Dye-Sensitized Solar Cells Using Natural Dyes and Nanostructural Improvement of TiO2 Film

Chapter
Part of the Green Energy and Technology book series (GREEN)

Abstract

The characteristics of the dye-sensitized solar cells using natural dyes, such as those of red-cabbage, curcumin, and red-perilla, and synthesized dyes, such as NKX-2553, NKX-2677, and D149, in which a precious metal is not contained, will be explained. The largest conversion efficiency obtained is over 1% for the dye-sensitized solar cell using the dye of red-cabbage. This value is relatively small. However, the cost performance (defined by [conversion efficiency]/[cost of dye]) is more than 50 times greater than that of the dye-sensitized solar cell using Ruthenium complex. Therefore, when the cost of FTO and ITO substrates, oxide semiconductor, electrolyte solution, and opposite electrode becomes very low, dye-sensitized solar cells fabricated using natural dyes may become more pervasive, although the physical device becomes larger than one using a Ruthenium complex. The effects of pH of the dye solution on the characteristic of the dye-sensitized solar cells will be also described. The conversion efficiencies of the dye-sensitized solar cells using the dye of red-cabbage, red-perilla, NKX-2553, and NKX-2677 become larger when the pH value is low. It is expected that this technique will be used in future dye-sensitized solar cell systems.

References

  1. 1.
    Gratzel M (2003) Dye-sensitized solar cells. J Photochem Photobiol C: Photochem Rev 4:145CrossRefGoogle Scholar
  2. 2.
    Law M, Greene LE, Johnson JC, Saykally R, Yang P (2005) Nanowire dye-sensitized solar cells. Nat Mater 4:455–459CrossRefGoogle Scholar
  3. 3.
    Furukawa S, Okada K, Ohno T, Sato H, Ohta H, Iino H, Arakawa H, Yasuda T (2007) Trans Mater Res Soc Jpn 32(2):321Google Scholar
  4. 4.
    Furukawa S, Yamauchi S, Iino H, Iwamoto T, Kuwada K (2008). In: The 5th international symposium on organic molecular electronics, 6C-4, 22–23 May, HimejiGoogle Scholar
  5. 5.
    Furukawa S, Iino H, Iwamoto T, Kukita K, Yamauchi S (2009) Characteristics of dye-sensitized solar cells using natural dye. Thin Solid Films 518:526–529CrossRefGoogle Scholar
  6. 6.
    Shen Q, Arae D, Toyoda T (2004) J Photochem Photobol A: Chem 164:75Google Scholar
  7. 7.
    Sabataityte J, Oja I, Lenzmann F, Volobujeva O, Krunks M, Chim CR (2006) 9:708Google Scholar
  8. 8.
    Kang M, Hak Kim J, Won J, Soo Kang Y (2006) Dye-sensitized solar cells based on crosslinked poly(ethylene glycol) electrolytes. J Photochem Photobiol A: Chem 183:15CrossRefGoogle Scholar
  9. 9.
    Shaheer Akhtar M, Chun J-M, Yang O-B (2007) Electrochem Commun 9:2833Google Scholar
  10. 10.
    Lee K, Suryanarayanan V, Ho K (2007) Sol Energy Mater Sol Cells 91:1416Google Scholar
  11. 11.
    Lan Z, Wu J, Lin J, Huang M, Yin S, Sato T (2007) Electrochim Acta 52:6673Google Scholar
  12. 12.
    Kukita K, Furukawa S (2010) Annual meeting of the Institute of Electrical Engineers of Japan, 17–19 March, Tokyo (In Japanese)Google Scholar

Copyright information

© Springer-Verlag London Limited 2011

Authors and Affiliations

  1. 1.Graduate School of Computer Science and Systems EngineeringKyushu Institute of TechnologyKitakyushu-shiJapan

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