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The Chemistry of Ruthenium Oxidation Complexes

  • William P. Griffith
Chapter
Part of the Catalysis by Metal Complexes book series (CMCO, volume 34)

Abstract

This chapter introduces the topic and scope of the book and principally concerns the basic preparation, physical and chemical properties of Ru-based ­oxidation catalysts, then summarising the catalytic oxidations which they accomplish. More detail on these is given in the succeeding four chapters. The major oxidants RuO4 (1.2.1), perruthenate [RuO4] (1.3.1) – mainly TPAP, (nPr4N)[RuO4], ruthenate [RuO4]2− (1.4.1), trans-Ru(O)2(TMP) (1.4.2.5), RuCl2(PPh3)3 (1.9.3) and cis-RuCl2(dmso)4 (1.9.4) are covered in some detail, but many other catalysts are also discussed. In some cases brief comments are made on the mechanisms involved when data on these are given in the cited papers. There is also an Appendix (1.11) which gives brief details on the preparation of four ruthenium oxidation catalysts and selected model oxidations using them.

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Copyright information

© Springer Netherlands 2009

Authors and Affiliations

  1. 1.Department of ChemistryImperial CollegeLondonUnited Kingdom

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