Abstract
The invention of dye-sensitized solar cell (DSSC) provided a promising alternative to Si-based photovoltaic devices. The first generation of DSSCs was constructed on nanoparticle wide bandgap semiconductor photoanodes. However, despite its unmatched success to date, the nanoparticle-based photoanode suffers from exceedingly slow electron transport due to the intrinsic defect states in the nanoparticle network, which eventually limits any further advancement in the device efficiency. Recent efforts have been directed toward developing ordered electron transport pathways using a variety of pseudo-1D photoanodes that exhibit enhanced charge transport and greater material versatility. Further exploration and optimization of these alternative nanoarchitectured photoanodes may eventually lead to device performance exceeding the current state-of-the-art.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Basic Research Needs for Solar Energy Utilization, DoE Report of Basic Energy Sciences Workshop on Solar Energy Utilization August 18–21, 2005
O’ Regan B, Grätzel M (1991) A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature 353:737–740
Nazeeruddin MK, Kay A, Rodicio I et al (1993) Conversion of light to electricity by cis-X2bis(2, 2’-bipyridyl-4, 4’-dicarboxylate)ruthenium(II) charge-transfer sensitizers (X = Cl-, Br-, I-, CN-, and SCN-) on nanocrystalline titanium dioxide electrodes. J Am Chem Soc 115:6382–6390
Nazeeruddin MK, De Angelis F, Fantacci S et al (2005) Combined experimental and DFT-TDDFT computational study of photoelectrochemical cell ruthenium sensitizers. J Am Chem Soc 127:16835–16847
Chiba Y, Islam A, Watanabe Y et al. (2006) Dye-sensitized solar cells with conversion efficiency of 11.1%. Jap J Appl Phys 45: L638–L640
Grätzel M (2003) Applied physics—solar cells to dye for. Nature 421:586–587
Gratzel M (2005) Solar energy conversion by dye-sensitized photovoltaic cells. Inorg Chem 44:6841–6851
Gratzel M (2005) Dye-sensitized solid–state heterojunction solar cells. MRS Bull 30:23–27
Fisher AC, Peter LM, Ponomarev EA et al (2000) Intensity dependence of the back reaction and transport of electrons in dye-sensitized nanocrystalline TiO2 solar cells. J Phys Chem B 104:949–958
Oekermann T, Zhang D, Yoshida T, Minoura H (2004) Electron transport and back reaction in nanocrystalline TiO2 fi lms prepared by hydrothermal crystallization. J Phys Chem B 108:2227–2235
Nelson J (1999) Continuous-time random-walk model of electron transport in nanocrystalline TiO2 electrodes. Phys Rev B 59:15374–15380
van de Lagemaat J, Frank AJ (2001) Nonthermalized electron transport in dye-sensitized nanocrystalline TiO2 films: transient photocurrent and random-walk modeling studies. J Phys Chem B 105:11194–11205
Kopidakis N, Schiff EA, Park NG et al (2000) Ambipolar diffusion of photocarriers in electrolyte-fi lled, nanoporous TiO2. J Phys Chem B 104:3930–3936
Benkstein KD, Kopidakis N, van de Lagemaat J (2003) Influence of the percolation network geometry on electron transport in dye-sensitized titanium dioxide solar cells. J Phys Chem B 107:7759–7767
Kopidakis N, Benkstein KD, van de Lagemaat J et al (2003) Transport-limited recombination of photocarriers in dye-sensitized nanocrystalline TiO2 solar cells. J Phys Chem B 107:11307–11315
Kavan L, Grätzel M, Gilbert SE et al (1996) Electrochemical and photoelectrochemical investigation of single-crystal anatase. J Am Chem Soc 118:6716–6723
Peter L (2009) “Sticky electrons” transport and interfacial transfer of electrons in the dye-sensitized solar cell. Acc Chem Res 42:1839–1847
Boschloo G, Hagfeldt A (2009) Characteristics of the iodide/triiodide redox mediator in dye-sensitized solar cells. Acc Chem Res 42:1819–1826
Asano T, Kubo T, Nishikitani Y (2005) Short-circuit current density behavior of dye-sensitized solar cells. Jpn J Appl Phys 44:6776–6780
Zistler M, Wachter P, Wasserscheid P et al (2006) Comparison of electrochemical methods for triiodide diffusion coefficient measurements and observation of non-stokesian diffusion behaviour in binary mixtures of two ionic liquids. Electrochim Acta 52:161–169
Haque SA, Tachibana Y, Klug DR (1998) Charge recombination kinetics in dye-sensitized nanocrystalline titanium dioxide films under externally applied bias. J Phys Chem B 102:1745–1749
Roy JC, Hamill WH, Williams RR (1955) Diffusion kinetics of the photochemical and thermal dissociation-recombination of trihalide ions. J Am Chem Soc 77:2953–2957
Kubo W, Kambe S, Nakade S et al (2003) Photocurrent-determining processes in quasi-solid-state dye-sensitized solar cells using ionic gel electrolytes. J Phys Chem B 107:4374–4381
ITO S, Zakeeruddin SM, Comte P et al (2008) Bifacial dye-sensitized solar cells based on an ionic liquid electrolyte. Nature Photonics 2:693–698
Li G, Shrotriya V, Huang JS et al (2005) High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends. Nat Mater 4:864–868
Martinson ABF, Hamann TW, Pellin MJ et al (2008) New architectures for dye-sensitized solar cells. Chem Eur J 14:4458–4467
Law M, Greene LE, Johnson JC et al (2005) Nanowire dye-sensitized solar cells. Nat Mater 4:455–459
Greene LE, Law M, Goldberger J et al (2003) Low-temperature wafer-scale production of ZnO nanowire arrays. Angew Chem Int Ed 42:3031–3034
Mora-Seró I, Fabregat-Santiago F, Denier B et al (2006) Determination of carrier density of ZnO nanowires by electrochemical techniques. Appl Phys Lett 89:203117
Guillén E, Casanueva F, Anta JA et al (2008) Photovoltaic performance of nanostructured zinc oxide sensitised with xanthene dyes. J Photochem Photobio A Chem 200:364–370
Keis K, Lindgren J, Lindquist SE et al (2000) Studies of the adsorption process of Ru complexes in nanoporous ZnO electrodes. Langmuir 16:4688–4694
Horiuchi H, Katoh R, Hara K (2003) Electron injection efficiency from excited N3 into nanocrystalline ZnO films: effect of (N3 − Zn2+) aggregate formation. J Phys Chem B 107:2570–2574
Sayama K, Tsukagoshi S, Hara K et al (2002) Photoelectrochemical properties of j aggregates of benzothiazole merocyanine dyes on a nanostructured TiO2 film. J Phys Chem B 106:1363–1371
Feng X, Shankar K, Varghese OK et al (2008) Vertically aligned single crystal TiO2 nanowire arrays grown directly on transparent conducting oxide coated glass: synthesis details and applications. Nano Lett 8:3781–3786
Paulose M, Shankar K, Varghese OK et al (2006) Application of highly-ordered TiO2 nanotube-arrays in heterojunction dye-sensitized solar cells. J Phys D Appl Phys 39:2498–2503
Paulose M, Prakasam HE, Varghese OK et al (2007) TiO2 nanotube arrays of 1000 μm length by anodization of titanium foil: phenol red diffusion. J Phys Chem C 111:14992–14997
Martinson ABF, Elam JW, Hupp JT et al (2007) ZnO nanotube based dye-sensitized solar cells. Nano Lett 7:2183–2187
Martinson ABF, Elam JW, Liu J et al (2008) Radial electron collection in dye-sensitized solar cells. Nano Lett 8:2862–2866
Martinson ABF, Goes MS, Fabregat-Santiago F (2009) Electron transport in dye-sensitized solar cells based on ZnO nanotubes: evidence for highly efficient charge collection and exceptionally rapid dynamics. J Phys Chem A 113:4015–4021
Irwin MD, Buchholz DB, Hains AW (2008) p-Type semiconducting nickel oxide as an efficiency-enhancing anode interfacial layer in polymer bulk-heterojunction solar cells. Proc Natl Acad Sci 105:2783–2787
Liang Y, Zhen C, Zou D et al (2004) Preparation of free-standing nanowire arrays on conductive substrates. J Am Chem Soc 126:16338–16339
Ko S, Lee D, Jee S et al (2006) Mechanical properties and residual stress in porous anodic alumina structures. Thin Solid Films 515:1932–1937
Jiang CY, Sun XW, Lo GQ et al (2007) Improved dye-sensitized solar cells with a ZnO-nanoflower photoanode. Appl Phys Lett 90:263501
Cheng HM, Chiu WH, Lee CH et al (2008) Formation of branched ZnO nanowires from solvothermal method and dye-sensitized solar cells applications. J Phys Chem C 112:16359–16364
Zhu K, Neale NR, Miedaner A et al (2007) Enhanced charge-collection efficiencies and light scattering in dye-sensitized solar cells using oriented TiO0 nanotube arrays. Nano Lett 7:69–74
Zhu K, Vinzant TB, Neale NR et al (2007) Removing structural disorder from oriented TiO2 nanotube arrays: reducing the dimensionality of transport and recombination in dye-sensitized solar cells. Nano Lett 7:3739–3754
Kim D, Ghicov A, Albu SP et al (2008) Bamboo-type TiO2 nanotubes: improved conversion efficiency in dye-sensitized solar cells. J Am Chem Soc 130:16454–16455
Yang Z, Xu T, Ito Y et al (2009) Enhanced electron transport in dye-sensitized solar cells using short ZnO nanotips on a rough metal anode. J Phys Chem C 113:20521–20526
Du Pasquier A, Chen HH, Lu YC (2006) Dye sensitized solar cells using well-aligned zinc oxide nanotip arrays. Appl Phys Lett 89:253513
Chen HH, Du Pasquier A, Saraf G et al (2008) Dye-sensitized solar cells using ZnO nanotips and Ga-doped ZnO films. Semicond Sci Technol 23:045004
Peter LM (2007) Characterization and modeling of dye-sensitized solar cells. J Phys Chem C 111:6601–6612
Anderson PA (1940) The contact difference of potential between barium and zinc the external work function of zinc. Phys Rev 57:122–127
Reinaudi L, DelPopolo M, Leiva E (1997) Work function calculation for thick metal slabs with local pseudopotentials. Surf Sci 372:L309–L314
Sun Z, Wang C, Yang J, Zhao B, Lombardi JR (2008) Nanoparticle metal—semiconductor charge transfer in ZnO/PATP/Ag assemblies by surface-enhanced Raman spectroscopy. J Phys Chem C 112:6093–6098
Katoh R, Furube A, Barzykin AV, Arakawa H, Tachiya M (2004) Kinetics and mechanism of electron injection and charge recombination in dye-sensitized nanocrystalline semiconductors. Coord Chem Rev 248:1195–1213
Kamiya T, Tajima K, Nomura K, Yanagi H, Hosono H (2008) Interface electronic structures of zinc oxide and metals: first-principle study. Physica Status Solidi (a) 205:1929–1933
Benda V, Gowar J, Grant DA (1999) Power semiconductor devices: theory and applications. Wiley, New York, pp 62–65
Kieven D, Dittrich T, Belaidi A, Tornow J, Schwarzburg K, Allsop N, Lux-Steiner M (2008) Effect of internal surface area on the performance of ZnO/In2S3/CuSCN solar cells with extremely thin absorber. Appl Phys Lett 92:153107
Hahn R, Schmidt-Stein F, Salonen J, Thiemann S, Song Y, Kunze J, Lehto V, Schmuki P (2009) Semimetallic TiO2 nanotubes. Angew Chem Int Ed 48:7236–7239
Hamann TW, Jensen RA, Martinson ABF, Ryswyk HV, Hupp JT (2008) Advancing beyond current generation dye-sensitized solar cells energy. Environ Sci 1:66–78
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2011 Springer-Verlag London Limited
About this chapter
Cite this chapter
Xu, T. (2011). Nanoarchitectured Electrodes for Enhanced Electron Transport in Dye-Sensitized Solar Cells. In: Zang, L. (eds) Energy Efficiency and Renewable Energy Through Nanotechnology. Green Energy and Technology. Springer, London. https://doi.org/10.1007/978-0-85729-638-2_7
Download citation
DOI: https://doi.org/10.1007/978-0-85729-638-2_7
Published:
Publisher Name: Springer, London
Print ISBN: 978-0-85729-637-5
Online ISBN: 978-0-85729-638-2
eBook Packages: EngineeringEngineering (R0)