Abstract
Structure, microstructure, dielectric and transport properties of ceramics (La0.9Sr0.1)[(Gal-xMx)0.8Mg0.2]Oy with M=Fe, Ni, Mn have been studied. Substitution of Fe, Ni, Mn for gallium leads to the perovskite lattice contraction at low concentrations of the transition elements, while to the increasing in the unit cell volume due to the transition element valence changing at higher concentrations. For all the systems studied transformation from pure ionic to the mixed ionic-electronic conductivity is observed at increasing the transition ions content. Concentration dielectric-metal transitions have been revealed in the Mn-containing system, magnetic phase transitions have been observed in compositions with x=0.8 and 1.0 at low temperatures.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
T. Seiyama, Catalysis Reviews. Science and Engineering, 1992, 34, 281.
Z. Zhang, X. E. Verykios, and M. Baerns, Catalysis Reviews. Science and Engineering, 1994. 36, 507.
E. L. L. Nagaev, Soviet Phys. Uspekhi, 1996, 166, 833.
J. H. Lunsford, Catalysis Today, 2000, 63, 165.
J. E. ten Elshof, H. J. M. Bouwmeester, H. Verweeij, Appl. Catal., 1995, A130, 195.
U. Balachandran, J. T. Dusek, S. M. Sweeney, et al, Amer. Ceram. Soc. Bull., 1995, 74, 71.
Y. Lu, A. G. Dixon W. R. Moser Y. H. Ma, U. Balachandran, J. Membr. Sci., 2000, 170, 27.
B. J. Mitchell, J. W. Richardson, C. D. Murphy, Materials Research Bulletin, 2000, 35, 491.
T. Ishihara, H. Matsuda, Y. Takita, J. Amer. Chem. Soc., 1994, 116, 3801.
P. Huang, A. Petric, J. Electrochem. Soc., 1996, 143, 1644.
V. Feng, J. B. Goodenough, J. Amer. Ceram. Soc., 1996, 79, 1100.
K. Huang, R. Tichy, J. B. Goodenough, J. Amer. Ceram. Soc., 1998, 81, 2565.
T. Inagaki, K. Miura, H. Yoshida, H. Fujita, Solid State Ionics, 1999, 118, 265.
T. Mathews, J. R. Sellar, Solid State Ionics, 2000, 135, 411.
L. Vasylechko, V. Vashook, D. Savitskiiet al. JSolid State Chem., 2003, 172, 396.
T. Yu. Glavatskikh, N. U. Venskovsky, G. M. Kaleva, A. V. Mosunovet al, Inorganic materials, 2001, 37, 764 (translated from Russian).
V. V. Aleksandrovskii, N. U. Venskovskii, G. M. Kaleva, E. D. Politovaet al, Inorganic materials, 2001, 37, 764 (translated from Russian).
V. V. Aleksandrovskii, N. U. Venskovskii, G. M. Kaleva, et al, Bull. Russian Acad. Sci. , Physics, 2001, 65, 1237 (translated from Russian).
W. Archibald, J. -S. Zhou, and J. B. Goodenough, Phys. Rev., 1996, 53, 14445.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2004 Springer Science+Business Media Dordrecht
About this paper
Cite this paper
Politova, E.D. et al. (2004). Structure, Microstructure and Transport Properties of Mixed Conducting Lanthanum Gallate Based Perovskite Ceramics. In: Orlovskaya, N., Browning, N. (eds) Mixed Ionic Electronic Conducting Perovskites for Advanced Energy Systems. Nato Science Series, vol 173. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-2349-1_18
Download citation
DOI: https://doi.org/10.1007/978-1-4020-2349-1_18
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-1944-9
Online ISBN: 978-1-4020-2349-1
eBook Packages: Springer Book Archive