Abstract
The use of optical spectroscopy for structural studies is well established in high-pressure experiments using optically transparent anvil cells [1–3]. Electronic spectroscopy (UVVIS) and vibrational (IR, Raman) spectroscopy are often used as complementary tools in the structural characterization of materials under extreme conditions. Aside from the standard techniques such as X-ray diffraction (XRD) or absorption (XAS), spectroscopy offers a simple way for obtaining structural information either from the bulk or at a local level. From the splitting pattern of the vibrational peaks or the crystal-field (CF) electronic spectra.
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Rodriguez, F. (2004). Correlation Between the Structure and Optical Properties of Perovskites at High Pressure. In: Katrusiak, A., McMillan, P. (eds) High-Pressure Crystallography. NATO Science Series, vol 140. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-2102-2_21
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DOI: https://doi.org/10.1007/978-1-4020-2102-2_21
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