Abstract
The results of study oxygen's influence on the radiation-thermal decomposition of n-heptane admixtures in water medium are adduced. The main parameters of radiolysis were changed within the limits: temperature 20–400℃, absorbed dose-0÷16.0 kGy at dose rate 3.2 kGy/h. As a product of decomposition are observed H2, CO, CH4, C2H4, C2H6, C3H8, C3H6, C4H8, hydrocarbons C5-C6. The changes of n-heptane concentration in the reactor also are established. The increasing of n-heptane decomposition rate and decreasing of gas formation rate in presence of O2 are observed. As a result of summarizing of experimental data, the kinetic model of processes has been proposed.
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Mustafayev, I., Rzayev, R., Guliyeva, N. (2007). Radiation-Thermal Purification of Wastewater from Oil Pollution. In: Zaidi, M.K. (eds) Wastewater Reuse–Risk Assessment, Decision-Making and Environmental Security. NATO Science for Peace and Security Series. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-6027-4_31
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DOI: https://doi.org/10.1007/978-1-4020-6027-4_31
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-6026-7
Online ISBN: 978-1-4020-6027-4
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