Skip to main content

STRUCTURAL AND METHODICAL FEATURES OF THE INSTALLATION FOR INVESTIGATIONS OF HYDROGEN-SORPTION CHARACTERISTICS OF CARBON NANOMATERIALS AND THEIR COMPOSITES

  • Conference paper
Hydrogen Materials Science and Chemistry of Carbon Nanomaterials

Abstract

The laboratory setup for investigations of hydrogen capacity of materials has been created at the Institute for Problems of Materials Science of NAS of Ukraine. It completely meets the modern requirements for the experimental equipment of this class. The setup design makes it possible to investigate hydrogen-sorption characteristics of different materials with low specific density, including nanocarbon structures and composites on their basis, by the volumetric method in the pressure range between 0.01 and 16 MPa H2 and at temperatures from 77 K to 1273 K. The setup provides a sufficient degree of accuracy. It is equipped with a metal-hydride unit for hydrogen storage/compression. The design and service conditions of this device are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Schlapbach L. Materials Research Bulletin. - 2002. - V. 27. - P. 675.

    CAS  Google Scholar 

  2. Shigematsu K., Abe K., Mitani M., Tanaka K. Chem. Express. - 1992. -V.7, N.12. - P. 37.

    Google Scholar 

  3. Hirsch A.H. The chemistry of the fullerenes. - Stuttgart: Georg. Thieme Verlag. - 1994. - 203 p.

    Google Scholar 

  4. Lobach A.S., Tarasov B.P., Shul’ga Yu.M., Perov A.A., Stepanov A.N. The D2 reaction with palladium fulleride C60Pd4,9 // Izv. RAN., Ser. khim. - 1996. - N1. - P. 483-484 (in Russian).

    Google Scholar 

  5. Drelinkiewicz A., Byszewski P., Bielanski A. Catalytic hydrogenation of C60 fullerene // React. Kinet. Catal. Lett. - 1996. - V.59, N.1. - P. 19–27.

    Article  CAS  Google Scholar 

  6. Nozu R., Matsumoto O. Hydrogenation of C60 by electrolysis of KOH-H2O solution // J. Electrochem. Soc. - 1996. - V. 143, N.6. - P. 1919–1923.

    Article  CAS  Google Scholar 

  7. Gol’dshleger N.F., Moravsky A.P. Hydrides of the fullerenes // Uspekhi khimii. - 1997. - V. 66, N 4. - P. 353–375 (in Russian).

    CAS  Google Scholar 

  8. Tarasov B.P., Fokin V.N., Moravsky A.P., Shul’ga Yu.M., Yartys’ V.A., Schur D.V. Promotion of fullerene hydride synthesis by intermetallic compounds. In: Proceed. of 12th World Hydrogen Energy Conference. - Buenos Aires, Argentina. - 1998. - V. 2. - P. 1221–1230.

    CAS  Google Scholar 

  9. Dresselhaus M.S., Williams K.A., Eklund P.C. Hydrogen absorption in carbon materials // MRS Bulletin. - 1999. - V.24, N. 11. - P. 45–50.

    CAS  Google Scholar 

  10. Trefilov V.I., Schur D.V., Tarasov B.P., Shul’ga Yu.M., Chernogorenko A.B., Pishuk V.K., Zaginaychenko S.Yu. Fullerenes is a basis of future materials. - Kiev: Izd. ADEF. - 2001. - 148 p.

    Google Scholar 

  11. A Multiyear Plan for the Hydrogen R&D Program. Rationale, Structure, and Technology Roadmaps, Office of Power Delivery, Office of Power Technologies, Energy Efficiency and Renewable Energy, U.S. Department of Energy, August 1999.

    Google Scholar 

  12. Tarasov B.P., Gol’dshleger N.F., Moravsky A.P. Hydrogen-containing compounds of carbon nanostructures // Usp. khim. - 2001. - V. 70, N2. - P.149–166 (in Russian).

    Google Scholar 

  13. Dantzer P. Hydrogen in Metals III. Properties and Applications.- Ed. by H. Wipf, Springer-Verlag. - 1997. 1997–279 p.

    Google Scholar 

  14. Sandrock G., Suda S., Schlapbach L. Applications.- Hydrogen in Intermetallic Compounds. II. Surface and Dynamic Properties, Applications. - Ed. by L. Schlapbach, Springer-Verlag. - 1992. 1992–197 p.

    Google Scholar 

  15. Sandrock G. J. Alloys and Compounds. - 1999. - V. 293–295. - P. 877.

    Article  Google Scholar 

  16. Bowman R.C. (Jr.), Fultz B. Metallic hydrides I: Hydrogen storage and other gas applications.- Materials Research Bulletin. - 2002. - V. 27, N. 9. - P. 688.

    CAS  Google Scholar 

  17. Joubert J.-M., Latroche M., Percheron-Guegan A. Metallic hydrides II: Materials for electrochemical storage. - Materials Research Bulletin. - 2002. - V. 27, N. 9. - P. 694.

    CAS  Google Scholar 

  18. Akiba E., Okada M. Metallic hydrides III: Body-centered cubic solid solution alloys.- Materials Research Bulletin. - 2002. - V. 27, N. 9. - P. 699.

    CAS  Google Scholar 

  19. Massalski T.B. Binary Alloy Phase Diagrams. American Society for Metals. Metals Park. Ohio. - 1986, 1987. - V. 1, 2. - 2224 p.

    Google Scholar 

  20. Hansen M., Anderko K. Structures of binary alloys. - M.: Metallurgizdat, 1962. - V. 1, 2. - 1188 p. (in Russian).

    Google Scholar 

  21. Shank F.A. Structures of binary alloys. - M.: Metallurgiya, 1973. - 760 p. (in Russian).

    Google Scholar 

  22. Savitskiy E.M., Terekhova V.F. Constitution diagrams of lanthan alloy with cerium and with calcium // Zhurnal neorganicheskoy khimii. - 1958. - V. 3, N 3. - P. 756–762 (in Russian).

    Google Scholar 

  23. Klimenko A.V., Seunjens J., Miller L.L., Beaudry B.J., Jacobson R.A., Gschneidner K.A. (Jr.) Structure of LaNi2,286 and the La-Ni system from LaNi1,75 to LaNi2,50 // J. Less-Common Met. - 1988. - V. 144. - P. 133–141.

    Article  CAS  Google Scholar 

  24. Pan Y.Y., Nash P., La-Ni (Lanthanum-Nickel)”, Phase Diagrams of Binary Nickel Alloys, P. Nash, Ed., ASM International, Materials Park, OH. - 1991. - P. 183–188.

    Google Scholar 

  25. Zhang D., Tang J., Gschneidner K.A. (Jr.) A redetermination of the La-Ni phase diagram from LaNi to LaNi5 (50-83,3 at.% Ni) // J. Less-Common Met. - 1991. - V. 169. - P. 45–53.

    Article  CAS  Google Scholar 

  26. Buschow K.H.J., van Mal H.H. Phase relations and hydrogen absorption in the lanthanum-nickel system // J. Less-Common Met. - 1973. - V. 29. - P. 203.

    Article  Google Scholar 

  27. Xinghang, Wang Zhigum, Lin Guoguan, Zhang Weijing, Pan Shuning // Proc. 61th, Nat. Symp. Phase Diagr., Shenyang. Now. - 1990. - V. 20-24. - P. 125–126.

    Google Scholar 

  28. Vogel R., Iandelli A., Rolla L. Z. Metallkd. - 1947. - V. 38. - P. 97–103 (in German).

    Google Scholar 

  29. WiHenberg L.J., Grove G.R. U.S. At. Energy Comm., MLM-1184. - 1963. - V. 10–11; MLM-1199. - 1963. - P. 6–7.

    Google Scholar 

  30. Gebhart I.M., Etter D.E. III, Tucker P.A. “Proc. 6th RaRe Earth Res. Conf.”, 1967. - P. 452–457.

    Google Scholar 

  31. Gscheidner K.A., Verkode M.E. Document IS - RIC-7, 27–29 (1974).

    Google Scholar 

  32. Duisemaliev U.K. Cerium solubility in nickel and mechanical properties in nickel-cerium alloys // Zhurnal neorganicheskoy khimii. - 1964. - V. 9. - N 3. - P. 755–756.

    CAS  Google Scholar 

  33. Kocherzhinsky Yu.A., Shilkin E.A., Vasilenko V.I. Apparatus for differential thermal analysis with thermovapour sensor up to 2200°C. // Diagrammy sostoyaniya metallicheskikh system. - M.: Nauka, 1971. - P. 245–249.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2007 Springer

About this paper

Cite this paper

SAVENKO, A. et al. (2007). STRUCTURAL AND METHODICAL FEATURES OF THE INSTALLATION FOR INVESTIGATIONS OF HYDROGEN-SORPTION CHARACTERISTICS OF CARBON NANOMATERIALS AND THEIR COMPOSITES. In: Veziroglu, T.N., et al. Hydrogen Materials Science and Chemistry of Carbon Nanomaterials. NATO Security through Science Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-5514-0_47

Download citation

Publish with us

Policies and ethics