Synthesis and characterization of porous Vycor®7930—MI (M = Li, Ag) composites are discussed. Two types of composites were prepared: sintered composites obtained by classical sintering (CS) and composites obtained by electro-crystallisation (EC). In the case of LiI composites an increase of the conductivity of two orders of magnitude as compared to the conductivity of pure LiI was observed. In such a case good coating of insulating particles and filling of the pores was observed. In the case of AgI the main important finding is the presence of an hysteresis phenomenon in the conductivity versus temperature curve at a temperature close to the transition α ↔ β AgI.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
C.C Liang, J. Electrochem. Soc. 120, 1289 (1973).
J.B. Phipps, D.L. Johnson, D.H. Whitmore, Solid State Ionics 5, 393 (1981).
F.W. Poulsen, N.H. Andersen, B. Kindl, J. Schoonman, Solid State Ionics 9 & 10, 119 (1983).
J. Maier, J. Phys. Chem. Solids 46, 309 (1985).
G. Ardel, D. Golonitsky, E. Peled, Y. Wang, G. Wang, S. Bajue, S. Greenbaum, Solid State Ionics 113–115, 477 (1998).
H. Yamada, A. J. Bhattacharyya, J. Maier, Adv. Funct. Mater. 16, 525 (2006).
H. Maekawa, R. Tanaka, T. Sato, Y. Fujimaki, T. Yamamura, Solid State Ionics 175,281 (2004).
H. Maekawa, Y. Fujimaki, H. Shen, J. Kawamura, T. Yamamura, Solid State Ionics 177, 2711 (2006).
H. Yamada, I. Moriguchi, T. Kudo, Solid State Ionics 176, 945 (2005).
S. Albert, N. Frolet, P. Yot, A. Pradel, M. Ribes, Solid State Ionics 177, 3009 (2006).
S. Albert, N. Frolet, P. Yot, A. Pradel, M. Ribes, Micropor. Mesopor. Mater. 99, 56 (2007).
S. Albert, N. Frolet, P.G. Yot, A. Pradel, M. Ribes, Mater. Sci. Eng. B 150 (3), 199 (2008).
T.H. Elmer (Ed.), Engineered Materials Handbook, Porous and Reconstructed Glasses, Vol. 4: Ceramics and Glasses (ASM International, Materials Park, OH, USA, 1992), p. 427.
Corning©, http://www.corning.com/lightingmaterials/images/Vycor_7930.pdf.
H.P. Hood, M.E. Nordberg, “Treated Borosilicate Glass,” U.S. patent 2,106,744, Feb. 1938.
H.P. Hood, M.E. Nordberg, “Method of Treating Borosilicate Glasses,” U.S. patent 2,286,275, June 1942.
M. Nagai, T. Nishino, Solid State Ionics 53–56, 63 (1992).
M. Nagai, T. Nishino, J. Mater. Synth. Process. 6 (3), 197 (1998).
J.-S. Lee, S. Adams, J. Maier, J. Phys. Chem. Solids, 61, 1607 (2000).
M. Tatsumisago, Y. Shinkuma, T. Minami, Nature 354, 217 (1991).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2009 Springer Science + Business Media B.V
About this paper
Cite this paper
Pradel, A., Yot, P., Albert, S., Frolet, N., Ribes, M. (2009). Nanostructured Ionic Conductors: Investigation Of Sio2−Mi (M = Li, Ag) Composites. In: Reithmaier, J.P., Petkov, P., Kulisch, W., Popov, C. (eds) Nanostructured Materials for Advanced Technological Applications. NATO Science for Peace and Security Series B: Physics and Biophysics. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-9916-8_26
Download citation
DOI: https://doi.org/10.1007/978-1-4020-9916-8_26
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-9915-1
Online ISBN: 978-1-4020-9916-8
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)