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Mineralogy of Red Soils in Southern China in Relation to Their Development and Charge Characteristics

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The Red Soils of China

Abstract

The mineral composition of the different size fractions of red soils from southern China was investigated using X-ray diffraction (XRD), infrared spectroscopy analysis (IR), transmission electron microscopy (TEM) and chemical methods. Surface charge and phosphate adsorption characteristics of the soils were also determined. The results showed that kaolinite and/or halloysite are the most common clay minerals in the soils. However, the abundance and mineral composition of the soils varied with latitude, elevation, parent materials, and topographic position. Types of kaolin mineral in the soils changed with soil types, the relative proportion of kaolinite increasing with weathering degree. Under current subtropical climates, a transformation process of mica to vermiculite also occurs in these soils. Goethite and hematite are the only two crystalline Fe oxides occurring in significant quantity in these soils. The goethite/(goethite+hematite) ratios ranged from 0 to 1, being the highest in yellow soils, and the lowest in soils derived from purple sandstone where only hematite was present. Substitution of Al in goethite ranged from 6.6 to 29.9 mole % with a mean value of 16.7 mole %Al, while substitution of Al in hematite ranged from 0 to 12.1 mole %. The values of Al substitution of hematite were closely related to the corresponding values of the coexisting goethite. Phosphorus (P) adsorption of all the soils studied was well described by the Freundlich and Langmuir equations. The maximum buffering capacity (MBC) of P ranged from 66.5 to 9880 mg kg-1 in the increasing order of red-purple sandstone soil < purple sandstone soil < red sandstone soil < red soil < lateritic red soil < yellow soil < latosol. The zero point of charge (ZPC) values obtained by salt titration-potential titration varied from 3.03 to 5.49, the highest value being found in the latosol derived from basalt and the lowest in purple sandstone soil. Correlation analysis indicates that the main minerals responsible for phosphate adsorption in the soils were gibbsite, amorphous iron oxides and kaolin, whereas the PZC was mainly controlled by kaolin, gibbsite and oxides.

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References

  • Anand, R.R. and R.J. Gilkes. 1987. Iron oxides in lateritic soil from western Australia. J. Soil Sci. 38: 607–622.

    Article  CAS  Google Scholar 

  • Barron,V., M. Herruzo, and J. Torrent. 1988. Phosphate adsorption by aluminous hematities of different shapes. Soil Sci. Soc. Am. J. 52: 647–651.

    Article  CAS  Google Scholar 

  • Bigham, J.M., D.C. Golden, S.W. Boul, S.B. Weed, and L.H. Bowen. 1978. Iron oxide mineralogy of well drained Utisols and Oxisols:II.Influence on color, surface area and phosphate retention. Soil Sci. Soc. Am. J. 42: 825–830.

    Article  CAS  Google Scholar 

  • Chinese Soil Taxonomy Research Group, Institute of Soil Science, Academia Sinica. 1995. Chinese Soil Taxonomy (Revised proposal) (in Chinese). Chinese Agri. Sci. Tech.Press, Beijing.pp. 58–60.

    Google Scholar 

  • Churchman, G.J., J.S. Whitton, and G.G.C. Claridge. 1984. Intercalation methods using formamide for differentiating halloysite from kaolinite.Clays and Clay Minerals. 32 (4): 241–248

    CAS  Google Scholar 

  • FAO/UNESCO. 1974. Soil Map of the World 1:5000000.vol. 1, Legend. UNESCO,Paris.

    Google Scholar 

  • Fitzpatrick,R.W. and U. Schwertmann. 1982. Al-substituted goethite-an indicator of pedogenic and other weathering environments in southern Africa. Geoderma. 27: 335–347

    Article  CAS  Google Scholar 

  • Group of Utilization, Improvement and Regionation of Red Soils and Yellow Soils. 1985. Utilization, Improvement and Regionization of Red Soil and Yellow Soil Region. Beijing: Chinese Agricultural Press.

    Google Scholar 

  • Hseung,Y. and Q.K. Li. 1990. Soils of China, second edition, Beijing: Science Press.

    Google Scholar 

  • Hue, N.V. 1991. Effects of organic acids/anions on P sorption and phytoavailability in soils with different mineralogies. Soil Sci. 152: 463–471.

    Article  CAS  Google Scholar 

  • Institute of Soil Science, Academia Sinica. 1978. Methods of Soil Physical and Chemical Analysis (in Chinese). Shanghai Sci. Tech. Pub. Shanghai. pp. 132–517.

    Google Scholar 

  • Jones, R.C. 1981. X-ray diffraction line profile analysis vs. phosphorus sorption by 11 Puerto Rican soils. Soil Sci. Soc. Am. J. 45: 818–825.

    Article  CAS  Google Scholar 

  • Kampf,N.and U. Schwertmann. 1982. The 5 M NaOH concentration treatment for iron oxides in soils. Clays and Clay Minerals. 30: 401–408.

    Google Scholar 

  • Karim,M.I. and W.A. Adams. 1984. Relationships between sesquioxides, kaolinite and phosphate sorption in a catena of Oxisols in Malawi. Soil Sci. Soc. Am. J. 48: 406–409.

    Article  CAS  Google Scholar 

  • Li, Q.K. (ed.). 1983. Red Earths of China (in Chinese). Sci. Press, Beijing. pp. 74–127.

    Google Scholar 

  • Luo, J.X., D.Y. Yang, and M.Y. Jiang. 1993. Mineralogical characteristics of yellow-red soils derived from granite, Pedosphere. 3(3):247–252

    Google Scholar 

  • Macias Vasques. F. 1981. Formation of gibbsite in soils and saprolites of temperate humid zones. Clay Minerals. 16: 43–52

    Article  Google Scholar 

  • Mehra, O.P. and M.L. Jackson. 1960. Iron oxide removal from soils and clay by a dithionite-citrate system buffered with sodium bicarbonate. In: Clays and Clay Minerals. Proc.7th Natl. Congr. Pergamon, London.

    Google Scholar 

  • Moshi,A.O.,A. Wild, and D.J. Greenland. 1974. Effect of organic matter on the charge and phosphate adsorption characteristics of Kikuyu red clay from Kenya. Geoderma. 11: 275–285.

    Article  Google Scholar 

  • Sakurau, K., Y. Ohdate, and K. Kyuma. 1988. Comparison of salt titration and potentiometric titration methods for the determination of zero point of charge. Soil Sci. Plant Nutr. 34: 171–182.

    Article  Google Scholar 

  • Schwertmann, U. 1964. The differentiation of iron oxide in soils by a photochemical extraction with acid ammonium oxalate. Z. Pflanzenernaehr. Dueng. Bodenkund. 105: 194–201.

    Article  CAS  Google Scholar 

  • Schwertmann, U. 1979. The influence of aluminum on iron oxides. II.Preparation and properties of Al-substituted hematite. Clays and Clay Minerals. 27: 105–112.

    Article  CAS  Google Scholar 

  • Schwertmann, U. 1985. The effect of pedogenic environments on iron oxide minerals. Advances in Soil Science. 1: 171–200.

    Article  CAS  Google Scholar 

  • Schwertmann, U. and N. Kampf. 1985. Properties of goethite and hematite in kaolinitic soils of southern and central Brazil. Soil Science. 139: 344–350.

    Article  CAS  Google Scholar 

  • Schwertmann, U., R.W. Fitzpartrick, R.M. Taylor, and D.G. Lewis. 1979. Influence of aluminium on iron oxides. II. Preparation and properties of Al-substituted hematites. Clays and Clay Minerals. 27: 105–112.

    Google Scholar 

  • Schulze, D.G. 1984. The influence of aluminium on iron oxides. VIII.Unit cell dimensions of Alsubstituted goethites and estimation of Al from them. Clays and Clay Minerals. 32: 36–44.

    Article  CAS  Google Scholar 

  • Sibanda, H.M.and S.D. Young. 1986. Competitive adsorption of humic acids and phosphate on goethite, gibbsite and two tropical soils. J. Soil Sci. 37: 197–204.

    Article  CAS  Google Scholar 

  • Singh,B. and R.J. Gilkes. 1992. Properties and distribution of iron oxides and their association with minor elements in the soils of southern-western Australia. Journal of Soil Science. 43: 77–98.

    Article  CAS  Google Scholar 

  • Torrent, J., U. Schwertmann, and D.G. Schulze. 1980. Iron oxide mineralogy of some soils of two river terrace sequences in Spain. Geoderma. 23: 191–208.

    Article  CAS  Google Scholar 

  • Torrent, J.and G. Cabedo. 1986. Sources of iron oxides in reddish brown soil profiles from calcarenites in southern Spain. Geoderma. 37: 57–66.

    Article  CAS  Google Scholar 

  • Torrent, J., V. Barron, and U. Schwertmann. 1990. Phosphate adsorption and desorption by goethite differing in crystal morphology. Soil Sci. Soc. Am. J. 54: 1007–1012.

    Article  Google Scholar 

  • Wilson, M.J. 1994. Clay Mineralogy: Spectroscopic and Chemical Determinative Methods. Chapman and Hall, London.

    Book  Google Scholar 

  • Yang, D.Y. and M.Y. Jiang. 1991. Clay mineral composition and evolution of red earths and yellow earths derived from granite in eastern China. Acta Pedologica Sinica. 28: 276–283

    CAS  Google Scholar 

  • Zhang, M.K. 1990. Significance of soil iron forms on classification of red earth and yellow earth in Zhejiang province (in Chinese). Acta Agriculturae Universities Zhejiangensis. 16(1): 42–56.

    Google Scholar 

  • Zhang, M.K. 1991. Properties and classification of soils derived from middle-late Quaternary sediments in the mid-lower reaches of the Yangtze river (in Chinese), Ph.D. thesis, Zhejiang Agricultural University.

    Google Scholar 

  • Zhang, M.K. 1996. Composition and pedogenetic significance of iron oxides of soils derived from metamorphic rock in southern Zhejiang province(in Chinese). Bulletin of Science and Technology. 12 (1): 54–58.

    Google Scholar 

  • Zhang, M.K. 1997a. Occurrence and origin of crystalline iron oxides in paddy soils derived from red earth, Journal of Zhejiang Agricultural University. 23 (5): 589–594.

    CAS  Google Scholar 

  • Zhang, M.K. 1997b. Study on structural disorder of kaolinite in red soils (in Chinese). Bulletin of Science and Technology. 14 (1): 17–21.

    Google Scholar 

  • Zhang, M.K. 1999. Identification of titanium oxides in soils (in Chinese). Soils. 31(1): 46–49.

    CAS  Google Scholar 

  • Zhang, M.K., M.J. Wilson, and Z.L. He. 1998a. Iron oxides and their relations to colors in some soils of southern China. Pedosphere. 8: 53–58.

    Google Scholar 

  • Zhang, M. K., M.J. Wilson, Z.L. He, L. Clark, and D.M.L.Duthie. 1998b. Phosphate adsorption and surface charge characteristics and their relations to mineralogy of some soils from southern China. Pedosphere. 8: 297–305.

    CAS  Google Scholar 

  • Zhang, M.K., M.J. Wilson, and Z.L. He. 2000. Mineralogy of Zhijiang plinthitic red clay in Hangzhou city (in Chinese), Journal of Zhejiang University (Agriculture and Life Sciences). 26 (1): 22–24.

    Google Scholar 

  • Zhang, M.K., Z.L. He, and M.J. Wilson. 1999a. Mineralogy of three soils derived from red and purple sandstone in Zhejiang province, China (in Chinese). Acta Pedologica Sinica. 36: 308–317.

    CAS  Google Scholar 

  • Zhang, M.K., Z.L. He, M.J. Wilson. 1999b. Identification of plumbogummite group minerals in red soils by the X-ray diffraction method, Chinese Journal of Soil Science, 29 (5): 196–198.

    Google Scholar 

  • Zhang, M. K., Z.L. He, and M.J. Wilson. 1997. Profile development and mineral evolution of soils in the subtropical hilly regions. In: Huang C.Y and Z. M. Xie (ed). Research and Application of Soil Chemistry. p 122–128. Chinese Environmental Science Press, Bejiang.

    Google Scholar 

  • Zhang, M.K., Z.L. He, and M.J. Wilson. 1998c. Identification of kaolin-group in red soils. Soils. 30: 106–110.

    CAS  Google Scholar 

  • Zhang, M.K., M.J. Wilson, Z.L. He, D.M.L. Duthie. 1998d. Mineralogical characteristics of some red soils in southern China, Journal ofZhejiang Agricultural University. 24 (4): 449–455.

    CAS  Google Scholar 

  • Zhang, X.N. 1963. Clay mineralogy of tropical soils in the Hainan Island. Acta Pedological Sinica. 11: 56–69.

    Google Scholar 

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Authors and Affiliations

  1. Department of Resource Science, College of Resource and Environmental Sciences, Zhejiang University, Hangzhou, Zhejiang Province, 310029, China

    Mingkui Zhang & Zhenli He

  2. Macaulay Land Use Research Institute, Aberdeen, AB15 8QH, UK

    M. J. Wilson

Authors
  1. Mingkui Zhang
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  2. M. J. Wilson
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  3. Zhenli He
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Editor information

Editors and Affiliations

  1. Macaulay Land Use Research Institute, Aberdeen, UK

    M. J. Wilson

  2. Zhejiang University, Hangzhou, People’s Republic of China

    Zhenli He  & Xiaoe Yang  & 

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© 2004 Kluwer Academic Publishers

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Zhang, M., Wilson, M.J., He, Z. (2004). Mineralogy of Red Soils in Southern China in Relation to Their Development and Charge Characteristics. In: Wilson, M.J., He, Z., Yang, X. (eds) The Red Soils of China. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-2138-1_4

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  • DOI: https://doi.org/10.1007/978-1-4020-2138-1_4

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-6597-1

  • Online ISBN: 978-1-4020-2138-1

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