Abstract
In this chapter we shall be mainly concerned with interactions of the Lewis acid-base type. Most of these interactions will involve the organometallic compound acting as a Lewis acid and receiving electrons from some donor species. It is also possible, in a formal sense, to regard an organometallic compound RM as arising from combination of the base R− and acid M+. These, and related, ideas have considerable impact on structure and reactivity in organometallic chemistry. The aim of this chapter is, primarily, to show that coordination is a concept which can be used to unify and systematise much material that occurs elsewhere in this book.
Preview
Unable to display preview. Download preview PDF.
References
Ahrland, S., Chatt, J., and Davies, N. R. (1958). Quart. Rev. (Lond.) 12, 265
Almemark, M., and Åkermark, B. (1978). J. chem. Soc. chem. Commun. 66
Anderson, G. K., and Cross, R. J. (1984). Acc. chem. Res. 17, 67
Berke, H., and Hoffmann, R. (1978). J. Am. chem. Soc. 100, 7224
Braterman, P. S., Cross, R. J., and Young, G. B. (1977). J. chem. Soc. Dalton Trans. 1892
Calderazzo, F. (1977). Angew. Chem. int. Edn Engl. 16, 299
Chambers, R. L., and Jensen, F. R. (1978). In Aspects of Mechanism and Organometallic Chemistry (J. H. Brewster, ed.). Plenum Press, New York, p. 169
Gladysz, J. A. (1982). Adv. organomet. Chem. 20, 1
Gough, R. G., and Dixon, J. A. (1968). J. org. Chem. 33, 2148
Jensen, W. B. (1978). Chem. Rev. 78, 1
Kochi, J. K. (1978). Organometallic Mechanisms and Catalysis. Academic Press, New York
Kochi, J. K. (1980). Pure appl. Chem. 52, 571
Krusic, P. J., Stoklosa, H., Manzer, L. E., and Meakin, P. (1975). J. Am. chem. Soc. 97, 667
Lappert, M. F., and Lednor, P. W. (1976). Adv. organomet. Chem. 14, 345
Mente, D. C., Mills, J. L. and Mitchell, R. E. (1975). Inorg. Chem. 14, 123
Noack, K., and Calderazzo, F. (1967). J. organomet. Chem. 10, 101
Nugent, W. A., and Kochi, J. K. (1977). J. organomet. Chem. 124, 37
Pearson, R. G. (1963). J. Am. chem. Soc. 85, 3533
Pearson, R. G. (1968). J. chem. Educ. 45, 581
Thiele, K.-H. (1972). Pure appl. Chem. 30, 575
van Koten, G., Jastrzebski, J. T. B. H., Noltes, J. G., Spek, A. L., and Schoone, J. C. (1978). J. organomet. Chem. 148, 233
Werner, H., and Feser, R. (1979). Angew. Chem. int. Edn Engl. 18, 157
Wilkinson, G. (1974). Science 185, 109
Wong, C. L., and Kochi, J. K. (1979). J. Am. chem. Soc. 101, 5593
General Reading
Daub, G. W. (1977). Oxidatively induced cleavage of transition metal carbon bonds. Prog. inorg. Chem. 22, 409
Henrici-Olivé, G., and Olivé, S. (1977). Coordination and Catalysis. Verlag Chemie, Weinheim
Jensen, W. B. (1978). The Lewis acid-base definitions: a status report. Chem. Rev. 78, 1
Kochi, J. K. (1978). Organometallic Mechanisms and Catalysis. Academic Press, New York; see particularly part III
Pearson, R. G. (1968). Hard and soft acids and bases, HSAB, Part I. J. chem. Educ. 45, 581
Author information
Authors and Affiliations
Copyright information
© 1986 A. W. Parkins and R. C. Poller
About this chapter
Cite this chapter
Parkins, A.W., Poller, R.C. (1986). The Coordination Chemistry of Organometallic Compounds. In: An Introduction to Organometallic Chemistry. Palgrave, London. https://doi.org/10.1007/978-1-349-18198-8_6
Download citation
DOI: https://doi.org/10.1007/978-1-349-18198-8_6
Publisher Name: Palgrave, London
Print ISBN: 978-0-333-36433-8
Online ISBN: 978-1-349-18198-8
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)