Abstract
The equation of state and dielectric properties of water near its critical point are studied within the picture that the local structure of a system is mainly formed by the dimers, which rotate almost freely. It is shown that the degree of association is about 0.9. The coordinates of the critical point are successfully reproduced. The value and the temperature dependence of the dielectric permittivity, constructed in the canonical framework are in good agreement with the experimental data.
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Kulinskii, V., Malomuzh, N.P. (2007). Properties of water near its critical point. In: Rzoska, S.J., Mazur, V.A. (eds) Soft Matter under Exogenic Impacts. NATO Science Series II: Mathematics, Physics and Chemistry, vol 242. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-5872-1_19
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DOI: https://doi.org/10.1007/978-1-4020-5872-1_19
Publisher Name: Springer, Dordrecht
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