,296.Google Scholar
  34. ITRC (Interstate Technology & Regulatory Council). 1998. Technical and Regulatory Requirements for Enhanced In Situ Bioremediation of Chlorinated Solvents in Groundwater. ITRC, Washington, DC, USA. Accessed June 13, 2009.
  35. ITRC. 2005. Technical and Regulatory Guidance for In Situ Chemical Oxidation of Contaminated Soil and Groundwater, 2nd ed (ISCO-2). ITRC, Washington, DC, USA. Accessed June 13, 2009.
  36. Johnson TL, Scherer MM, Tratnyek PG. 1996. Kinetics of halogenated organic compound degradation by iron metal. Environ Sci Technol 30:2634–2640.CrossRefGoogle Scholar
  37. Kennedy LG, Everett JW, Gonzales J. 2006. Assessment of biogeochemical natural attenuation and treatment of chlorinated solvents, Altus Air Force Base, Altus, Oklahoma. J Contam Hydrol 83:221–236.CrossRefGoogle Scholar
  38. Koenigsberg SS, Sandefur CA. 1999. The use of Hydrogen Release Compound for the accelerated bioremediation of anaerobically degradable contaminants: The advent of time-release electron donors. Remediat J 10:31–54.Google Scholar
  39. Lee RW, Jones SA, Kuniansky EL, Harvey GJ, Sherwood-Lollar B, Slater GF. 2000. Phreatophyte influence on reductive dechlorination in a shallow aquifer contaminated with trichloroethene (TCE). Internat J Phytoremediation 2:193–211.CrossRefGoogle Scholar
  40. Leeson A, Johnson PC, Johnson RL, Coonfare CT, Johnson TL, Bruce CL, Hinchee RE. 2000. Multi-Site Air Sparging and Technology Transfer. Cost and Performance Report. ESTCP, Arlington, VA, USA. Accessed June 13, 2009.
  41. Leeson A, Johnson PC, Johnson RL, Vogel CM, Hinchee RE, Marley M, Peargin T, Bruce CL, Amerson IL, Coonfare CT, Gillespie RD, McWhorter DB. 2002. Air Sparging Design Paradigm. ESTCP, Arlington, VA, USA. Accessed June 13, 2009.
  42. Lendvay JM, Löffler FE, Dollhopf M, Aiello MR, Daniels G, Fathepure BZ, Gebhard M, Heine R, Helton R, Shi J, Krajmalnik-Brown R, Major CL, Barcelona MJ, Petrovskis E, Tiedje JM, Adriaens P. 2003. Bioreactive barriers: A comparison of bioaugmentation and biostimulation for chlorinated solvent remediation. Environ Sci Technol 37:1422–1431.CrossRefGoogle Scholar
  43. Lovley DR, Fraga JL, Blunt-Harris EL, Hayes LA, Phillips EJP, Coates JD. 1999. Humic substances as a mediator for microbially catalyzed metal reduction. Acta Hydrochim Hydrobiol 26:152–157.CrossRefGoogle Scholar
  44. Lowry GV, Reinhard M. 1999. Hydrodehalogenation of 1– to 3–carbon halogenated organic compounds in water using a palladium catalyst and hydrogen gas. Environ Sci Technol 33:1905–1910.CrossRefGoogle Scholar
  45. Major DW, McMaster MM, Cox EE, Edwards EA, Dworatzek SM, Hendrickson ER, Starr MG, Payne JA, Buonamici LW. 2002. Field demonstration of successful bioaugmentation to achieve dechlorination of tetrachloroethene to ethene. Environ Sci Technol 36:5106–5116.CrossRefGoogle Scholar
  46. Mayer HJ, Greenberg MR. 2005. Using integrated geospatial mapping and conceptual site models to guide risk-based environmental clean-up decisions. Risk Anal 25:429–446.CrossRefGoogle Scholar
  47. McCarty PL. 1994. An Overview of Anaerobic Transformation of Chlorinated Solvents. Symposium on Intrinsic Bioremediation of Ground Water. EPA 540/R-94/515. USEPA, Washington, DC, USA, pp 135–142.Google Scholar
  48. McCarty PL, Goltz MN, Hopkins GD, Dolan ME, Allan JP, Kawakami BT, Carrothers TJ. 1998. Full-scale evaluation of in situ cometabolic degradation of trichloroethylene in groundwater through toluene injection. Environ Sci Technol 32:88–100.CrossRefGoogle Scholar
  49. McCutcheon SC, Schnoor JL. 2003. Overview of phytotransformation and control of wastes. In McCutcheon SC, Schnoor JL, eds, Phytoremediation—Transformation and Control of Contaminants. Wiley Press, Hoboken, NJ, USA, pp 3–58.Google Scholar
  50. McGuire TM, Newell CJ, Looney BB, Vangelas KM. 2003. Historical and Retrospective Survey of Monitored Natural Attenuation: A Line of Inquiry Supporting Monitored Natural Attenuation and Enhanced Passive Bioremediation of Chlorinated Solvents. WSRC-TR-2003–00333. Westinghouse Savannah River Company, Aiken, SC, USA. Accessed June 13, 2009.
  51. McNab WW, Ruiz R, Reinhard M. 2000. In-situ destruction of chlorinated hydrocarbons in groundwater using catalytic reductive dehalogenation in a reactive well: Testing and operational experiences. Environ Sci Technol 34:149–153.CrossRefGoogle Scholar
  52. Mravik SC, Sillan RK, Wood AL, Sewell GW. 2003. Field evaluation of solvent extraction residual biotreatment technology. Environ Sci Technol 37:5040–5049.CrossRefGoogle Scholar
  53. Nelson MD, Parker BL, Al TA, Cherry JA, Loomer D. 2001. Geochemical reactions resulting from in-situ oxidation of PCE DNAPL by KMnO4 in a sandy aquifer. Environ Sci Technol 35:1266–75.CrossRefGoogle Scholar
  54. Newman LA, Strand SE, Choe N, Duffy J, Ekuan G, Ruszaj M, Shurtleff BB, Wilmoth J, Heilman P, Gordon MP. 1997. Uptake and transformation of trichloroethylene by hybrid poplars. Environ Sci Technol 31:1062–1067.CrossRefGoogle Scholar
  55. NFESC (Naval Facilities Engineering Service Center). 2001. Guidance for Optimizing Remedial Action Operation. Interim Final Report. SR-2101–ENV. NFESC, Port Hueneme, CA, USA. Accessed June 13, 2009.
  56. NFESC. 2005. Multi-Site In Situ Air Sparging. Cost and Performance Report. NFESC, Port Hueneme, CA, USA. Accessed June 13, 2009.
  57. NRC (National Research Council). 1994. Alternatives to Ground Water Cleanup. National Academies Press, Washington, DC, USA. 336 p.Google Scholar
  58. NRC. 1997. Innovations in Ground Water and Soil Cleanup. National Academies Press, Washington, DC, USA. 310 p.Google Scholar
  59. O’Hannesin SF, Gillham RW. 1998. Long-term performance of an in situ ‘iron wall’ for remediation of VOCs. Ground Water 36:164–170.CrossRefGoogle Scholar
  60. Oldenhuis R, Vink RLJM, Janssen DB, Witholt B. 1989. Degradation of chlorinated aliphatic hydrocarbons by Methylosinus trichosporium OB3b expressing soluble methane monooxygenase. Appl Environ Microbiol 55:2819–2826.Google Scholar
  61. Pollard SJT, Brookes A, Earl N, Lowe J, Kearney T, Nathanail CP. 2004. Integrating decision tools for sustainable management of land contamination. Sci Total Environ 325:15–28.CrossRefGoogle Scholar
  62. Quinn J, Geiger C, Krug T, Major DW, Yoon WS, Gavaskar A, Holdsworth T. 2005. Field demonstration of DNAPL dehalogenation using emulsified zero-valent iron. Environ Sci Technol 39:1309–1318.CrossRefGoogle Scholar
  63. Reynolds GW, Hoff JT, Gillham RW. 1990. Sampling bias caused by materials used to monitor halocarbons in groundwater. Environ Sci Technol 24:135–142.CrossRefGoogle Scholar
  64. Sale TC, Gilbert DM. 2002. Redox Water Treatment System. U.S. Patent No. 6,342,150 B1.Google Scholar
  65. Sale TC, Peterson M, Gilbert D. 2005. Electrically Induced Redox Barriers for Treatment of Groundwater. Final Report submitted to ESTCP, Arlington, VA, USA. Accessed June 13, 2009.
  66. Schnoor JL. 1997. Phytoremediation. Evaluation Report TE-98–01. Ground-Water Remediation Technologies Analysis Center. Pittsburgh, PA, USA.Google Scholar
  67. Schnoor JL, Licht LA, McCutcheon SC, Wolfe NL, Carreira LH. 1995. Phytoremediation of organic and nutrient contaminants. Environ Sci Technol 29:318–323.Google Scholar
  68. Semprini L. 1997. Strategies for the aerobic co-metabolism of chlorinated solvents. Curr Op Biotechnol 8:296–308.CrossRefGoogle Scholar
  69. Siegrist RL, Urynowicz MA, West OR, Crimi ML, Lowe KS. 2001. Principles and Practices of In Situ Chemical Oxidation Using Permanganate. Battelle Press, Columbus, OH, USA. 336 p.Google Scholar
  70. Sorenson KS, Peterson LN, Hinchee RE, Ely RL. 2000. An evaluation of aerobic trichloroethene attenuation using first-order rate estimation. Bioremediation J 4:337–357.CrossRefGoogle Scholar
  71. Sweeney KH, Fischer JR. 1972. Reductive Degradation of Halogenated Pesticides. U.S. Patent No. 3,640,821.Google Scholar
  72. Tiedje JM, Mohn WW. 1992. Microbial reductive dehalogenation. Microbiol Rev 56:482–507.Google Scholar
  73. USEPA (U.S. Environmental Protection Agency). 1998. Technical Protocol for Evaluating Natural Attenuation of Clorinated Solvents in Ground Water. EPA/600/R-98/128. Office of Research and Development, USEPA, Washington, DC, USA.Google Scholar
  74. USEPA. 1999. Groundwater Cleanup: Overview of Operating Experience at 28 Sites. EPA-542–R-99–006. USEPA, Washington, DC, USA.Google Scholar
  75. USEPA. 2000. Introduction to Phytoremediation. EPA/600/R-99/107. National Risk Management Laboratory, USEPA, Cincinnati, OH, USA. Accessed June13, 2009.
  76. USEPA. 2003. Phytoremediation of Groundwater at Air Force Plant 4, Carswell, TX. EPA/540/R-03/506. National Risk Management Laboratory, USEPA, Cincinnati, OH, USA.Google Scholar
  77. USEPA. 2007. Treatment Technologies for Site Cleanup: Annual Status Report. 12th ed. EPA-542–R-07–012. USEPA, Washington, DC, USA. Accessed June 13, 2009.
  78. Vik EA, Bardos P, Brogan J, Edwards D, Gondi F, Henrysson T, Jensen BK, Jorge C, Mariotti C, Nathanail P, Papassiopi N. 2001. Towards a framework for selecting remediation technologies for contaminated sites. Land Contam Reclam 9:119–127.Google Scholar
  79. Vogel TM, McCarty PL. 1985. Biotransformation of tetrachloroethylene to trichloroethylene, dichloroethylene, vinyl chloride, and carbon dioxide under methanogenic conditions. Appl Environ Microbiol 49:1080–1083.Google Scholar
  80. Wackett LP, Gibson DT. 1988. Degradation of trichloroethylene by toluene dioxygenase in whole-cell studies with Pseudomonas putida F1. Appl Environ Microbiol 54:1703–1708.Google Scholar
  81. Watts RJ, Teel AL. 2006. Treatment of contaminated soils and groundwater using ISCO. Pract Period Haz Toxic Rad Waste Mgmt 10:2–9.CrossRefGoogle Scholar
  82. Watts RJ, Sarasa J, Loge FJ, Teel AL. 2005. Oxidative and reductive pathways in manganese-catalyzed Fenton(s reactions. J Environ Eng 131:158–164.CrossRefGoogle Scholar
  83. Weidemeier TH, Swanson MA, Moutoux DE, Gordon EK, Wilson JT, Wilson BH, Kampbell DH, Haas PE, Miller RN, Hansen JE, Chapelle FH. 1998. Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Groundwater. AFCEE, Brooks AFB, TX, USA. Accessed June 13, 2009.
  84. Wilson JT, Wilson BH. 1985. Biotransformation of trichloroethylene in soil. Appl Environ Microbiol 49:242–243.Google Scholar
  85. Wilson JT, Weaver JW, Kampbell DH. 1994. Intrinsic bioremediation of TCE in groundwater at an NPL site in St. Joseph, Michigan. Symposium on Intrinsic Bioremediation of Groundwater. EPA/540/R-94/515. USEPA, Ada, OK, USA.Google Scholar
  86. Zhang W. 2003. Nanoscale iron particles for environmental remediation: An overview. J Nanoparticle Res 5:323–332.CrossRefGoogle Scholar
  87. Zhang W, Wang C, Lien H. 1998. Catalytic reduction of chlorinated hydrocarbons by bimetallic particles. Catalysis Today 40:387–395.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • Hans F. Stroo
    • 1
  1. 1.HydroGeoLogic, Inc.AshlandUSA

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