The theoretical analysis and experimental data on the adsorption and catalysis of H - containing molecules: dipole-like H2, H2O and H2S with slight dipole moment. The feature of the spectra of electron states in nanostructures demonstrates mechanisms responsible for the enhanced gas sensitivity and catalysis. Comparison of experimental results on the electro-adsorption phenomena with theory allows to estimate the characteristic energy bands on the surface Ea for different molecules.
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References
Physics base of micro and nanoelectronics, Unoversity, P.H. “BGC”, Kiev (2005).
Y. Zhong, C. Rivas, R. Lake, K. Alam, T. Boyken, Y. Klimeck, Electronic properties of Silicon nanowires, IEEE Transaction on Electron Devices 52, 1097 (2005).
A. Zangwill, Physics of Surfaces, Cambridge University Press (1988).
M.O. Castro Gooyen, Complex Pd-Cu adsorption properties, Surf. Sci. 307– 309, 387 (1994).
V.G. Litovchenko, Models of the adsorption-catalitic canters on transiton metals, Condensed Matter Phys. 1–2, 388 (1998).
V.G. Litovchenko, A.A. Efremov, Ar. Kiv et al., Adsorption-catalytic properties of thin Pd and PdCux films, Phys. Low-Dim. Struct. 3–4, 17 (2004).
V.G. Litovchenko, T.I. Gorbanyuk, A.A. Efremov, A.A. Evtukh, Effect of macrostructure and composition of the top metal electrode on properties of MIC gas sensors, Microelectron. Realibility 40, 821 (2000).
G. Bozzolo, J. Garces, R. Noeble, P. Abel, H. Mosca, Atomic modeling of surface and bulc properties of Cu, Pd and the Cu-Pd system, Progress in Surface Science 73, pp. 79 (2003).
V. Litovchenko, T. Gorbanyuk, O. Efremov et al., Catalytic proporties of ultrathin layers of Pd and alloys, Ukr. Phys. J. 98, 565 (2003).
V.G. Litovchenko, A.A. Efremov, Analyses of ageing mechanisms of gas MIS sensors with Pd(CuxPd) gate, Sensor Electron. Microsyst. Technol. 1–2, 5 (2004).
V.G. Litovchenko, T.I. Gorbanyuk, V.S. Solntsev, A.A. Evtukh, Mechanism of Hydrogen containing and oxygen molecules sensing by Pd- or Cu/Pd-porous Si-Si structures, Appl. Surf. Sci. 234, 262 (2004).
T.I. Gorbanyuk, A.A. Evtukh, V.G. Litovchenko and V.S. Solntsev, Nanoporous silicon doped by Cu for gas-sensing applications, Physica E: Low-dimens. Syst. Nanostruct. 38, 211 (2007).
V.G. Litovchenko, A.O. Grigorev, Calculation of the barriers for QW Structures, Ukr. Phys. J. 52, 17 (2007).
V.G. Litovchenko, Adsorbo-electrical effects in layered structures Insulator-Semiconductors, J. Phys-Chem. 52, 3063 (1978).
V.G. Litovchenko, Changing of the electronic parameters of surface by adsorption, in Collection “Semiconductor techniques and microelectronics, Naukova Dumka, Kiev, 3 (1972).
I. Lungstrem, Adsorption gas sensing, Sensor Actuators 2, 403 (1981).
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Litovchenko, V.G., Solntsev, V.S. (2008). Sensing Effects In The Nanostructured Systems. In: Bonča, J., Kruchinin, S. (eds) Electron Transport in Nanosystems. NATO Science for Peace and Security Series B: Physics and Biophysics. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-9146-9_29
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