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Electrochemistry for the Environment pp 25–54Cite as

Importance of Electrode Material in the Electrochemical Treatment of Wastewater Containing Organic Pollutants

Abstract

Electrochemical oxidation is a promising method for the treatment of wastewaters containing organic compounds. As a general rule, the electrochemical incineration of organics at a given electrode can take place at satisfactory rates and without electrode deactivation only at high anodic potentials in the region of the water discharge due to the participation of the intermediates of oxygen evolution. The nature of the electrode material strongly influences both the selectivity and the efficiency of the process. In particular, anodes with low oxygen evolution overpotential (i.e., good catalysts for oxygen evolution reactions), such as graphite, IrO2, RuO2, and Pt only permit the partial oxidation of organics, while anodes with high oxygen evolution overpotential (i.e., anodes that are poor catalysts for oxygen evolution reactions), such as SnO2, PbO2, and boron-doped diamond (BDD) favor the complete oxidation of organics to CO2 and so are ideal electrodes for wastewater treatment.However, the application of SnO2 and PbO2 anodes may be limited by their short service life and the risk of lead contamination, while BDD electrodes exhibit good chemical and electrochemical stability, a long life, and a wide potential window for water discharge, and are thus promising anodes for industrial-scale wastewater treatment.

Keywords

  • Chemical Oxygen Demand
  • Oxygen Evolution
  • Current Efficiency
  • Oxygen Evolution Reaction
  • Lead Dioxide

These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  • Alvarez-Gallegos, A. and Pletcher, D. (1998) Removal of low level organics via hydrogen peroxide formed in a reticulated vitreous carbon cathode cell, Part 1. The electrosynthesis of hydrogen peroxide in aqueous acidic solutions. Electrochim. Acta 44, 853–861.

    CAS  Google Scholar 

  • Alvarez-Gallegos, A. and Pletcher, D. (1999) The removal of low level organics via hydrogen peroxide formed in a reticulated vitreous carbon cathode cell, Part 2. The removal of phenols and related compounds from aqueous solutions. Electrochim. Acta 44, 2483–2492.

    Google Scholar 

  • Awad, Y. M. and Abuzaid, N. S. (1997) Electrochemical treatment of phenolic wastewater: Efficiency, design considerations and economic evaluation. J. Environ. Sci. Health A 32, 1393–1414.

    CrossRef  Google Scholar 

  • Awad, Y. M. and Abuzaid, N. S. (1999) Electrochemical oxidation of phenol using graphite anodes. Sep. Sci. Technol. 34, 699–708.

    CrossRef  CAS  Google Scholar 

  • Awad, Y. M. and Abuzaid, N. S. (2000) Influence of residence time on the anodic oxidation of phenol. Sep. Purif. Technol. 18, 227–236.

    CrossRef  CAS  Google Scholar 

  • Beer, H. B. (1966) US Patent Appl. 549 194.

    Google Scholar 

  • Bellagamba, R., Michaud, P. A., Comninellis, C. and Vatistas, N. (2002) Electro-combustion of polyacrylates with boron-doped diamond anodes. Electrochem. Commun. 4, 171–176.

    CrossRef  CAS  Google Scholar 

  • Bock, C. and MacDougall, B. (1999) Anodic oxidation of p-benzoquinone and maleic acid. J. Electrochem. Soc. 146, 2925–2932.

    CrossRef  CAS  Google Scholar 

  • Bock, C. and MacDougall, B. (2000) Influence of metal oxide properties on the oxidation of organics. J. Electroanal. Chem. 491, 48–54.

    CrossRef  CAS  Google Scholar 

  • Bonfatti, F., Ferro, S., Lavezzo, F., Malacarne, M., Lodi, G. and De Battisti, A. (1999) Electro-chemical incineration of glucose as a model organic substrate. I. Role of the electrode material. J. Electrochem. Soc. 146, 2175–2179.

    CAS  Google Scholar 

  • Bonfatti, F., De Battisti, A., Ferro, S., Lodi, G. and Osti, S. (2000a) Anodic mineralization of organic substrates in chloride-containing aqueous media. Electrochim. Acta 46, 305–314.

    CrossRef  CAS  Google Scholar 

  • Bonfatti, F., Ferro, S., Lavezzo, F., Malacarne, M., Lodi, G. and De Battisti, A. (2000b) Electro-chemical incineration of glucose as a model organic substrate. II. Role of active chlorine mediation. J. Electrochem. Soc. 147, 592–596.

    CAS  Google Scholar 

  • Boudenne, J. L. and Cerclier, O. (1999) Performance of carbon black-slurry electrodes for 4-chlorophenol oxidation. Water Res. 33, 494–504.

    CrossRef  CAS  Google Scholar 

  • Boudenne, J. L., Cerclier, O., Galea, J. and Vlist, E. V. D. (1996) Electrochemical oxidation of aqueous phenol at a carbon black slurry electrode. Appl. Catal. A: General 143, 185–202.

    CrossRef  CAS  Google Scholar 

  • Boye, B., Dieng, M. M. and Brillas, E. (2002) Degradation of herbicide 4-chlorophenoxyacetic acid by advanced electrochemical oxidation methods. Environ. Sci. Technol. 36, 3030–3035.

    CrossRef  CAS  Google Scholar 

  • Brillas, E., Bastida, R. M., Llosa, E. and Casado, J. (1995) Electrochemical destruction of aniline and chloroaniline for wastewater treatment using a carbon PTFE O2-fed cathode. J. Electrochem. Soc. 142, 1733–1741.

    CrossRef  CAS  Google Scholar 

  • Brillas, E., Mur, E. and Casado, J. (1996) Iron(II) catalysis of the mineralization of aniline using a carbon-PTFE O2-fed cathode. J. Electrochem. Soc. 143, L49–L53.

    CrossRef  CAS  Google Scholar 

  • Brillas, E., Boye, B. and Dieng, M. M. (2003) Peroxi-coagulation and photoperoxi-coagulation treatments of the herbicide 4-chlorophenoxyacetic acid in aqueous medium using an oxygen-diffusion cathode. J. Electrochem. Soc. 150, E148–E154.

    CrossRef  CAS  Google Scholar 

  • Brillas, E., Boye, B., Sires, I., Garrido, J. A., Rodriguez, R. M., Arias, C., Cabot, P. L. and Comninellis, C. (2004) Electrochemical destruction of chlorophenoxy herbicides by anodic oxidation and electro-Fenton using a boron-doped diamond electrode. Electrochim. Acta 49, 4487–4496.

    CrossRef  CAS  Google Scholar 

  • Canizares, P., Dominguez, J. A., Rodrigo, M. A., Villasenor, J. and Rodriguez, J. (1999) Effect of the current intensity in the electrochemical oxidation of aqueous phenol wastes at an activated carbon and steel anode. Ind. Eng. Chem. Res. 38, 3779–3785.

    CrossRef  CAS  Google Scholar 

  • Canizares, P., Diaz, M., Dominguez, J. A., Garcia-Gomez, J. and Rodrigo, M. A. (2002) Electrochemical oxidation of aqueous phenol wastes on synthetic diamond thin-film electrodes. Ind. Eng. Chem. Res. 41, 4187–4194.

    CrossRef  CAS  Google Scholar 

  • Canizares, P., Garcia-Gomez, J., Lobato, J. and Rodrigo, M. A. (2003a) Electrochemical oxidation of aqueous carboxylic acid wastes using diamond thin-film electrodes. Ind. Eng. Chem. Res. 42, 956–962.

    CrossRef  CAS  Google Scholar 

  • Canizares, P., Garcia-Gomez, J., Saez, C. and Rodrigo, M. A. (2003b) Electrochemical oxida-tion of several chlorophenols on diamond electrodes: Part I. Reaction mechanism. J. Appl. Electrochem. 33, 917–927.

    CAS  Google Scholar 

  • Canizares, P., Garcia-Gomez, J., Saez, C. and Rodrigo, M. A. (2004a) Electrochemical oxida-tion of several chlorophenols on diamond electrodes: Part II. Influence of waste character-istics and operating conditions. J. Appl. Electrochem. 34, 87–94.

    CAS  Google Scholar 

  • Canizares, P., Saez, C., Lobato, J. and Rodrigo, M. A. (2004b) Electrochemical treatment of 2,4-dinitrophenol aqueous wastes using boron-doped diamond anodes. Electrochim. Acta 49, 4641–4650.

    CrossRef  CAS  Google Scholar 

  • Canizares, P., Saez, C., Lobato, J. and Rodrigo, M. A. (2004c) Electrochemical treatment of 4-nitrophenol-containing aqueous wastes using boron-doped diamond anodes. Ind. Eng. Chem. Res. 43, 1944–1951.

    CrossRef  CAS  Google Scholar 

  • Chang, H. and Johnson, D. C. (1990) Electrocatalysis of anodic oxygen-transfer reactions. J. Electrochem. Soc. 137, 2452–2457.

    CrossRef  CAS  Google Scholar 

  • Chen, G. (2004) Electrochemical technologies in wastewater treatment. Sep. Purif. Technol. 38, 11–41.

    CrossRef  CAS  Google Scholar 

  • Chen, G., Chen, X. and Yue, P. L. (2002) Electrochemical behavior of novel Ti ∕ IrOx − Sb2O5 − SnO2 anodes. J. Phys. Chem. B 106, 4364–4369.

    CrossRef  CAS  Google Scholar 

  • Chen, X., Chen, G., Gao, F. and Yue, P. L. (2003) High-performance Ti/BDD electrodes for pollutant oxidation. Environ. Sci. Technol. 21, 5021–5026.

    CrossRef  CAS  Google Scholar 

  • Chiang, L. C., Chang, J. E. and Wen, T. C. (1995) Indirect oxidation effect in electrochemical oxidation treatment of landfill leachate. Water Res. 29, 671–678.

    CrossRef  CAS  Google Scholar 

  • Comninellis, C. (1994) Electrocatalysis in the electrochemical conversion/combustion of organic pollutants for waste water treatment. Electrochim. Acta 39, 1857–1862.

    CrossRef  CAS  Google Scholar 

  • Comninellis, C. and De Battisti, A. (1996) Electrocatalysis in anodic oxidation of organics with simultaneous oxygen evolution. J. Chim. Phys. 93, 673–679.

    CAS  Google Scholar 

  • Comninellis, C. and Nerini, A. (1995) Anodic oxidation of phenol in the presence of NaCl for wastewater treatment. J. Appl. Electrochem. 25, 23–28.

    CrossRef  CAS  Google Scholar 

  • Comninellis, C. and Pulgarin, C. (1991) Anodic oxidation of phenol for wastewater treatment. J. Appl. Electrochem. 21, 703–708.

    CrossRef  CAS  Google Scholar 

  • Comninellis, C. and Pulgarin, C. (1993) Electrochemical oxidation of phenol for wastewater treatment using SnO2 anodes. J. Appl. Electrochem. 23, 108–112.

    CrossRef  CAS  Google Scholar 

  • Comninellis, C., Duo, I., Michaud, P. A., Marselli, B. and Park, S. M. (2005) Application of syhthetic boron-doped diamond electrodes in electrooxidation processes. In: A. Fujishima, Y. Einaga, T. N. Rao and D. A. Tryk (Eds.), Diamond Electrochemistry. Elsevier, Amsterdam, pp. 449–476.

    Google Scholar 

  • Correa-Lozano, B., Comninellis, C. and De Battisti, A. (1997) Service life of Ti ∕ SnO2 − Sb2O5 anodes. J. Appl. Electrochem. 27, 970–974.

    CrossRef  CAS  Google Scholar 

  • Cossu, R., Polcaro, A. M., Lavagnolo, M. C., Mascia, M., Palmas, S. and Renoldi, F. (1998) Electrochemical treatment of landfill leachate: Oxidation at Ti ∕ PbO2 and Ti ∕ SnO2 anodes. Ind. Eng. Chem. Res. 32, 3570–3573.

    CAS  Google Scholar 

  • Dhooge, P. M. and Park, S. M. (1983) Electrochemistry of coal slurries - 2. Studies on various experimental parameters affecting oxidation of coal slurries. J. Electrochem. Soc. 130, 1029–1036.

    CAS  Google Scholar 

  • Do, J. S. and Chen, C. P. (1993) In situ oxidative degradation of formaldehyde with electro-generated hydrogen peroxide. J. Electrochem. Soc. 140, 1632–1637.

    CrossRef  CAS  Google Scholar 

  • Do, J. S. and Chen, C. P. (1994a) In situ oxidative degradation of formaldehyde with hydrogen peroxide electrogenerated on the modified graphite. J. Appl. Electrochem. 24, 936–942.

    CrossRef  CAS  Google Scholar 

  • Do, J. S. and Chen, C. P. (1994b) Kinetics of in situ oxidative degradation of formaldehyde with electrogenerated hydrogen peroxide. Ind. Eng. Chem. Res. 33, 387–394.

    CrossRef  CAS  Google Scholar 

  • Do, J. S. and Yeh, W. C. (1995) In situ degradation of formaldehyde with electrogenerated hypochlorite ion. J. Appl. Electrochem. 25, 483–489.

    CrossRef  CAS  Google Scholar 

  • Do, J. S., Yeh, W. C. and Chao, I. Y. (1997) Kinetic of the oxidative degradation of formaldehyde with electrogen hypochlorite. Ind. Eng. Chem. Res. 36, 349–356.

    CrossRef  CAS  Google Scholar 

  • Farmer, J. C., Wang, F. T., Hawley-Fedder, R. A., Lewis, P. R., Summers, L. J. and Foiles, L. (1992) Electrochemical treatment of mixed and hazardous wastes: Oxidation of ethylene glycole and benzene by silver(II). J. Electrochem. Soc. 139, 654–662.

    CrossRef  CAS  Google Scholar 

  • Feng, Y. J. and Li, X. Y. (2003) Electro-catalytic oxidation of phenol on several metal-oxide electrodes in aqueous solution. Water Res. 37, 2399–2407.

    CrossRef  CAS  Google Scholar 

  • Feng, J., Johnson, D. C., Lowery, S. N. and Carey, J. (1994) Electrocatalysis of anodic oxygen-transfer reactions evolution of ozone. J. Electrochem. Soc. 141, 2708–2711.

    CrossRef  CAS  Google Scholar 

  • Feng, J., Houk, L. L., Johnson, D. C., Lowery, S. N. and Carey, J. J. (1995) Electrocatalysis of anodic oxygen-transfer reactions: The electrochemical incineration of benzoquinone. J. Electrochem. Soc. 142, 3626–3632.

    CrossRef  CAS  Google Scholar 

  • Fernandes, A., Morao, A., Magrinho, M., Lopes, A. and Goncalves, I. (2004) Electrochemical degradation of C. I. Acid Orange 7. Dyes Pigm. 61, 287–296.

    CrossRef  CAS  Google Scholar 

  • Foller, P. C. and Tobias, C. W. (1982) The anodic evolution of ozone. J. Electrochem. Soc. 129, 506–515.

    CrossRef  CAS  Google Scholar 

  • Foti, G., Gandini, D. and Comninellis, C. (1997) Anodic oxidation of organics on thermally prepared oxide electrodes. Curr. Top. Electrochem. 5, 71–91.

    CAS  Google Scholar 

  • Foti, G., Gandini, D., Comninellis, C., Perret, A. and Haenni, W. (1999) Oxidation of organics by intermediates of water discharge on IrO2 and synthetic diamond anodes. Electrochem. Solid State Lett. 2, 228–230.

    CrossRef  CAS  Google Scholar 

  • Gandini, D., Comninellis, C., Perret, A. and Haenni, W. (1999) Anodic oxidation of organics on synthetic diamond thin-film electrodes. ICHEME Symp. Series 145, 181–190.

    CAS  Google Scholar 

  • Gandini, D., Mahe, E., Michaud, P. A., Haenni, W., Perret, A. and Comninellis, C. (2000) Oxidation of carboxylic acids at boron-doped diamond electrodes for wastewater treatment. J. Appl. Electrochem. 30, 1345–1350.

    CrossRef  CAS  Google Scholar 

  • Gattrell, M. and Kirk, D. (1990) The electrochemical oxidation of aqueous phenol at a glassy carbon electrode. Can. J. Chem. Eng. 68, 997–1003.

    CrossRef  CAS  Google Scholar 

  • Gattrell, M. and Kirk, D. (1993) A study of the oxidation of phenol at platinum and preoxidized platinum surfaces. J. Electrochem. Soc. 140, 1534–1540.

    CrossRef  CAS  Google Scholar 

  • Gherardini, L., Michaud, P. A., Panizza, M., Comninellis, C. and Vatistas, N. (2001) Electro-chemical oxidation of 4-chlorophenol for wastewater treatment. Definition of normalized current efficiency. J. Electrochem. Soc. 148, D78.

    CAS  Google Scholar 

  • Grimm, J. H., Bessarabov, D. G., Simon, U. and Sanderson, R. D. (2000) Characterization of doped tin dioxide anodes prepared by a sol-gel technique and their application in an SPE-reactor. J. Appl. Electrochem. 30, 293–302.

    CrossRef  CAS  Google Scholar 

  • Guivarch, E., Oturan, N. and Oturan, M. A. (2003) Removal of organophosphorus pesticides from water by electrogenerated Fenton’s reagent. Environ. Chem. Lett. 1, 165–168.

    CrossRef  CAS  Google Scholar 

  • Hattori, S., Doi, M., Takahashi, E., Kurosu, T., Nara, M., Nakamatsu, S., Nishiki, Y., Furuta, T. and Iida, M. (2003) Electrolytic decomposition of amaranth dyestuff using diamond electrodes. J. Appl. Electrochem. 33, 85–91.

    CrossRef  CAS  Google Scholar 

  • Houk, L. L., Johnson, S. K., Feng, J., Houk, R. S. and Johnson, D. C. (1998) Electrochemical incineration of benzoquinone in aqueous media using a quaternary metal oxide electrode in the absence of a soluble supporting electrolyte. J. Appl. Electrochem. 28, 1167–1177.

    CrossRef  CAS  Google Scholar 

  • Iniesta, J., Michaud, P. A., Panizza, M., Cerisola, G., Aldaz, A. and Comninellis, C. (2001a) Electrochemical oxidation of phenol at boron-doped diamond electrode. Electrochim. Acta 46, 3573–3578.

    CrossRef  CAS  Google Scholar 

  • Iniesta, J., Michaud, P. A., Panizza, M. and Comninellis, C. (2001b) Electrochemical oxidation of 3-methylpyridine at a boron-doped diamond electrode: Application to electroorganic synthesis and wastewater treatment. Electrochem. Commun. 3, 346–351.

    CrossRef  CAS  Google Scholar 

  • Iniesta, J., Exposito, E., Gonzalez-Garcia, J., Montiel, V. and Aldaz, A. (2002) Electrochemical treatment of industrial wastewater containing phenols. J. Electrochem. Soc. 149, D57-D62.

    CrossRef  CAS  Google Scholar 

  • Israilides, C. J., Vlyssides, A. G., Mourafeti, V. N. and Karvouni, G. (1997) Olive oil waste-water treatment with the use of an electrolysis system. Bioresource Technol. 61, 163–170.

    CrossRef  CAS  Google Scholar 

  • Johnson, S. K., Houk, L. L., Feng, J., Houk, R. S. and Johnson, D. C. (1999) Electrochemical incineration of 4-chlorophenol and the identification of products and intermediates by mass spectrometry. Environ. Sci. Technol. 33, 2638–2644.

    CrossRef  CAS  Google Scholar 

  • Kawagoe, K. T. and Johnson, D. C. (1994) Electrocatalysis of anodic oxygen-transfer reactions. Oxidation of phenol and benzene at bismuth-doped lead dioxide electrodes in acidic solutions. J. Electrochem. Soc. 141, 3404–3409.

    CAS  Google Scholar 

  • Keech, P. G. and Bunce, N. J. (2003) Electrochemical oxidation of simple indoles at a PbO2 anode. J. Appl. Electrochem. 33, 79–83.

    CrossRef  CAS  Google Scholar 

  • Kirk, D., Sharifian, H. and Foulkes, F. R. (1985) Anodic oxidation of aniline for waste water treatment. J. Appl. Electrochem. 15, 285–292.

    CrossRef  CAS  Google Scholar 

  • Kotz, R., Stucki, S. and Carcer, B. (1991) Electrochemical wastewater treatment using high overvoltage anodes. Part I: physical and electrochemical properties of SnO2 anodes. J. Appl. Electrochem. 21, 14–20.

    CrossRef  Google Scholar 

  • Kraft, A., Stadelmann, M. and Blaschke, M. (2003) Anodic oxidation with doped diamond electrodes: A new advanced oxidation process. J. Hazard. Mater. 103, 247–261.

    CrossRef  CAS  Google Scholar 

  • Lamy, C. (1984) Electrocatalytic oxidation of organic compounds on noble metals in aqueous solution. Electrochim. Acta 29, 1581–1588.

    CrossRef  CAS  Google Scholar 

  • Lamy, C., Leger, J. M., Clavilier, J. and Parsons, R. (1983) Structural effects in electrocatalysis: A comparative study of the oxidation of CO, HCOOH and CH3OH on single crystal Pt electrodes. J. Electroanal. Chem. 150, 71–77.

    CrossRef  CAS  Google Scholar 

  • Lanza, M. R. V. and Bertazzoli, R. (2002) Cyanide oxidation from wastewater in a flow electrochemical reactor. Ind. Eng. Chem. Res. 41, 22–26.

    CrossRef  CAS  Google Scholar 

  • Leffrang, U., Ebert, K., Flory, K., Galla, U. and Schmeider, H. (1995) Organic waste destruction by indirect electrooxidation. Sep. Purif. Technol. 30, 1883–1899.

    CAS  Google Scholar 

  • Li, X.-y., Cui, Y.-h., Feng, Y.-j., Xie, Z.-m. and Gu, J.-D. (2005) Reaction pathways and mechanisms of the electrochemical degradation of phenol on different electrodes. Water Res. 39, 1972–1981.

    Google Scholar 

  • Lin, S. H. and Chen, M. L. (1997) Treatment of textile wastewater by chemical methods for reuse. Water Res. 31, 868–876.

    CrossRef  CAS  Google Scholar 

  • Lipp, L. and Pletcher, D. (1997) Preparation and characterization of tin dioxide coated titanium electrodes. Electrochim. Acta 42, 1091–1099.

    CrossRef  CAS  Google Scholar 

  • Lissens, G., Pieters, J., Verhaege, M., Pinoy, L. and Verstraete, W. (2003) Electrochemical degradation of surfactants by intermediates of water discharge at carbon-based electrodes. Electrochim. Acta 48, 1655–1663.

    CrossRef  CAS  Google Scholar 

  • Malpass, G. R. P., Neves, R. S. and Motheo, A. J. (2006) A comparative study of commercial and laboratory-made Ti ∕ Ru0. 3Ti0. 7O2 DSA electrodes: “In situ” and “ex situ” surface characterisation and organic oxidation activity. Electrochim. Acta 52, 936–944.

    CAS  Google Scholar 

  • Marselli, B., Garcia-Gomez, J., Michaud, P. A., Rodrigo, M. A. and Comninellis, C. (2003) Electrogeneration of hydroxyl radicals on boron-doped diamond electrodes. J. Electrochem. Soc. 150, D79–D83.

    CrossRef  CAS  Google Scholar 

  • Martinez-Huitle, C. A., Ferro, S. and De Battisti, A. (2004a) Electrochemical incineration of oxalic acid: Role of electrode material. Electrochim. Acta 49, 4027–4034.

    CrossRef  CAS  Google Scholar 

  • Martinez-Huitle, C. A., Quiroz, M. A., Comninellis, C., Ferro, S. and De Battisti, A. (2004b) Electrochemical incineration of chloranilic acid using Ti ∕ IrO2, Pb ∕ PbO2 and Si/BDD electrodes. Electrochim. Acta 50, 949–956.

    CrossRef  CAS  Google Scholar 

  • Martinez-Huitle, C. A., Ferro, S. and De Battisti, A. (2005) Electrochemical incineration in the presence of halides. Electrochem. Solid State Lett. 8, 35–39.

    CrossRef  CAS  Google Scholar 

  • Montilla, F., Michaud, P. A., Morallon, E., Vazquez, J. L. and Comninellis, C. (2002) Electro-chemical oxidation of benzoic acid at boron-doped diamond electrodes. Electrochim. Acta 47, 3509–3513.

    CrossRef  CAS  Google Scholar 

  • Morao, A., Lopes, A., Amorim, M. T. P. d. and Goncalves, I. C. (2004) Degradation of mixtures of phenols using boron doped diamond electrodes for wastewater treatment. Electrochim. Acta 49, 1587–1595.

    Google Scholar 

  • Naumczyk, J., Szpyrkowicz, L. and Zillio-Grandi, F. (1996) Electrochemical treatment of textile wastewater. Water Sci. Technol. 34, 17–24.

    CAS  Google Scholar 

  • Nelson, N. (2002) Electrochemical destruction of organic hazardous wastes. Plainum Met. Rev. 46, 18–23.

    CAS  Google Scholar 

  • Ogutveren, U. B., Toru, E. and Koparal, S. (1999) Removal of cyanide by anodic oxidation for wastewater treatment. Water Res. 33, 1851–1856.

    CrossRef  CAS  Google Scholar 

  • Panizza, M. and Cerisola, G. (2001) Removal of organic pollutants from industrial wastewater by electrogenerated Fenton’s reagent. Water Res. 35, 3987–3992.

    CrossRef  CAS  Google Scholar 

  • Panizza, M. and Cerisola, G. (2003a) Electrochemical oxidation of 2-naphthol with in situ electrogenerated active chlorine. Electrochim. Acta 48, 1515–1519.

    CrossRef  CAS  Google Scholar 

  • Panizza, M. and Cerisola, G. (2003b) Influence of anode material on the electrochemical oxidation of 2-naphthol. Part 1. Cyclic voltammetry and potential step experiments. Electrochim. Acta 48, 3491–3497.

    CAS  Google Scholar 

  • Panizza, M. and Cerisola, G. (2004a) Electrochemical oxidation as final treatment of synthetic tannery wastewater. Environ. Sci. Technol. 38, 5470–5475.

    CrossRef  CAS  Google Scholar 

  • Panizza, M. and Cerisola, G. (2004b) Influence of anode material on the electrochemical oxidation of 2-naphthol: Part 2. Bulk electrolysis experiments. Electrochim. Acta 49, 3221–3226.

    CrossRef  CAS  Google Scholar 

  • Panizza, M. and Cerisola, G. (2005) Application of diamond electrodes to electrochemical processes. Electrochim. Acta 51, 191–199.

    CrossRef  CAS  Google Scholar 

  • Panizza, M. and Cerisola, G. (2006a) Electrochemical oxidation of aromatic sulphonated acids on a boron-doped diamond electrode. Int. J. Environ. Pollut. 27, 64–74.

    CAS  Google Scholar 

  • Panizza, M. and Cerisola, G. (2006b) Electrochemical processes for the treatment of organic pollutants. In: D. V. Zinger (Eds.), Advances in Chemistry Research, Vol. 2. Nova Science, New York, NY, pp. 1–38.

    Google Scholar 

  • Panizza, M. and Cerisola, G. (2006c) Olive mill wastewater treatment by anodic oxidation with parallel plate electrodes. Water Res. 40, 1179–1184.

    CrossRef  CAS  Google Scholar 

  • Panizza, M., Bocca, C. and Cerisola, G. (2000) Electrochemical treatment of wastewater containing poliaromatic organic pollutants. Water Res. 34, 2601–2605.

    CrossRef  CAS  Google Scholar 

  • Panizza, M., Michaud, P. A., Cerisola, G. and Comninellis, C. (2001a) Anodic oxidation of 2-naphthol at boron-doped diamond electrodes. J. Electroanal. Chem. 507, 206.

    CrossRef  CAS  Google Scholar 

  • Panizza, M., Michaud, P. A., Cerisola, G. and Comninellis, C. (2001b) Electrochemical treatment of wastewater containing organic pollutants on boron-doped diamond electrodes. Prediction of specific energy consumption and required electrode area. Electrochem. Commun. 3, 336.

    CAS  Google Scholar 

  • Panizza, M., Delucchi, M. and Cerisola, G. (2005) Electrochemical degradation of anionic surfactants. J. Appl. Electrochem. 35, 357–361.

    CrossRef  CAS  Google Scholar 

  • Perret, A., Haenni, W., Skinner, N., Tang, X. M., Gandini, D., Comninellis, C., Correa, B. and Foti, G. (1999) Electrochemical behavior of synthetic diamond thin film electrodes. Diam. Relat. Mater. 8, 820–823.

    CrossRef  CAS  Google Scholar 

  • Piya-areetham, P., Shenchunthichai, K. and Hunsom, M. (2006) Application of electrooxidation process for treating concentrated wastewater from distillery industry with a voluminous electrode. Water Res. 40, 2857–2864.

    CrossRef  CAS  Google Scholar 

  • Pletcher, D. and Walsh, F. C. (1982) Industrial Electrochemistry. Chapman and Hall, London.

    Google Scholar 

  • Polcaro, A. M. and Palmas, S. (1997) Electrochemical oxidation of chlorophenols. Ind. Eng. Chem. Res., 1791–1798.

    Google Scholar 

  • Polcaro, A. M., Palmas, S., Renoldi, F. and Mascia, M. (1999) On the performance of Ti∕SnO2 and Ti∕PbO2 anodes in electrochemical degradation of 2-chlorophenol for wastewater treatment. J. Appl. Electrochem. 29, 147–151.

    CrossRef  CAS  Google Scholar 

  • Polcaro, A. M., Palmas, S., Renoldi, F. and Mascia, M. (2000) Three-dimensional electrodes for the electrochemical combustion of organic pollutants. Electrochim. Acta 46, 389–394.

    CrossRef  CAS  Google Scholar 

  • Polcaro, A. M., Vacca, A., Palmas, S. and Mascia, M. (2003) Electrochemical treatment of wastewater containing phenolic compounds: Oxidation at boron-doped diamond electrodes. J. Appl. Electrochem. 33, 885–892.

    CrossRef  CAS  Google Scholar 

  • Polcaro, A. M., Vacca, A., Mascia, M. and Palmas, S. (2005) Oxidation at boron doped diamond electrodes: An effective method to mineralise triazines. Electrochim. Acta 50, 1841–1847.

    CrossRef  CAS  Google Scholar 

  • Ponce-de-Leon, C. and Pletcher, D. (1995) Removal of formaldehyde from aqueous solutions via oxygen reduction using a reticulated vitreous carbon cathode cell. J. Appl. Electrochem. 25, 307–314.

    CAS  Google Scholar 

  • Pulgarin, C., Adler, N., Peringer, P. and Comninellis, C. (1994) Electrochemical detoxification of a 1,4-benzoquinone solution in wastewater treatment. Water Res. 28, 887–893.

    CrossRef  CAS  Google Scholar 

  • Rajeshwar, K. and Ibanez, J. G. (1997) Environmental Electrochemistry. Fundamentals and Applications in Pollution Abatement. Academic, London.

    Google Scholar 

  • Rajeshwar, K., Ibanez, J. G. and Swain, G. M. (1994) Electrochemistry and environment. J. Appl. Electrochem. 24, 1077–1091.

    CrossRef  CAS  Google Scholar 

  • Rodgers, J. D., Jedral, W. and Bunce, N. J. (1999) Electrochemical oxidation of chlorinated phenols. Environ. Sci. Technol. 33, 1453–1457.

    CrossRef  CAS  Google Scholar 

  • Rodrigo, M. A., Michaud, P. A., Duo, I., Panizza, M., Cerisola, G. and Comninellis, C. (2001) Oxidation of 4-Chlorophenol at boron-doped diamond electrodes for wastewater treatment. J. Electrochem. Soc. 148, D60–D64.

    CrossRef  CAS  Google Scholar 

  • Rychen, P., Pupunat, L., Haenni, W. and Santoli, E. (2003) Water treatment applications with BDD electrodes and the DiaCell concept. New Diam. Front. Carbon Technol. 13, 109–117.

    CAS  Google Scholar 

  • Saracco, G., Solarino, L., Aigotti, R., Specchia, V. and Maja, M. (2000) Electrochemical oxidation of organic pollutants at low electrolyte concentrations. Electrochim. Acta 46, 373–380.

    CrossRef  CAS  Google Scholar 

  • Sharifian, H. and Kirk, D. (1986) Electrochemical oxidation of phenol. J. Electrochem. Soc. 113, 921–924.

    CrossRef  Google Scholar 

  • Simond, O., Schaller, V. and Comninellis, C. (1997) Theoretical model for the anodic oxidation of organics on metal oxide electrodes. Electrochim. Acta 42, 2009–2012.

    CrossRef  CAS  Google Scholar 

  • Smith-de-Sucre, V. and Watkinson, A. P. (1981) Anodic oxidation of phenol for wastewater treatment. Can. J. Chem. Eng. 59, 52–59.

    CrossRef  Google Scholar 

  • Socha, A., Chrzescijanska, E. and Kusmierek, E. (2005) Electrochemical and photoelectro-chemical treatment of 1-aminonaphthalene-3,6-disulphonic acid. Dyes Pigm. 67, 71–75.

    CrossRef  CAS  Google Scholar 

  • Soriaga, M. P. and Hubbard, A. T. (1982) Determination of the orientation of adsorbed molecules at solid–liquid interfaces by thin-layer electrochemistry: Aromatic compounds at platinum electrodes. J. Am. Chem. Soc. 104, 2735–2742.

    CrossRef  CAS  Google Scholar 

  • Stucki, S., Kotz, R., Carcer, B. and Suter, W. (1991) Electrochemical wastewater treatment using high overvoltage anodes. Part II: Anode performance and applications. J. Appl. Electrochem. 21, 99–104.

    CAS  Google Scholar 

  • Szpyrkowicz, L., Naumczyk, J. and Zilio-Grandi, F. (1995) Electrochemical treatment of tannery wastewater using Ti/Pt and Ti/Pt/Ir electrodes. Water Res. 29, 517–524.

    CrossRef  CAS  Google Scholar 

  • Szpyrkowicz, L., Juzzolino, C., Kaul, S. N., Daniele, S. and DeFaveri, M. (2000) Electro-chemical oxidation of dyeing baths bearing disperse dyes. Ind. Eng. Chem. Res. 39, 3241–3248.

    CrossRef  CAS  Google Scholar 

  • Szpyrkowicz, L., Kelsall, G. H., Kaul, S. N. and DeFaveri, M. (2001) Performance of electro-chemical reactor for treatment of tannery wastewaters. Chem. Eng. Sci. 56, 1579–1586.

    CrossRef  CAS  Google Scholar 

  • Tahar, N. B. and Savall, A. (1998) Mechanistic aspects of phenol electrochemical degradation by oxidation on a Ta/PbO2 anode. J. Electrochem. Soc. 145, 3427–3434.

    CrossRef  CAS  Google Scholar 

  • Tahar, N. B. and Savall, A. (1999a) A comparison of different lead dioxide coated electrodes for the electrochemical destruction of phenol. J. New Mat. Electr. Sys. 2, 19–26.

    CAS  Google Scholar 

  • Tahar, N. B. and Savall, A. (1999b) Electrochemical degradation of phenol in aqueous solution on bismuth doped lead dioxide: A comparison of the activities of various electrode formulations. J. Appl. Electrochem. 29, 277–283.

    CrossRef  CAS  Google Scholar 

  • Tatapudi, P. and Fenton, J. M. (1993) Synthesis of ozone in a proton exchange membrane electrochemical reactor. J. Electrochem. Soc. 140, 3527–3530.

    CrossRef  CAS  Google Scholar 

  • Troster, I., Fryda, M., Herrmann, D., Schafer, L., Haenni, W., Perret, A., Blaschke, M., Kraft, A. and Stadelmann, M. (2002) Electrochemical advanced oxidation process for water treatment using DiaChem electrodes. Diam. Relat. Mater. 11, 640–645.

    CrossRef  CAS  Google Scholar 

  • Vicent, F., Morallon, E., Quijada, C., Vazquez, J. L., Aldaz, A. and Cases, F. (1998) Characterization and stability of doped SnO2 anodes. J. Appl. Electrochem. 28, 607–612.

    CrossRef  CAS  Google Scholar 

  • Vlyssides, A. G. and Israilides, C. J. (1997) Detoxification of tannery waste liquors with an electrolysis system. Environ. Pollut. 97, 147–152.

    CrossRef  CAS  Google Scholar 

  • Vlyssides, A. G., Papaioannou, D., Loizidoy, M., Karlis, P. K. and Zorpas, A. A. (2000) Testing an electrochemical method for treatment of textile dye wastewater. Waste Manage. 20, 569–574.

    CrossRef  CAS  Google Scholar 

  • Vlyssides, A. G., Karlis, P. K. and Mahnken, G. (2003) Influence of various parameters on the electrochemical treatment of landfill leachates. J. Appl. Electrochem. 33, 155–159.

    CrossRef  CAS  Google Scholar 

  • Yang, C. H., Lee, C. C. and Wen, T. C. (2000) Hypochlorite generation on Ru–Ti binary oxide for the treatment of dye wastewater. J. Appl. Electrochem. 30, 1043–1051.

    CrossRef  CAS  Google Scholar 

  • Zanta, C. L. P. S., Andrade, A. R. d. and Boodts, J. F. C. (2000) Electrochemical behaviour of olefins: Oxidation at ruthenium-titanium dioxide and iridium-titanium dioxide coated electrodes. J. Appl. Electrochem., 467–474.

    Google Scholar 

  • Zanta, C. L. P. S., Michaud, P. A., Comninellis, C., Andrade, A. R. D. and Boodts, J. F. C. (2003) Electrochemical oxidation of p-chlorophenol on SnO2-Sb2O5 based anodes for wastewater treatment. J. Appl. Electrochem. 33, 1211–1215.

    CrossRef  CAS  Google Scholar 

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Acknowledgments

The author wishes to express his sincere thanks to Prof. Giacomo Cerisola for his helpful discussions during the preparation of this article and to the journals and all the authors who gave permission for the reproduction of figures and tables.

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  1. Department of Chemical and Process Engineering, University of Genoa, Genoa, Italy

    Marco Panizza

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  1. Dept. Chemical Engineering, Ecole Polytech. Fed. Lausanne, Lausanne, 1015, Switzerland

    Christos Comninellis

  2. Science and Technology, Hong Kong University of, Clear Water Bay, Kowloon, Hong Kong/PR China

    Guohua Chen

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Panizza, M. (2010). Importance of Electrode Material in the Electrochemical Treatment of Wastewater Containing Organic Pollutants. In: Comninellis, C., Chen, G. (eds) Electrochemistry for the Environment. Springer, New York, NY. https://doi.org/10.1007/978-0-387-68318-8_2

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