Summary
The thermodynamic state of a saline solution is completely specified by the temperature, pressure and chemical potentials of the components that are present. The chemical potential can be defined rigorously in mathematical terms but in this form often provides difficulty in conception. In order to overcome this difficulty for solutions, it is useful to relate the chemical potential to some ideal reference solution; the deviation between real and ideal solution is formalized in terms of an activity coefficient, and sometimes in the case of a solvent by an osmotic coefficient. The activity coefficients can be obtained from experiment, and are well tabulated.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Adam, N. K. (1941). The Physics and Chemistry of Surfaces 3rd Edn. Oxford University Press.
Bridgman, P. W. (1914) Phys. Rev. 3, 273.
Callen, H. B. (1960). Thermodynamics. John Wiley and Sons, New York.
Davies, C. W. (1962). Ion Association. Butterworths, London.
Debye, P., and Mickel, E. (1923). Phys. Z. 24, 185.
Defay, R., Prigogine, I., Bellemans, A., and Everett, D. H. (1966). Surface Tension and Adsorption. Longmans, Green, London.
Denbigh, K. G. (1957). The Principles of Chemical Equilibrium. Cambridge University Press.
Gibbs, J. W. (1961). The Scientific Papers of J. Willard Gibbs, vol. 1, Thermodynamics. Dover Publications, New York.
Guggenheim, E. A. (1929). J. Phys. Chem. 33, 842.
Guggenheim, E. A. (1957) Thermodynamics 3rd Edn. North-Holland Publishing Co., Amsterdam.
Harned, H. S., and Owen, B. B. (1958). The Physical Chemistry of Electrolytic Solutions 3rd Edn. Reinhold Publishing Corp., New York.
Hinke, J. A. M. (1961). J. Physiol. 156, 314.
Hodgkin, A. L. (1967). The Conduction of the Nervous Impulse. Liverpool University Press.
Lewis, G. N., and Randall, M. (1923). Thermodynamics and the Free Energy of Chemical Substances. McGraw-Hill, New York.
Lewis, G. N., and Randall, M. (1961). Thermodynamics 2nd Edn. Revised by K. S. Pitzer and L. Brewer. McGraw-Hill, New York.
Noyes, A. A., and Bray, W. C. (1911). J. Amer. chem. Soc. 33, 1646.
Prigogine, I., and Defay, R. (1954). Chemical Thermodynamics. Translated by D. H. Everett. Longmans, Green, London.
Robinson, R. A., and Stokes, R. H. (1959). Electrolyte Solutions 2nd Edn. revised. Butterworth, London.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Copyright information
© 1971 Australian Academy of Science
About this chapter
Cite this chapter
Lane, J.E., Mansfield, W.W. (1971). Thermodynamics of Saline Water. In: Talsma, T., Philip, J.R. (eds) Salinity and Water Use. Palgrave Macmillan, London. https://doi.org/10.1007/978-1-349-01391-3_3
Download citation
DOI: https://doi.org/10.1007/978-1-349-01391-3_3
Publisher Name: Palgrave Macmillan, London
Print ISBN: 978-1-349-01393-7
Online ISBN: 978-1-349-01391-3
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)