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Abstract

Consider the case of a metal M in equilibrium with its ions

$$ {M^{Z + }}\; + \;Ze\; \rightleftharpoons \;M $$

The tendency of a metal to transfer its ions into solution is counterbalanced by an electrode potential difference. Thus equilibrium potentials of metals characterise the free energy change of the process of metal ion removal from metal into solution. In the table below are given some values of normal (standard) equilibrium potentials (that is, where the activity of their own ions in solution is unity) at 298 K; these are known as standard potentials.

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Further Reading

  • Evans, U.R., Corrosion and Oxidation of Metals (Edward Arnold, 1960)

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  • Pludek, V.R., Design and Corrosion Control (Macmillan Press, 1977)

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  • Scully, J.C., Fundamentals of Corrosion, 2nd ed. (Pergamon, 1975)

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  • Shreir, L.L., (ed.) Corrosion, vols I and II (Newnes-Butterworth, 1976)

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  • Tomashov, N.D., Theory of Corrosion and Protection of Metals (Macmillan, 1966)

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  • West, J.M., Electrodeposition and Corrosion Processes (Van Nostrand, 1971)

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© 1981 Gladius Lewis

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Lewis, G. (1981). Corrosion. In: Properties of Engineering Materials. Palgrave, London. https://doi.org/10.1007/978-1-349-05837-2_5

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  • DOI: https://doi.org/10.1007/978-1-349-05837-2_5

  • Publisher Name: Palgrave, London

  • Print ISBN: 978-1-349-05839-6

  • Online ISBN: 978-1-349-05837-2

  • eBook Packages: EngineeringEngineering (R0)

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