Skip to main content

THE CONFIGURATIONAL HEAT CAPACITY OF FULLERITE OVER THE REGION OF SCL ↔ FCCL PHASE TRANSITION

  • Conference paper
Hydrogen Materials Science and Chemistry of Carbon Nanomaterials

Abstract

The statistical calculation of the temperature dependence of heat capacity of ordering two-component fullerite has been fulfilled in the approximation of pair interaction between fullerenes by the method of average energies in the model of spherically symmetrical stiff balls.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Jin Y., Cheng J., Varma-Nair M., Liang G., Fu J., Wunderlich B., Xiang X.-D., Mostovoy R., Zettl A.K. Thermodynamic characterization of C60 by differential scanning calorimetry // Journ. Phys. Chem. - 1992. - V. 96. - P. 5151-5156.

    Article  CAS  Google Scholar 

  2. Lebedev B.V., Zhogova K.B., Bykova T.A., Kaverin S.B., Karnatsevich V.L., Lopatin M.A. Thermodynamics of C60 fullerene in the 0-340 K region // Izv. RAN. Ser. khim. - 1996. - P. 2229–2233 (in Russian).

    Google Scholar 

  3. Dikiy V.V., Kabo G.Ya. Thermodynamical properties of C60 and C70 fullerenes (overview) // Usp. khimii. - 2000. - V. 69. - P. 107–117 (in Russian).

    Google Scholar 

  4. Kabo A.G., Diky V.V. Details of calibration of a scanning calorimeter of the triple heat bridge type // Thermochim. Acta. - 2000. - V. 347. - P. 79–84.

    Article  CAS  Google Scholar 

  5. Dikiy V.V., Kabo A.G., Zhura L.S. Measurements of high-temperature capacity of C60 fullerene in a solid state // Fullerenes and fullerene-like structures. - Minsk: BSU, NAS of Belarus. - 2000. - P. 180–184 (in Russian).

    Google Scholar 

  6. David W.I., Ibberson R.M., Dennis T.J., Harr J.P., Prassides K. Structural phase transitions in a solid of carbon sixty-atom fullerene molecules // Europhys. Lett. -1992. - V.18, N3. - P. 219–225.

    Article  ADS  CAS  Google Scholar 

  7. Blinc R., Selinger J., Dolinsek J., Arcon D. Two - dimensional 13C NMR study of orientational ordering in solid C60 // Phys. Rev. B. - 1994. - V. 49. - P. 4993– 5002.

    Article  ADS  CAS  Google Scholar 

  8. Brazhkin V.V., Lyapin A.G. Transformation of C60 fullerite at high pressures snd temperatures // Usp. khim. nauk. - 1996. - V. 166, N. 8. - P. 893–897 (in Russian).

    CAS  Google Scholar 

  9. Tareeva E.E., Schelkacheva T.I. Orientational ordering in solid C60: method of branching // Teoretich. i matem. fizika. - 1999. - V. 121, N 3. - P. 479–491 (in Rus).

    Google Scholar 

  10. Shteinman E.A. Investigation of nature and properties of structural defects in fullerites // Nauka proizvodstvu. - 2001. - N2. - P. 61–70 (in Russian).

    Google Scholar 

  11. Makarova T.L. Electrical and optical properties of monomerical and polymerical fullerenes (overview) // Fizika i tekhnika poluprovodnikov. - 2001. - V.35, N3. - P. 257–293 (in Russian).

    Google Scholar 

  12. Sundqvist B. Fullerenes under high pressures // Adv.Phys.-1999.-V.48,N1.-P. 1–134.

    Article  ADS  CAS  Google Scholar 

  13. Boba M.S., T.S.L., Balssubtamaian R. et al. Studies on the thermodynamics of the C60-C70 binary system // Journ. Phys. Chem. - 1994. - Vol. 98. - P. 1333– 1340.

    Article  Google Scholar 

  14. Kniaz K., Fisher J.E., Girifalco L.A. Fullerene alloys // Sol. State Comm. - 1995. - Vol. 96. - P. 739–743.

    Article  CAS  Google Scholar 

  15. Havlik D., Schranz W., Haluska M., Kuzmany N., Rogl P. Thermal expansion measurements of C60-C70 mized crystals // Sol. State Comm. - 1997. - Vol. 104. - P. 775–779.

    Article  CAS  Google Scholar 

  16. Bezmelnitsyn V.N., Eletsky A.V., Okun’ M.V. Fullerenes in solutions // Usp. fiz. nauk. - 1998. - V. 168, N11. - P. 1195–1221 (in Russian).

    Article  CAS  Google Scholar 

  17. Vovk O.M., Isakina A.P., Garbuz A.S., Kravchenko Yu.S. Solid solutions of C60-C70 fullerenes produced from hexane-toluene solution // Fullerenes and fullerene-like structures.-Minsk: BSU, NAS of Belarus. - 2000. - P. 70–76. (in Rus.).

    Google Scholar 

  18. Girifalco LA. Molecular properties of C60 in the gas and solid phases // Journ. Phys. Chem. - 1992. - V. 96. - P. 858–861.

    Article  Google Scholar 

  19. Zaginaichenko S.Yu., Matysina Z.A., Schur D.V. Theoretical investigation of hydrogen solubility in FCC fullerite // Nanosystems, nanomaterials, nanotechnologies. - 2005. - Vol. 3, N. 2. - P. 331–354 (in Russian).

    Google Scholar 

  20. Matysina Z.A., Molodkin V.B., Zaginaichenko S.Yu., Schur D.V. Phase transformations in carbon materials // Nanosystems, nanomaterials, nanotechnologies. - 2005. - Vol. 3, N. 1. - P. 11–38 (in Russian).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2007 Springer

About this paper

Cite this paper

MATYSINA, Z., ZAGINAICHENKO, S.Y., SCHUR, D., TRIFONOVA, T. (2007). THE CONFIGURATIONAL HEAT CAPACITY OF FULLERITE OVER THE REGION OF SCL ↔ FCCL PHASE TRANSITION. In: Veziroglu, T.N., et al. Hydrogen Materials Science and Chemistry of Carbon Nanomaterials. NATO Security through Science Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-5514-0_27

Download citation

Publish with us

Policies and ethics