Abstract
As seen in the previous chapter, potential–pH diagrams (Pourbaix diagrams) are a useful first guide as to the corrosion behavior of many different systems. However, Pourbaix diagrams do not give any information as to corrosion rates. Although a given reaction may be spontaneous, it does not necessarily proceed at a fast rate. The reaction may in fact proceed “slowly” rather than “quickly”, but we cannot determine this difference from thermodynamics alone.
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McCafferty, E. (2010). Kinetics of Corrosion. In: Introduction to Corrosion Science. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-0455-3_7
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