Experimental Techniques: Theory and Application to Iron(III) Model Compounds

  • C. A. Mcauliffe
Part of the Aspects of Inorganic Chemistry book series

Abstract

Particularly useful techniques for identifying the presence of polynuclear iron(III) ions are those that are sensitive to the characteristic feature of the cluster—the interaction between the different sets of 3d electrons. In this regard the magnetic moment, its temperature dependence and the e.p.r. spectrum are particularly important probes. Several other techniques have been used to elucidate structural details of the co-ordination geometry, the bonding between iron atoms in the cluster and between the cluster and the protein. These include electronic-absorption spectroscopy within the d5 configuration, Mössbauer and vibrational spectroscopies and X-ray diffraction.

Keywords

Anisotropy Manganese Polypeptide Sponge Cyanide 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Copyright information

© Palgrave Macmillan, a division of Macmillan Publishers Limited 1975

Authors and Affiliations

  • C. A. Mcauliffe
    • 1
  1. 1.Institute of Science and TechnologyUniversity of ManchesterUK

Personalised recommendations